| Summary: | Under the energy crisis and with greenhouse gases causing an ecological imbalance, biofuel has attracted worldwide attention due to its sustainability and low net-carbon emission. For years, the traditional biodiesel industry has been demanding a high-performance solid base catalyst. Its poor reusability is the bottleneck for a promising calcium-based solid-base catalyst. In this work, we successfully adopted a new silicate-strength strategy to improve the stability while preserving the activity of the catalyst. The newly synthesized catalyst, NCSO, had two main catalytic phases, Na<sub>2</sub>CaSiO<sub>4</sub> and CaO, and showed a 98.2% FAMEs yield in 60 min at 80 °C with a methanol/oil molar ratio of 9:1 and 5 wt.% catalyst loading. After 12 consecutive reuses, a 57.3% FAMEs yield could still be achieved. The effect of the reaction temperature, methanol ratio, catalyst loading, and reaction time on the FAMEs yield was also investigated. With a combined characterization of XRD, XPS, and SEM, etc., we confirmed that Na<sub>2</sub>CaSiO<sub>4</sub> and CaO showed a synergistic effect in catalyzing the transesterification reaction: the addition of the Na<sub>2</sub>CaSiO<sub>4</sub> phase in NCSO could significantly improve the activity of CaO, while the CaO phase, in turn, helps to stabilize the Na<sub>2</sub>CaSiO<sub>4</sub> phase. This silicate-strength strategy provides a new route to synthesize stable and highly active solid base catalysts.
|
|---|