Direct Synthesis of Sodalite from Indonesian Kaolin for Adsorption of Pb2+ Solution, Kinetics, and Isotherm Approach

Indonesian kaolin was used as precursor for synthesis of sodalite. Synthesis parameters were optimized by varying the Si/Al ratios, stirring and aging conditions, and water composition. X-ray diffraction (XRD), Fourier Transform Infra Red (FTIR), Scanning Electron Microscope-Energy Dispersive Xray (...

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Main Authors: Tri Wahyuni, Didik Prasetyoko, Suprapto Suprapto, Imroatul Qoniah, Hasliza Bahruji, Ahmad Anwarud Dawam, Sugeng Triwahyono, Aishah Abdul Jalil
Format: Article
Language:English
Published: Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) 2019-12-01
Series:Bulletin of Chemical Reaction Engineering & Catalysis
Subjects:
Online Access:https://journal.bcrec.id/index.php/bcrec/article/view/2939
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author Tri Wahyuni
Didik Prasetyoko
Suprapto Suprapto
Imroatul Qoniah
Hasliza Bahruji
Ahmad Anwarud Dawam
Sugeng Triwahyono
Aishah Abdul Jalil
author_facet Tri Wahyuni
Didik Prasetyoko
Suprapto Suprapto
Imroatul Qoniah
Hasliza Bahruji
Ahmad Anwarud Dawam
Sugeng Triwahyono
Aishah Abdul Jalil
author_sort Tri Wahyuni
collection DOAJ
description Indonesian kaolin was used as precursor for synthesis of sodalite. Synthesis parameters were optimized by varying the Si/Al ratios, stirring and aging conditions, and water composition. X-ray diffraction (XRD), Fourier Transform Infra Red (FTIR), Scanning Electron Microscope-Energy Dispersive Xray (SEM-EDX), and Particle Size Analyzer (PSA) were used to characterize sodalite. The potential of sodalite as adsorbent for heavy metal Pb2+ ions removal from waste water was investigated in this work. The uptake adsorption capacities of sodalite was 90-100 mg/g from synthesized sodalite crystallized for 24 and 48 hours, and commercial silica. The kinetic of Pb2+ adsorption was a pseudo second order reaction and the adsorption coefficients was followed Langmuir adsorption isotherm.
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spelling doaj.art-650f5b0b59924bce88dbd6399ed1368f2023-09-22T03:42:29ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932019-12-0114350251210.9767/bcrec.14.3.2939.502-5122288Direct Synthesis of Sodalite from Indonesian Kaolin for Adsorption of Pb2+ Solution, Kinetics, and Isotherm ApproachTri Wahyuni0Didik Prasetyoko1Suprapto Suprapto2Imroatul Qoniah3Hasliza Bahruji4Ahmad Anwarud Dawam5Sugeng Triwahyono6https://orcid.org/0000-0002-6004-7762Aishah Abdul Jalil7Department of Chemistry, Faculty of Sciences, Institut Teknologi Sepuluh Nopember, Surabaya, IndonesiaDepartment of Chemistry, Faculty of Sciences, Institut Teknologi Sepuluh Nopember, Surabaya, IndonesiaDepartment of Chemistry, Faculty of Sciences, Institut Teknologi Sepuluh Nopember, Surabaya, IndonesiaDepartment of Chemistry, Faculty of Sciences, Institut Teknologi Sepuluh Nopember, Surabaya, IndonesiaCentre of Advanced Material and Energy Sciences, University Brunei Darussalam, Brunei DarussalamDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Institut Teknologi Sepuluh Nopember, Surabaya, IndonesiaIbnu Sina Institute for Fundamental Science Studies, Universiti Teknologi Malaysia, MalaysiaIbnu Sina Institute for Fundamental Science Studies, Universiti Teknologi Malaysia, MalaysiaIndonesian kaolin was used as precursor for synthesis of sodalite. Synthesis parameters were optimized by varying the Si/Al ratios, stirring and aging conditions, and water composition. X-ray diffraction (XRD), Fourier Transform Infra Red (FTIR), Scanning Electron Microscope-Energy Dispersive Xray (SEM-EDX), and Particle Size Analyzer (PSA) were used to characterize sodalite. The potential of sodalite as adsorbent for heavy metal Pb2+ ions removal from waste water was investigated in this work. The uptake adsorption capacities of sodalite was 90-100 mg/g from synthesized sodalite crystallized for 24 and 48 hours, and commercial silica. The kinetic of Pb2+ adsorption was a pseudo second order reaction and the adsorption coefficients was followed Langmuir adsorption isotherm.https://journal.bcrec.id/index.php/bcrec/article/view/2939sodalitekaolinkineticspb2+ adsorptionisotherm
spellingShingle Tri Wahyuni
Didik Prasetyoko
Suprapto Suprapto
Imroatul Qoniah
Hasliza Bahruji
Ahmad Anwarud Dawam
Sugeng Triwahyono
Aishah Abdul Jalil
Direct Synthesis of Sodalite from Indonesian Kaolin for Adsorption of Pb2+ Solution, Kinetics, and Isotherm Approach
Bulletin of Chemical Reaction Engineering & Catalysis
sodalite
kaolin
kinetics
pb2+ adsorption
isotherm
title Direct Synthesis of Sodalite from Indonesian Kaolin for Adsorption of Pb2+ Solution, Kinetics, and Isotherm Approach
title_full Direct Synthesis of Sodalite from Indonesian Kaolin for Adsorption of Pb2+ Solution, Kinetics, and Isotherm Approach
title_fullStr Direct Synthesis of Sodalite from Indonesian Kaolin for Adsorption of Pb2+ Solution, Kinetics, and Isotherm Approach
title_full_unstemmed Direct Synthesis of Sodalite from Indonesian Kaolin for Adsorption of Pb2+ Solution, Kinetics, and Isotherm Approach
title_short Direct Synthesis of Sodalite from Indonesian Kaolin for Adsorption of Pb2+ Solution, Kinetics, and Isotherm Approach
title_sort direct synthesis of sodalite from indonesian kaolin for adsorption of pb2 solution kinetics and isotherm approach
topic sodalite
kaolin
kinetics
pb2+ adsorption
isotherm
url https://journal.bcrec.id/index.php/bcrec/article/view/2939
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