Understanding Bridging Sites and Accelerating Quantum Efficiency for Photocatalytic CO2 Reduction
Highlights The S-vacancies result in the change of d-band electronic state of Mo. An internal quantum efficiency of 94.01% at 380 nm for photocatalytic CO2 reduction reaction (CO2RR). The Mo–S bridging bonds optimize adsorption energies and accelerate CO2RR kinetics.
| Main Authors: | , , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
SpringerOpen
2023-11-01
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| Series: | Nano-Micro Letters |
| Subjects: | |
| Online Access: | https://doi.org/10.1007/s40820-023-01221-3 |
| _version_ | 1827068215013933056 |
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| author | Kangwang Wang Zhuofeng Hu Peifeng Yu Alina M. Balu Kuan Li Longfu Li Lingyong Zeng Chao Zhang Rafael Luque Kai Yan Huixia Luo |
| author_facet | Kangwang Wang Zhuofeng Hu Peifeng Yu Alina M. Balu Kuan Li Longfu Li Lingyong Zeng Chao Zhang Rafael Luque Kai Yan Huixia Luo |
| author_sort | Kangwang Wang |
| collection | DOAJ |
| description | Highlights The S-vacancies result in the change of d-band electronic state of Mo. An internal quantum efficiency of 94.01% at 380 nm for photocatalytic CO2 reduction reaction (CO2RR). The Mo–S bridging bonds optimize adsorption energies and accelerate CO2RR kinetics. |
| first_indexed | 2024-03-11T11:02:11Z |
| format | Article |
| id | doaj.art-6477895a266f49759ff6990df39daacb |
| institution | Directory Open Access Journal |
| issn | 2311-6706 2150-5551 |
| language | English |
| last_indexed | 2025-03-19T23:47:10Z |
| publishDate | 2023-11-01 |
| publisher | SpringerOpen |
| record_format | Article |
| series | Nano-Micro Letters |
| spelling | doaj.art-6477895a266f49759ff6990df39daacb2024-10-13T11:32:19ZengSpringerOpenNano-Micro Letters2311-67062150-55512023-11-0116111710.1007/s40820-023-01221-3Understanding Bridging Sites and Accelerating Quantum Efficiency for Photocatalytic CO2 ReductionKangwang Wang0Zhuofeng Hu1Peifeng Yu2Alina M. Balu3Kuan Li4Longfu Li5Lingyong Zeng6Chao Zhang7Rafael Luque8Kai Yan9Huixia Luo10School of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices, Key Lab of Polymer Composite and Functional Materials, Sun Yat-Sen UniversitySchool of Environmental Science and Engineering, Sun Yat-Sen UniversitySchool of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices, Key Lab of Polymer Composite and Functional Materials, Sun Yat-Sen UniversityDepartamento de Química Orgánica, Universidad de CórdobaSchool of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices, Key Lab of Polymer Composite and Functional Materials, Sun Yat-Sen UniversitySchool of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices, Key Lab of Polymer Composite and Functional Materials, Sun Yat-Sen UniversitySchool of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices, Key Lab of Polymer Composite and Functional Materials, Sun Yat-Sen UniversitySchool of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices, Key Lab of Polymer Composite and Functional Materials, Sun Yat-Sen UniversityCenter for Refining and Advanced Chemicals, King Fahd University of Petroleum and MineralsSchool of Environmental Science and Engineering, Sun Yat-Sen UniversitySchool of Materials Science and Engineering, State Key Laboratory of Optoelectronic Materials and Technologies, Guangdong Provincial Key Laboratory of Magnetoelectric Physics and Devices, Key Lab of Polymer Composite and Functional Materials, Sun Yat-Sen UniversityHighlights The S-vacancies result in the change of d-band electronic state of Mo. An internal quantum efficiency of 94.01% at 380 nm for photocatalytic CO2 reduction reaction (CO2RR). The Mo–S bridging bonds optimize adsorption energies and accelerate CO2RR kinetics.https://doi.org/10.1007/s40820-023-01221-3Quantum efficiencyElectronic structureSteric interactionBridging sitesCO2 reduction |
| spellingShingle | Kangwang Wang Zhuofeng Hu Peifeng Yu Alina M. Balu Kuan Li Longfu Li Lingyong Zeng Chao Zhang Rafael Luque Kai Yan Huixia Luo Understanding Bridging Sites and Accelerating Quantum Efficiency for Photocatalytic CO2 Reduction Nano-Micro Letters Quantum efficiency Electronic structure Steric interaction Bridging sites CO2 reduction |
| title | Understanding Bridging Sites and Accelerating Quantum Efficiency for Photocatalytic CO2 Reduction |
| title_full | Understanding Bridging Sites and Accelerating Quantum Efficiency for Photocatalytic CO2 Reduction |
| title_fullStr | Understanding Bridging Sites and Accelerating Quantum Efficiency for Photocatalytic CO2 Reduction |
| title_full_unstemmed | Understanding Bridging Sites and Accelerating Quantum Efficiency for Photocatalytic CO2 Reduction |
| title_short | Understanding Bridging Sites and Accelerating Quantum Efficiency for Photocatalytic CO2 Reduction |
| title_sort | understanding bridging sites and accelerating quantum efficiency for photocatalytic co2 reduction |
| topic | Quantum efficiency Electronic structure Steric interaction Bridging sites CO2 reduction |
| url | https://doi.org/10.1007/s40820-023-01221-3 |
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