Nickel bismuth boride, Ni23-xBixB6[x = 2.44 (1)]

The τ-boride Ni23-xBixB6 [x = 2.44 (1)] adopts a ternary variant of the cubic Cr23C6-type structure, with Ni8 cubes and Ni12 cuboctahedra arranged in a NaCl-type pattern. Two of the four independent metal sites (8c, overline{4}3m symmetry; 4a, moverline{3}m symmetry) are o...

Full description

Bibliographic Details
Main Authors: David Berthebaud, Akira Sato, Takao Mori
Format: Article
Language:English
Published: International Union of Crystallography 2011-02-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536811000894
_version_ 1819104962355920896
author David Berthebaud
Akira Sato
Takao Mori
author_facet David Berthebaud
Akira Sato
Takao Mori
author_sort David Berthebaud
collection DOAJ
description The τ-boride Ni23-xBixB6 [x = 2.44 (1)] adopts a ternary variant of the cubic Cr23C6-type structure, with Ni8 cubes and Ni12 cuboctahedra arranged in a NaCl-type pattern. Two of the four independent metal sites (8c, overline{4}3m symmetry; 4a, moverline{3}m symmetry) are occupied by a mixture of Ni and Bi atoms in a 0.106 (6):0.894 (6) and a 0.350 (7):0.650 (7) ratio, respectively.
first_indexed 2024-12-22T02:14:41Z
format Article
id doaj.art-64e7d48321384e30b30e29a0c270d989
institution Directory Open Access Journal
issn 1600-5368
language English
last_indexed 2024-12-22T02:14:41Z
publishDate 2011-02-01
publisher International Union of Crystallography
record_format Article
series Acta Crystallographica Section E
spelling doaj.art-64e7d48321384e30b30e29a0c270d9892022-12-21T18:42:18ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-02-01672i17i1710.1107/S1600536811000894Nickel bismuth boride, Ni23-xBixB6[x = 2.44 (1)]David BerthebaudAkira SatoTakao MoriThe τ-boride Ni23-xBixB6 [x = 2.44 (1)] adopts a ternary variant of the cubic Cr23C6-type structure, with Ni8 cubes and Ni12 cuboctahedra arranged in a NaCl-type pattern. Two of the four independent metal sites (8c, overline{4}3m symmetry; 4a, moverline{3}m symmetry) are occupied by a mixture of Ni and Bi atoms in a 0.106 (6):0.894 (6) and a 0.350 (7):0.650 (7) ratio, respectively.http://scripts.iucr.org/cgi-bin/paper?S1600536811000894
spellingShingle David Berthebaud
Akira Sato
Takao Mori
Nickel bismuth boride, Ni23-xBixB6[x = 2.44 (1)]
Acta Crystallographica Section E
title Nickel bismuth boride, Ni23-xBixB6[x = 2.44 (1)]
title_full Nickel bismuth boride, Ni23-xBixB6[x = 2.44 (1)]
title_fullStr Nickel bismuth boride, Ni23-xBixB6[x = 2.44 (1)]
title_full_unstemmed Nickel bismuth boride, Ni23-xBixB6[x = 2.44 (1)]
title_short Nickel bismuth boride, Ni23-xBixB6[x = 2.44 (1)]
title_sort nickel bismuth boride ni23 xbixb6 x 2 44 amp 8197 1
url http://scripts.iucr.org/cgi-bin/paper?S1600536811000894
work_keys_str_mv AT davidberthebaud nickelbismuthborideni23xbixb6x244amp81971
AT akirasato nickelbismuthborideni23xbixb6x244amp81971
AT takaomori nickelbismuthborideni23xbixb6x244amp81971