Synthesis of an ent-Halimanolide from ent-Halimic Acid

An efficient synthesis of ent-halimanolide 2 (15,16-epoxy-12-oxo-ent-halima- 5(10),13(16),14-trien-18,2β-olide), from ent-halimic acid has been achieved, corroborating the structure of the natural compound and establishing its absolute configuration.

Bibliographic Details
Main Authors: Julio G. Urones, Faustino Mollinedo, David Díez, Pilar Basabe, Rosalina F. Moro, Almudena Conde, Isidro S. Marcos
Format: Article
Language:English
Published: MDPI AG 2008-05-01
Series:Molecules
Subjects:
Online Access:http://www.mdpi.com/1420-3049/13/5/1120/
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author Julio G. Urones
Faustino Mollinedo
David Díez
Pilar Basabe
Rosalina F. Moro
Almudena Conde
Isidro S. Marcos
author_facet Julio G. Urones
Faustino Mollinedo
David Díez
Pilar Basabe
Rosalina F. Moro
Almudena Conde
Isidro S. Marcos
author_sort Julio G. Urones
collection DOAJ
description An efficient synthesis of ent-halimanolide 2 (15,16-epoxy-12-oxo-ent-halima- 5(10),13(16),14-trien-18,2β-olide), from ent-halimic acid has been achieved, corroborating the structure of the natural compound and establishing its absolute configuration.
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spelling doaj.art-64e6451492af4c3781021d73775396862022-12-22T02:09:27ZengMDPI AGMolecules1420-30492008-05-011351120113410.3390/molecules13051120Synthesis of an ent-Halimanolide from ent-Halimic AcidJulio G. UronesFaustino MollinedoDavid DíezPilar BasabeRosalina F. MoroAlmudena CondeIsidro S. MarcosAn efficient synthesis of ent-halimanolide 2 (15,16-epoxy-12-oxo-ent-halima- 5(10),13(16),14-trien-18,2β-olide), from ent-halimic acid has been achieved, corroborating the structure of the natural compound and establishing its absolute configuration.http://www.mdpi.com/1420-3049/13/5/1120/Ent-halimanolidesent-halimic acidditerpenoidsCladogynos orientalis.
spellingShingle Julio G. Urones
Faustino Mollinedo
David Díez
Pilar Basabe
Rosalina F. Moro
Almudena Conde
Isidro S. Marcos
Synthesis of an ent-Halimanolide from ent-Halimic Acid
Molecules
Ent-halimanolides
ent-halimic acid
diterpenoids
Cladogynos orientalis.
title Synthesis of an ent-Halimanolide from ent-Halimic Acid
title_full Synthesis of an ent-Halimanolide from ent-Halimic Acid
title_fullStr Synthesis of an ent-Halimanolide from ent-Halimic Acid
title_full_unstemmed Synthesis of an ent-Halimanolide from ent-Halimic Acid
title_short Synthesis of an ent-Halimanolide from ent-Halimic Acid
title_sort synthesis of an ent halimanolide from ent halimic acid
topic Ent-halimanolides
ent-halimic acid
diterpenoids
Cladogynos orientalis.
url http://www.mdpi.com/1420-3049/13/5/1120/
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