O-Phenyl (tert-butylamido)(p-tolylamido)phosphinate
In the title molecule, C17H23N2O2P, the P atom has a distorted tetrahedral environment. The P—N bond to the tolylamido fragment is 1.642 (4) Å while that to the butylamido fragment is 1.629 (3) Å. The dih...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811048537 |
| _version_ | 1798019078210715648 |
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| author | Mehrdad Pourayoubi Arnold L. Rheingold Chao Chen Fatemeh Karimi Ahmadabad Atekeh Tarahhomi |
| author_facet | Mehrdad Pourayoubi Arnold L. Rheingold Chao Chen Fatemeh Karimi Ahmadabad Atekeh Tarahhomi |
| author_sort | Mehrdad Pourayoubi |
| collection | DOAJ |
| description | In the title molecule, C17H23N2O2P, the P atom has a distorted tetrahedral environment. The P—N bond to the tolylamido fragment is 1.642 (4) Å while that to the butylamido fragment is 1.629 (3) Å. The dihedral angle between the two benzene rings is 82.3 (2)°. In the crystal, adjacent molecules are linked via weak N—H...(O)P and N—H...N hydrogen-bonding interactions into an extended chain parallel to the b axis. The three methyl groups of the tert-butylamido substituent are disordered over two sets of sites with equal occupancies. The crystal studied was found to be a non-merohedral twin with the minor twin component = 23.1 (1)%. |
| first_indexed | 2024-04-11T16:34:42Z |
| format | Article |
| id | doaj.art-648c73906e2245a7946108a41fa53202 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-04-11T16:34:42Z |
| publishDate | 2011-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-648c73906e2245a7946108a41fa532022022-12-22T04:13:52ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712o3405o340610.1107/S1600536811048537O-Phenyl (tert-butylamido)(p-tolylamido)phosphinateMehrdad PourayoubiArnold L. RheingoldChao ChenFatemeh Karimi AhmadabadAtekeh TarahhomiIn the title molecule, C17H23N2O2P, the P atom has a distorted tetrahedral environment. The P—N bond to the tolylamido fragment is 1.642 (4) Å while that to the butylamido fragment is 1.629 (3) Å. The dihedral angle between the two benzene rings is 82.3 (2)°. In the crystal, adjacent molecules are linked via weak N—H...(O)P and N—H...N hydrogen-bonding interactions into an extended chain parallel to the b axis. The three methyl groups of the tert-butylamido substituent are disordered over two sets of sites with equal occupancies. The crystal studied was found to be a non-merohedral twin with the minor twin component = 23.1 (1)%.http://scripts.iucr.org/cgi-bin/paper?S1600536811048537 |
| spellingShingle | Mehrdad Pourayoubi Arnold L. Rheingold Chao Chen Fatemeh Karimi Ahmadabad Atekeh Tarahhomi O-Phenyl (tert-butylamido)(p-tolylamido)phosphinate Acta Crystallographica Section E |
| title | O-Phenyl (tert-butylamido)(p-tolylamido)phosphinate |
| title_full | O-Phenyl (tert-butylamido)(p-tolylamido)phosphinate |
| title_fullStr | O-Phenyl (tert-butylamido)(p-tolylamido)phosphinate |
| title_full_unstemmed | O-Phenyl (tert-butylamido)(p-tolylamido)phosphinate |
| title_short | O-Phenyl (tert-butylamido)(p-tolylamido)phosphinate |
| title_sort | o phenyl tert butylamido p tolylamido phosphinate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811048537 |
| work_keys_str_mv | AT mehrdadpourayoubi ophenyltertbutylamidoptolylamidophosphinate AT arnoldlrheingold ophenyltertbutylamidoptolylamidophosphinate AT chaochen ophenyltertbutylamidoptolylamidophosphinate AT fatemehkarimiahmadabad ophenyltertbutylamidoptolylamidophosphinate AT atekehtarahhomi ophenyltertbutylamidoptolylamidophosphinate |