Summary: | The utilization of solar energy into electrochemical reduction systems has received considerable attention. Most of these attempts have been conducted in a single electrolyte without a membrane. Here, we report the system combined by the electrochemical CO<sub>2</sub> reduction on the Au dendrite electrode and the water oxidation on the Co-Pi electrode with a Nafion membrane. An efficient reduction of CO<sub>2</sub> to CO in the cathode using the proton from water oxidation in the anode is conducted using perovskite solar cells under 1 sun condition. The sustainable reaction condition is secured by balancing each reaction rate based on products analysis. Through this system, we collect reduction products such as CO and H<sub>2</sub> and oxidation product, O<sub>2</sub>, separately. Employing separation of each electrode system and series-connected perovskite solar cells, we achieve 8% of solar to fuel efficiency with 85% of CO selectivity under 1 sun illumination.
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