Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball Milling
A large amount of biomass straw waste is generated every year in the world, which can cause serious environmental pollution and resource waste if disposed of improperly. At present, biomass-derived porous carbon materials prepared from biomass waste as a carbon source have garnered attention due to...
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MDPI AG
2022-01-01
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author | Bixia Jiang Lin Cao Qinghua Yuan Zhuwen Ma Zhenrui Huang Zhidan Lin Peng Zhang |
author_facet | Bixia Jiang Lin Cao Qinghua Yuan Zhuwen Ma Zhenrui Huang Zhidan Lin Peng Zhang |
author_sort | Bixia Jiang |
collection | DOAJ |
description | A large amount of biomass straw waste is generated every year in the world, which can cause serious environmental pollution and resource waste if disposed of improperly. At present, biomass-derived porous carbon materials prepared from biomass waste as a carbon source have garnered attention due to their renewability, huge reserves, low cost, and environmental benevolence. In this work, high-performance carbon materials were prepared via a one-step carbonization-activation method and ball milling, with waste tobacco straw as precursor and nano-ZnO as template and activator. The specific surface area and porous structure of biomass-derived carbon could be controlled by carbonization temperature, which is closely related to the electrochemical performances of the carbon material. It was found that, when the carbonization temperature was 800 °C, the biochar possesses maximum specific surface area (1293.2 m<sup>2</sup>·g<sup>−1</sup>) and exhibits high capacitance of 220.7 F·g<sup>−1</sup>, at 1 A·g<sup>−1</sup> current density in a three-electrode configuration with 6 M KOH aqueous solution. The capacitance retention maintained about 94.83% at 5 A·g<sup>−1</sup> after 3000 cycles. This work proves the porous biochar derived from tobacco straws has a great potential prospect in the field of supercapacitors. |
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institution | Directory Open Access Journal |
issn | 1996-1944 |
language | English |
last_indexed | 2024-03-09T23:36:58Z |
publishDate | 2022-01-01 |
publisher | MDPI AG |
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spelling | doaj.art-63d2143d514b4baa913f10495ee708332023-11-23T16:59:21ZengMDPI AGMaterials1996-19442022-01-0115392410.3390/ma15030924Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball MillingBixia Jiang0Lin Cao1Qinghua Yuan2Zhuwen Ma3Zhenrui Huang4Zhidan Lin5Peng Zhang6Institute of Advanced Wear & Corrosion Resistant and Functional Materials, Jinan University, Guangzhou 510632, ChinaInstitute of Advanced Wear & Corrosion Resistant and Functional Materials, Jinan University, Guangzhou 510632, ChinaKey Laboratory of Crop Genetic Improvement of Guangdong Province/Guangdong Provincial Engineering & Technology Research Center for Tobacco Breeding and Comprehensive Utilization, Crops Research Institute, Guangdong Academy of Agricultural Sciences, Guangzhou 510640, ChinaKey Laboratory of Crop Genetic Improvement of Guangdong Province/Guangdong Provincial Engineering & Technology Research Center for Tobacco Breeding and Comprehensive Utilization, Crops Research Institute, Guangdong Academy of Agricultural Sciences, Guangzhou 510640, ChinaKey Laboratory of Crop Genetic Improvement of Guangdong Province/Guangdong Provincial Engineering & Technology Research Center for Tobacco Breeding and Comprehensive Utilization, Crops Research Institute, Guangdong Academy of Agricultural Sciences, Guangzhou 510640, ChinaInstitute of Advanced Wear & Corrosion Resistant and Functional Materials, Jinan University, Guangzhou 510632, ChinaInstitute of Advanced Wear & Corrosion Resistant and Functional Materials, Jinan University, Guangzhou 510632, ChinaA large amount of biomass straw waste is generated every year in the world, which can cause serious environmental pollution and resource waste if disposed of improperly. At present, biomass-derived porous carbon materials prepared from biomass waste as a carbon source have garnered attention due to their renewability, huge reserves, low cost, and environmental benevolence. In this work, high-performance carbon materials were prepared via a one-step carbonization-activation method and ball milling, with waste tobacco straw as precursor and nano-ZnO as template and activator. The specific surface area and porous structure of biomass-derived carbon could be controlled by carbonization temperature, which is closely related to the electrochemical performances of the carbon material. It was found that, when the carbonization temperature was 800 °C, the biochar possesses maximum specific surface area (1293.2 m<sup>2</sup>·g<sup>−1</sup>) and exhibits high capacitance of 220.7 F·g<sup>−1</sup>, at 1 A·g<sup>−1</sup> current density in a three-electrode configuration with 6 M KOH aqueous solution. The capacitance retention maintained about 94.83% at 5 A·g<sup>−1</sup> after 3000 cycles. This work proves the porous biochar derived from tobacco straws has a great potential prospect in the field of supercapacitors.https://www.mdpi.com/1996-1944/15/3/924porous carbon materialssupercapacitortobacco strawsbiochar |
spellingShingle | Bixia Jiang Lin Cao Qinghua Yuan Zhuwen Ma Zhenrui Huang Zhidan Lin Peng Zhang Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball Milling Materials porous carbon materials supercapacitor tobacco straws biochar |
title | Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball Milling |
title_full | Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball Milling |
title_fullStr | Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball Milling |
title_full_unstemmed | Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball Milling |
title_short | Biomass Straw-Derived Porous Carbon Synthesized for Supercapacitor by Ball Milling |
title_sort | biomass straw derived porous carbon synthesized for supercapacitor by ball milling |
topic | porous carbon materials supercapacitor tobacco straws biochar |
url | https://www.mdpi.com/1996-1944/15/3/924 |
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