Chlorido{5,5′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}manganese(III)
In the title complex, [Mn(C22H18N2O4)Cl], the MnIII centre is in a distorted square-pyramidal configuration, with the basal plane formed by the N2O2 donors of the tetradentate Schiff base dianion; the two phenolate O atoms and the two imine N atoms are each mutually cis. The chloride ion occupies th...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2008-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808009835 |
| _version_ | 1798018467325018112 |
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| author | Rohana Adnan Hoong-Kun Fun Suchada Chantrapromma Siang Guan Teoh Naser Eltaher Eltayeb |
| author_facet | Rohana Adnan Hoong-Kun Fun Suchada Chantrapromma Siang Guan Teoh Naser Eltaher Eltayeb |
| author_sort | Rohana Adnan |
| collection | DOAJ |
| description | In the title complex, [Mn(C22H18N2O4)Cl], the MnIII centre is in a distorted square-pyramidal configuration, with the basal plane formed by the N2O2 donors of the tetradentate Schiff base dianion; the two phenolate O atoms and the two imine N atoms are each mutually cis. The chloride ion occupies the apical position. The dihedral angle between the two outer phenolate rings of the tetradentate Schiff base ligand is 16.44 (9)°. The central benzene ring makes dihedral angles of 10.64 (9) and 25.17 (10)° with the two outer phenolate rings. In the crystal structure, weak C—H...O and C—H...Cl interactions link the molecules into wave-like face-to-face double layers along the c direction. A π–π interaction involving the two outer phenolate rings is observed, the centroid–centroid distance being 3.743 (11) Å. |
| first_indexed | 2024-04-11T16:24:31Z |
| format | Article |
| id | doaj.art-642a7ef33b754c91b6c8876085b2146e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:24:31Z |
| publishDate | 2008-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-642a7ef33b754c91b6c8876085b2146e2022-12-22T04:14:13ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-05-01645m670m67110.1107/S1600536808009835Chlorido{5,5′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}manganese(III)Rohana AdnanHoong-Kun FunSuchada ChantraprommaSiang Guan TeohNaser Eltaher EltayebIn the title complex, [Mn(C22H18N2O4)Cl], the MnIII centre is in a distorted square-pyramidal configuration, with the basal plane formed by the N2O2 donors of the tetradentate Schiff base dianion; the two phenolate O atoms and the two imine N atoms are each mutually cis. The chloride ion occupies the apical position. The dihedral angle between the two outer phenolate rings of the tetradentate Schiff base ligand is 16.44 (9)°. The central benzene ring makes dihedral angles of 10.64 (9) and 25.17 (10)° with the two outer phenolate rings. In the crystal structure, weak C—H...O and C—H...Cl interactions link the molecules into wave-like face-to-face double layers along the c direction. A π–π interaction involving the two outer phenolate rings is observed, the centroid–centroid distance being 3.743 (11) Å.http://scripts.iucr.org/cgi-bin/paper?S1600536808009835 |
| spellingShingle | Rohana Adnan Hoong-Kun Fun Suchada Chantrapromma Siang Guan Teoh Naser Eltaher Eltayeb Chlorido{5,5′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}manganese(III) Acta Crystallographica Section E |
| title | Chlorido{5,5′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}manganese(III) |
| title_full | Chlorido{5,5′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}manganese(III) |
| title_fullStr | Chlorido{5,5′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}manganese(III) |
| title_full_unstemmed | Chlorido{5,5′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}manganese(III) |
| title_short | Chlorido{5,5′-dimethoxy-2,2′-[1,2-phenylenebis(nitrilomethylidyne)]diphenolato-κ4O,N,N′,O′}manganese(III) |
| title_sort | chlorido 5 5 8242 dimethoxy 2 2 8242 1 2 phenylenebis nitrilomethylidyne diphenolato 954 4o n n 8242 o 8242 manganese iii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808009835 |
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