Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball Milling

A large amount of biomass straw waste is generated every year in the world, which can cause serious environmental pollution and resource waste if disposed of improperly. At present, biomass-derived porous carbon materials prepared from biomass waste as a carbon source have garnered attention due to...

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Main Authors: Bixia Jiang, Lin Cao, Qinghua Yuan, Zhuwen Ma, Zhenrui Huang, Zhidan Lin, Peng Zhang
Format: Article
Language:English
Published: MDPI AG 2022-01-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/15/3/924
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author Bixia Jiang
Lin Cao
Qinghua Yuan
Zhuwen Ma
Zhenrui Huang
Zhidan Lin
Peng Zhang
author_facet Bixia Jiang
Lin Cao
Qinghua Yuan
Zhuwen Ma
Zhenrui Huang
Zhidan Lin
Peng Zhang
author_sort Bixia Jiang
collection DOAJ
description A large amount of biomass straw waste is generated every year in the world, which can cause serious environmental pollution and resource waste if disposed of improperly. At present, biomass-derived porous carbon materials prepared from biomass waste as a carbon source have garnered attention due to their renewability, huge reserves, low cost, and environmental benevolence. In this work, high-performance carbon materials were prepared via a one-step carbonization-activation method and ball milling, with waste tobacco straw as precursor and nano-ZnO as template and activator. The specific surface area and porous structure of biomass-derived carbon could be controlled by carbonization temperature, which is closely related to the electrochemical performances of the carbon material. It was found that, when the carbonization temperature was 800 °C, the biochar possesses maximum specific surface area (1293.2 m<sup>2</sup>·g<sup>−1</sup>) and exhibits high capacitance of 220.7 F·g<sup>−1</sup>, at 1 A·g<sup>−1</sup> current density in a three-electrode configuration with 6 M KOH aqueous solution. The capacitance retention maintained about 94.83% at 5 A·g<sup>−1</sup> after 3000 cycles. This work proves the porous biochar derived from tobacco straws has a great potential prospect in the field of supercapacitors.
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spelling doaj.art-63d2143d514b4baa913f10495ee708332023-11-23T16:59:21ZengMDPI AGMaterials1996-19442022-01-0115392410.3390/ma15030924Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball MillingBixia Jiang0Lin Cao1Qinghua Yuan2Zhuwen Ma3Zhenrui Huang4Zhidan Lin5Peng Zhang6Institute of Advanced Wear & Corrosion Resistant and Functional Materials, Jinan University, Guangzhou 510632, ChinaInstitute of Advanced Wear & Corrosion Resistant and Functional Materials, Jinan University, Guangzhou 510632, ChinaKey Laboratory of Crop Genetic Improvement of Guangdong Province/Guangdong Provincial Engineering & Technology Research Center for Tobacco Breeding and Comprehensive Utilization, Crops Research Institute, Guangdong Academy of Agricultural Sciences, Guangzhou 510640, ChinaKey Laboratory of Crop Genetic Improvement of Guangdong Province/Guangdong Provincial Engineering & Technology Research Center for Tobacco Breeding and Comprehensive Utilization, Crops Research Institute, Guangdong Academy of Agricultural Sciences, Guangzhou 510640, ChinaKey Laboratory of Crop Genetic Improvement of Guangdong Province/Guangdong Provincial Engineering & Technology Research Center for Tobacco Breeding and Comprehensive Utilization, Crops Research Institute, Guangdong Academy of Agricultural Sciences, Guangzhou 510640, ChinaInstitute of Advanced Wear & Corrosion Resistant and Functional Materials, Jinan University, Guangzhou 510632, ChinaInstitute of Advanced Wear & Corrosion Resistant and Functional Materials, Jinan University, Guangzhou 510632, ChinaA large amount of biomass straw waste is generated every year in the world, which can cause serious environmental pollution and resource waste if disposed of improperly. At present, biomass-derived porous carbon materials prepared from biomass waste as a carbon source have garnered attention due to their renewability, huge reserves, low cost, and environmental benevolence. In this work, high-performance carbon materials were prepared via a one-step carbonization-activation method and ball milling, with waste tobacco straw as precursor and nano-ZnO as template and activator. The specific surface area and porous structure of biomass-derived carbon could be controlled by carbonization temperature, which is closely related to the electrochemical performances of the carbon material. It was found that, when the carbonization temperature was 800 °C, the biochar possesses maximum specific surface area (1293.2 m<sup>2</sup>·g<sup>−1</sup>) and exhibits high capacitance of 220.7 F·g<sup>−1</sup>, at 1 A·g<sup>−1</sup> current density in a three-electrode configuration with 6 M KOH aqueous solution. The capacitance retention maintained about 94.83% at 5 A·g<sup>−1</sup> after 3000 cycles. This work proves the porous biochar derived from tobacco straws has a great potential prospect in the field of supercapacitors.https://www.mdpi.com/1996-1944/15/3/924porous carbon materialssupercapacitortobacco strawsbiochar
spellingShingle Bixia Jiang
Lin Cao
Qinghua Yuan
Zhuwen Ma
Zhenrui Huang
Zhidan Lin
Peng Zhang
Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball Milling
Materials
porous carbon materials
supercapacitor
tobacco straws
biochar
title Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball Milling
title_full Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball Milling
title_fullStr Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball Milling
title_full_unstemmed Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball Milling
title_short Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball Milling
title_sort biomass straw derived porous carbon synthesized for supercapacitor by ball milling
topic porous carbon materials
supercapacitor
tobacco straws
biochar
url https://www.mdpi.com/1996-1944/15/3/924
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