Reductive Hydroformylation of Isosorbide Diallyl Ether
Isosorbide and its functionalized derivatives have numerous applications as bio-sourced building blocks. In this context, the synthesis of diols from isosorbide diallyl ether by hydrohydroxymethylation reaction is of extreme interest. This hydrohydroxymethylation, which consists of carbon-carbon dou...
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| Format: | Article |
| Language: | English |
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MDPI AG
2021-12-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/26/23/7322 |
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| author | Jérémy Ternel Adrien Lopes Mathieu Sauthier Clothilde Buffe Vincent Wiatz Hervé Bricout Sébastien Tilloy Eric Monflier |
| author_facet | Jérémy Ternel Adrien Lopes Mathieu Sauthier Clothilde Buffe Vincent Wiatz Hervé Bricout Sébastien Tilloy Eric Monflier |
| author_sort | Jérémy Ternel |
| collection | DOAJ |
| description | Isosorbide and its functionalized derivatives have numerous applications as bio-sourced building blocks. In this context, the synthesis of diols from isosorbide diallyl ether by hydrohydroxymethylation reaction is of extreme interest. This hydrohydroxymethylation, which consists of carbon-carbon double bonds converting into primary alcohol functions, can be obtained by a hydroformylation reaction followed by a hydrogenation reaction. In this study, reductive hydroformylation was achieved using isosorbide diallyl ether as a substrate in a rhodium/amine catalytic system. The highest yield in bis-primary alcohols obtained was equal to 79%. |
| first_indexed | 2024-03-10T04:47:20Z |
| format | Article |
| id | doaj.art-651414ac53344e8cadd50c33dcc18994 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-10T04:47:20Z |
| publishDate | 2021-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-651414ac53344e8cadd50c33dcc189942023-11-23T02:50:45ZengMDPI AGMolecules1420-30492021-12-012623732210.3390/molecules26237322Reductive Hydroformylation of Isosorbide Diallyl EtherJérémy Ternel0Adrien Lopes1Mathieu Sauthier2Clothilde Buffe3Vincent Wiatz4Hervé Bricout5Sébastien Tilloy6Eric Monflier7University of Artois, CNRS, Centrale Lille, University of Lille, UMR 8181–UCCS–Unité de Catalyse et Chimie du Solide, F-62300 Lens, FranceUniversity of Artois, CNRS, Centrale Lille, University of Lille, UMR 8181–UCCS–Unité de Catalyse et Chimie du Solide, F-62300 Lens, FranceUniversity of Lille, CNRS, Centrale Lille, ENSCL, University of Artois, UMR 8181, Unité de Catalyse et Chimie du Solide, F-59000 Lille, FranceRoquette Frères, 1 Rue de la Haute Loge, F-62136 Lestrem, FranceRoquette Frères, 1 Rue de la Haute Loge, F-62136 Lestrem, FranceUniversity of Artois, CNRS, Centrale Lille, University of Lille, UMR 8181–UCCS–Unité de Catalyse et Chimie du Solide, F-62300 Lens, FranceUniversity of Artois, CNRS, Centrale Lille, University of Lille, UMR 8181–UCCS–Unité de Catalyse et Chimie du Solide, F-62300 Lens, FranceUniversity of Artois, CNRS, Centrale Lille, University of Lille, UMR 8181–UCCS–Unité de Catalyse et Chimie du Solide, F-62300 Lens, FranceIsosorbide and its functionalized derivatives have numerous applications as bio-sourced building blocks. In this context, the synthesis of diols from isosorbide diallyl ether by hydrohydroxymethylation reaction is of extreme interest. This hydrohydroxymethylation, which consists of carbon-carbon double bonds converting into primary alcohol functions, can be obtained by a hydroformylation reaction followed by a hydrogenation reaction. In this study, reductive hydroformylation was achieved using isosorbide diallyl ether as a substrate in a rhodium/amine catalytic system. The highest yield in bis-primary alcohols obtained was equal to 79%.https://www.mdpi.com/1420-3049/26/23/7322catalysishydroformylationhydrogenationrhodiumtandem reaction |
| spellingShingle | Jérémy Ternel Adrien Lopes Mathieu Sauthier Clothilde Buffe Vincent Wiatz Hervé Bricout Sébastien Tilloy Eric Monflier Reductive Hydroformylation of Isosorbide Diallyl Ether Molecules catalysis hydroformylation hydrogenation rhodium tandem reaction |
| title | Reductive Hydroformylation of Isosorbide Diallyl Ether |
| title_full | Reductive Hydroformylation of Isosorbide Diallyl Ether |
| title_fullStr | Reductive Hydroformylation of Isosorbide Diallyl Ether |
| title_full_unstemmed | Reductive Hydroformylation of Isosorbide Diallyl Ether |
| title_short | Reductive Hydroformylation of Isosorbide Diallyl Ether |
| title_sort | reductive hydroformylation of isosorbide diallyl ether |
| topic | catalysis hydroformylation hydrogenation rhodium tandem reaction |
| url | https://www.mdpi.com/1420-3049/26/23/7322 |
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