Rhenium Complexes as Highly Active Catalysts for the Hydrosilylation of Carbonyl Compounds
[Re(PiPr3)2(NO)2]+[B(C6F5)4]? (1) and the new NO-functionalized compounds [Re(H)(PiPr3)2(NO)(NOB(C6F5)3)] (2) and [Re(H)(NO)(NOEt)(PiPr3)2]+[B(C6F5)4]? (3) were prepared and found to be excellent catalysts for hydrosilylation of ketones. For 2 and 3 the hydrosilylation procedures are sele...
| Main Authors: | , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
2005-03-01
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| Series: | CHIMIA |
| Subjects: | |
| Online Access: | https://chimia.ch/chimia/article/view/3960 |