A Review on Citric Acid as Green Modifying Agent and Binder for Wood

Citric acid (CA) can be found naturally in fruits and vegetables, particularly citrus fruit. CA is widely used in many fields but its usage as a green modifying agent and binder for wood is barely addressed. Esterification is one of the most common chemical reactions applied in wood modification. CA...

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Main Authors: Seng Hua Lee, Paridah Md Tahir, Wei Chen Lum, Li Peng Tan, Paiman Bawon, Byung-Dae Park, Syeed SaifulAzry Osman Al Edrus, Ummi Hani Abdullah
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/12/8/1692
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author Seng Hua Lee
Paridah Md Tahir
Wei Chen Lum
Li Peng Tan
Paiman Bawon
Byung-Dae Park
Syeed SaifulAzry Osman Al Edrus
Ummi Hani Abdullah
author_facet Seng Hua Lee
Paridah Md Tahir
Wei Chen Lum
Li Peng Tan
Paiman Bawon
Byung-Dae Park
Syeed SaifulAzry Osman Al Edrus
Ummi Hani Abdullah
author_sort Seng Hua Lee
collection DOAJ
description Citric acid (CA) can be found naturally in fruits and vegetables, particularly citrus fruit. CA is widely used in many fields but its usage as a green modifying agent and binder for wood is barely addressed. Esterification is one of the most common chemical reactions applied in wood modification. CA contains three carboxyl groups, making it possible to attain at least two esterification reactions that are required for crosslinking when reacting with the hydroxyl groups of the cell wall polymers. In addition, the reaction could form ester linkages to bring adhesivity and good bonding characteristics, and therefore CA could be used as wood binder too. This paper presents a review concerning the usage of CA as a wood modifying agent and binder. For wood modification, the reaction mechanism between wood and CA and the pros and cons of using CA are discussed. CA and its combination with various reactants and their respective optimum parameters are also compiled in this paper. As for the major wood bonding component, the bonding mechanism and types of wood composites bonded with CA are presented. The best working conditions for the CA in the fabrication of wood-based panels are discussed. In addition, the environmental impacts and future outlook of CA-treated wood and bonded composite are also considered.
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spelling doaj.art-64e4139ce3a242948f17e5b2d480f2882023-11-20T08:20:39ZengMDPI AGPolymers2073-43602020-07-01128169210.3390/polym12081692A Review on Citric Acid as Green Modifying Agent and Binder for WoodSeng Hua Lee0Paridah Md Tahir1Wei Chen Lum2Li Peng Tan3Paiman Bawon4Byung-Dae Park5Syeed SaifulAzry Osman Al Edrus6Ummi Hani Abdullah7Institute of Tropical Forestry and Forest Products (INTROP), Universiti Putra Malaysia, Serdang 43400 UPM, Selangor, MalaysiaInstitute of Tropical Forestry and Forest Products (INTROP), Universiti Putra Malaysia, Serdang 43400 UPM, Selangor, MalaysiaInstitute for Infrastructure Engineering and Sustainable Management (IIESM), Universiti Teknologi MARA, Shah Alam 40450, Selangor, MalaysiaFaculty of Veterinary Medicine, Universiti Malaysia Kelantan, Pengkalan Chepa, Kota Bharu 16100, Kelantan, MalaysiaFaculty of Forestry and Environment, Universiti Putra Malaysia, Serdang 43400 UPM, Selangor, MalaysiaDepartment of Wood and Paper Science, Kyungpook National University, Daegu 41566, KoreaInstitute of Tropical Forestry and Forest Products (INTROP), Universiti Putra Malaysia, Serdang 43400 UPM, Selangor, MalaysiaFaculty of Forestry and Environment, Universiti Putra Malaysia, Serdang 43400 UPM, Selangor, MalaysiaCitric acid (CA) can be found naturally in fruits and vegetables, particularly citrus fruit. CA is widely used in many fields but its usage as a green modifying agent and binder for wood is barely addressed. Esterification is one of the most common chemical reactions applied in wood modification. CA contains three carboxyl groups, making it possible to attain at least two esterification reactions that are required for crosslinking when reacting with the hydroxyl groups of the cell wall polymers. In addition, the reaction could form ester linkages to bring adhesivity and good bonding characteristics, and therefore CA could be used as wood binder too. This paper presents a review concerning the usage of CA as a wood modifying agent and binder. For wood modification, the reaction mechanism between wood and CA and the pros and cons of using CA are discussed. CA and its combination with various reactants and their respective optimum parameters are also compiled in this paper. As for the major wood bonding component, the bonding mechanism and types of wood composites bonded with CA are presented. The best working conditions for the CA in the fabrication of wood-based panels are discussed. In addition, the environmental impacts and future outlook of CA-treated wood and bonded composite are also considered.https://www.mdpi.com/2073-4360/12/8/1692citric acidesterificationbinding agentwood modificationwood composite
spellingShingle Seng Hua Lee
Paridah Md Tahir
Wei Chen Lum
Li Peng Tan
Paiman Bawon
Byung-Dae Park
Syeed SaifulAzry Osman Al Edrus
Ummi Hani Abdullah
A Review on Citric Acid as Green Modifying Agent and Binder for Wood
Polymers
citric acid
esterification
binding agent
wood modification
wood composite
title A Review on Citric Acid as Green Modifying Agent and Binder for Wood
title_full A Review on Citric Acid as Green Modifying Agent and Binder for Wood
title_fullStr A Review on Citric Acid as Green Modifying Agent and Binder for Wood
title_full_unstemmed A Review on Citric Acid as Green Modifying Agent and Binder for Wood
title_short A Review on Citric Acid as Green Modifying Agent and Binder for Wood
title_sort review on citric acid as green modifying agent and binder for wood
topic citric acid
esterification
binding agent
wood modification
wood composite
url https://www.mdpi.com/2073-4360/12/8/1692
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