Studies on the luminescence properties of CaZrO3:Eu3+ phosphors prepared by the solid state reaction method

CaZrO3:xEu3+ (x = 1.0, 2.0, 3.0, 4.0, and 5.0 mol%) phosphors were successfully prepared by a solid state reaction method. The crystal structure of sintered phosphors was hexagonal phase with space group of Pm-3m. The near ultra-violet (NUV) excitation, emission spectra of the CaZrO3:xEu3+ phosphors...

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Main Authors: Ishwar Prasad Sahu, D.P. Bisen, Raunak Kumar Tamrakar, K.V.R. Murthy, M. Mohapatra
Format: Article
Language:English
Published: Elsevier 2017-03-01
Series:Journal of Science: Advanced Materials and Devices
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S246821791630185X
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author Ishwar Prasad Sahu
D.P. Bisen
Raunak Kumar Tamrakar
K.V.R. Murthy
M. Mohapatra
author_facet Ishwar Prasad Sahu
D.P. Bisen
Raunak Kumar Tamrakar
K.V.R. Murthy
M. Mohapatra
author_sort Ishwar Prasad Sahu
collection DOAJ
description CaZrO3:xEu3+ (x = 1.0, 2.0, 3.0, 4.0, and 5.0 mol%) phosphors were successfully prepared by a solid state reaction method. The crystal structure of sintered phosphors was hexagonal phase with space group of Pm-3m. The near ultra-violet (NUV) excitation, emission spectra of the CaZrO3:xEu3+ phosphors were composed of sharp line emission associated with the transitions from the excited states 5D0 to the ground state 7Fj (j = 0, 1, 2, 3, 4) of Eu3+. The results indicated that CaZrO3:xEu3+ might become an important orange-red phosphor candidate for use in white light emitting diodes (WLEDs) with near-UV LED chips. The mechanoluminescence (ML) intensity increases linearly with increasing impact velocity of the moving piston, suggesting that the sintered phosphors can also be useful as a stress sensor.
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spelling doaj.art-6451d5c17caf42ed890988bc9ddf0fd62022-12-22T03:18:26ZengElsevierJournal of Science: Advanced Materials and Devices2468-21792017-03-0121697810.1016/j.jsamd.2017.01.002Studies on the luminescence properties of CaZrO3:Eu3+ phosphors prepared by the solid state reaction methodIshwar Prasad Sahu0D.P. Bisen1Raunak Kumar Tamrakar2K.V.R. Murthy3M. Mohapatra4School of Studies in Physics & Astrophysics, Pt. Ravishankar Shukla University, Raipur, C.G., 492010, IndiaSchool of Studies in Physics & Astrophysics, Pt. Ravishankar Shukla University, Raipur, C.G., 492010, IndiaDepartment of Applied Physics, Bhilai Institute of Technology, Durg, C.G., 491001, IndiaFaculty of Technology and Engineering, MS University of Baroda, Baroda, Gujarat, 390001, IndiaRadiochemistry Division, Bhabha Atomic Research Centre, Mumbai, M.H., 400085, IndiaCaZrO3:xEu3+ (x = 1.0, 2.0, 3.0, 4.0, and 5.0 mol%) phosphors were successfully prepared by a solid state reaction method. The crystal structure of sintered phosphors was hexagonal phase with space group of Pm-3m. The near ultra-violet (NUV) excitation, emission spectra of the CaZrO3:xEu3+ phosphors were composed of sharp line emission associated with the transitions from the excited states 5D0 to the ground state 7Fj (j = 0, 1, 2, 3, 4) of Eu3+. The results indicated that CaZrO3:xEu3+ might become an important orange-red phosphor candidate for use in white light emitting diodes (WLEDs) with near-UV LED chips. The mechanoluminescence (ML) intensity increases linearly with increasing impact velocity of the moving piston, suggesting that the sintered phosphors can also be useful as a stress sensor.http://www.sciencedirect.com/science/article/pii/S246821791630185XCaZrO3:Eu3+ phosphorsDecayColor purityWLEDsStress sensor
spellingShingle Ishwar Prasad Sahu
D.P. Bisen
Raunak Kumar Tamrakar
K.V.R. Murthy
M. Mohapatra
Studies on the luminescence properties of CaZrO3:Eu3+ phosphors prepared by the solid state reaction method
Journal of Science: Advanced Materials and Devices
CaZrO3:Eu3+ phosphors
Decay
Color purity
WLEDs
Stress sensor
title Studies on the luminescence properties of CaZrO3:Eu3+ phosphors prepared by the solid state reaction method
title_full Studies on the luminescence properties of CaZrO3:Eu3+ phosphors prepared by the solid state reaction method
title_fullStr Studies on the luminescence properties of CaZrO3:Eu3+ phosphors prepared by the solid state reaction method
title_full_unstemmed Studies on the luminescence properties of CaZrO3:Eu3+ phosphors prepared by the solid state reaction method
title_short Studies on the luminescence properties of CaZrO3:Eu3+ phosphors prepared by the solid state reaction method
title_sort studies on the luminescence properties of cazro3 eu3 phosphors prepared by the solid state reaction method
topic CaZrO3:Eu3+ phosphors
Decay
Color purity
WLEDs
Stress sensor
url http://www.sciencedirect.com/science/article/pii/S246821791630185X
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