Promotion Effect of Palladium on BiVO<sub>4</sub> Sensing Material for Epinephrine Detection

In this study, the Pd/BiVO<sub>4</sub> composite was prepared by hydrothermal method as an electrochemical sensing material for epinephrine. X-ray diffraction, scanning electron microscopy, and a transmission electron microscope were used to characterize the samples. In the electrochemic...

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Main Authors: Hsiang-Ning Luk, Tsong-Yung Chou, Bai-Hao Huang, Yu-Syuan Lin, Hui Li, Ren-Jang Wu
Format: Article
Language:English
Published: MDPI AG 2021-09-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/11/9/1083
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author Hsiang-Ning Luk
Tsong-Yung Chou
Bai-Hao Huang
Yu-Syuan Lin
Hui Li
Ren-Jang Wu
author_facet Hsiang-Ning Luk
Tsong-Yung Chou
Bai-Hao Huang
Yu-Syuan Lin
Hui Li
Ren-Jang Wu
author_sort Hsiang-Ning Luk
collection DOAJ
description In this study, the Pd/BiVO<sub>4</sub> composite was prepared by hydrothermal method as an electrochemical sensing material for epinephrine. X-ray diffraction, scanning electron microscopy, and a transmission electron microscope were used to characterize the samples. In the electrochemical detection system, cyclic voltammetry and differential pulse voltammetry were applied to measure the concentration of the epinephrine solution (0.9–27.5 µM) with the Pd/BiVO<sub>4</sub>-coated glassy carbon electrode. As a result, the oxidation peak current of Pd/BiVO<sub>4</sub>/GCE demonstrated good linearity with the epinephrine concentration. The detection limit of the epinephrine concentration by cyclic voltammetry and differential pulse voltammetry were 0.262 µM and 0.154 µM, respectively. Additionally, the proposed sensing material exhibited good reproducibility, stability, and selectivity. A plausible sensing mechanism was proposed.
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spelling doaj.art-63cdb321c5bb41dbbde5031654d0d6072023-11-22T12:21:08ZengMDPI AGCatalysts2073-43442021-09-01119108310.3390/catal11091083Promotion Effect of Palladium on BiVO<sub>4</sub> Sensing Material for Epinephrine DetectionHsiang-Ning Luk0Tsong-Yung Chou1Bai-Hao Huang2Yu-Syuan Lin3Hui Li4Ren-Jang Wu5Department of Anesthesia, Hualien Tzu-Chi Hospital, Hualien 97002, TaiwanDepartment of Laboratory Medicine and Biotechnology, Graduate Institute of Medical Biotechnology, Tzu Chi University, 701, Zhongyang Road Section 3, Hualien 97004, TaiwanDepartment of Applied Chemistry, Providence University, Shalu, Taichung 43301, TaiwanDepartment of Applied Chemistry, Providence University, Shalu, Taichung 43301, TaiwanCenter for Advanced Thin Films and Devices, School of Materials and Energy, Southwest University, Chongqing 400715, ChinaDepartment of Applied Chemistry, Providence University, Shalu, Taichung 43301, TaiwanIn this study, the Pd/BiVO<sub>4</sub> composite was prepared by hydrothermal method as an electrochemical sensing material for epinephrine. X-ray diffraction, scanning electron microscopy, and a transmission electron microscope were used to characterize the samples. In the electrochemical detection system, cyclic voltammetry and differential pulse voltammetry were applied to measure the concentration of the epinephrine solution (0.9–27.5 µM) with the Pd/BiVO<sub>4</sub>-coated glassy carbon electrode. As a result, the oxidation peak current of Pd/BiVO<sub>4</sub>/GCE demonstrated good linearity with the epinephrine concentration. The detection limit of the epinephrine concentration by cyclic voltammetry and differential pulse voltammetry were 0.262 µM and 0.154 µM, respectively. Additionally, the proposed sensing material exhibited good reproducibility, stability, and selectivity. A plausible sensing mechanism was proposed.https://www.mdpi.com/2073-4344/11/9/1083epinephrinecyclic voltammetrydifferential pulse voltammetryPd/BiVO<sub>4</sub>
spellingShingle Hsiang-Ning Luk
Tsong-Yung Chou
Bai-Hao Huang
Yu-Syuan Lin
Hui Li
Ren-Jang Wu
Promotion Effect of Palladium on BiVO<sub>4</sub> Sensing Material for Epinephrine Detection
Catalysts
epinephrine
cyclic voltammetry
differential pulse voltammetry
Pd/BiVO<sub>4</sub>
title Promotion Effect of Palladium on BiVO<sub>4</sub> Sensing Material for Epinephrine Detection
title_full Promotion Effect of Palladium on BiVO<sub>4</sub> Sensing Material for Epinephrine Detection
title_fullStr Promotion Effect of Palladium on BiVO<sub>4</sub> Sensing Material for Epinephrine Detection
title_full_unstemmed Promotion Effect of Palladium on BiVO<sub>4</sub> Sensing Material for Epinephrine Detection
title_short Promotion Effect of Palladium on BiVO<sub>4</sub> Sensing Material for Epinephrine Detection
title_sort promotion effect of palladium on bivo sub 4 sub sensing material for epinephrine detection
topic epinephrine
cyclic voltammetry
differential pulse voltammetry
Pd/BiVO<sub>4</sub>
url https://www.mdpi.com/2073-4344/11/9/1083
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AT baihaohuang promotioneffectofpalladiumonbivosub4subsensingmaterialforepinephrinedetection
AT yusyuanlin promotioneffectofpalladiumonbivosub4subsensingmaterialforepinephrinedetection
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AT renjangwu promotioneffectofpalladiumonbivosub4subsensingmaterialforepinephrinedetection