Facile synthesis of ammonium trivanadate(V)/nitrogen doped carbon composites with high catalytic activity for the selective oxidation of 5-hydroxymethylfurfural
2,5-Diformylfuran (DFF), arising as an oxidation product of 5-hydroxymethylfurfural (HMF), has garnered significant interest owing to its versatile range of applications. In this study, the desired catalyst of NH4V3O8/N-C was successfully prepared and investigated by various characterization methods...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Elsevier
2023-11-01
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| Series: | Catalysis Communications |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S1566736723001942 |
| _version_ | 1797449488849174528 |
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| author | Shuolin Zhou Jian Liu Sha Wen Li Yang Qiong Xu Dulin Yin Xianxiang Liu |
| author_facet | Shuolin Zhou Jian Liu Sha Wen Li Yang Qiong Xu Dulin Yin Xianxiang Liu |
| author_sort | Shuolin Zhou |
| collection | DOAJ |
| description | 2,5-Diformylfuran (DFF), arising as an oxidation product of 5-hydroxymethylfurfural (HMF), has garnered significant interest owing to its versatile range of applications. In this study, the desired catalyst of NH4V3O8/N-C was successfully prepared and investigated by various characterization methods. A systematic effect of reaction conditions was conducted, revealing that under 5 bar of oxygen pressure, DFF was synthesized from HMF selective oxidation using the NH4V3O8/N-C catalyst. This transformation was achieved within 2 h at 120 °C, exhibiting an impressive DFF selectivity of 97.8%. During the recycling experiment, the catalytic efficiency remained consistently high even after being employed for eight cycles. |
| first_indexed | 2024-03-09T14:25:48Z |
| format | Article |
| id | doaj.art-6541fede9c6b4cd199f7b789692d8ec1 |
| institution | Directory Open Access Journal |
| issn | 1873-3905 |
| language | English |
| last_indexed | 2024-03-09T14:25:48Z |
| publishDate | 2023-11-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Catalysis Communications |
| spelling | doaj.art-6541fede9c6b4cd199f7b789692d8ec12023-11-28T07:25:32ZengElsevierCatalysis Communications1873-39052023-11-01184106792Facile synthesis of ammonium trivanadate(V)/nitrogen doped carbon composites with high catalytic activity for the selective oxidation of 5-hydroxymethylfurfuralShuolin Zhou0Jian Liu1Sha Wen2Li Yang3Qiong Xu4Dulin Yin5Xianxiang Liu6Changsha Normal University, Changsha 410100, China; Corresponding authors.National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Hunan Normal University, Changsha 410081, ChinaNational & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Hunan Normal University, Changsha 410081, ChinaNational & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Hunan Normal University, Changsha 410081, ChinaNational & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Hunan Normal University, Changsha 410081, ChinaNational & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Hunan Normal University, Changsha 410081, China; Corresponding authors.National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Hunan Normal University, Changsha 410081, China; Corresponding authors.2,5-Diformylfuran (DFF), arising as an oxidation product of 5-hydroxymethylfurfural (HMF), has garnered significant interest owing to its versatile range of applications. In this study, the desired catalyst of NH4V3O8/N-C was successfully prepared and investigated by various characterization methods. A systematic effect of reaction conditions was conducted, revealing that under 5 bar of oxygen pressure, DFF was synthesized from HMF selective oxidation using the NH4V3O8/N-C catalyst. This transformation was achieved within 2 h at 120 °C, exhibiting an impressive DFF selectivity of 97.8%. During the recycling experiment, the catalytic efficiency remained consistently high even after being employed for eight cycles.http://www.sciencedirect.com/science/article/pii/S1566736723001942Nitrogen-doped carbonAmmonium trivanadate5-Hydroxymethylfurfural2, 5-DiformylfuranSelective oxidation |
| spellingShingle | Shuolin Zhou Jian Liu Sha Wen Li Yang Qiong Xu Dulin Yin Xianxiang Liu Facile synthesis of ammonium trivanadate(V)/nitrogen doped carbon composites with high catalytic activity for the selective oxidation of 5-hydroxymethylfurfural Catalysis Communications Nitrogen-doped carbon Ammonium trivanadate 5-Hydroxymethylfurfural 2, 5-Diformylfuran Selective oxidation |
| title | Facile synthesis of ammonium trivanadate(V)/nitrogen doped carbon composites with high catalytic activity for the selective oxidation of 5-hydroxymethylfurfural |
| title_full | Facile synthesis of ammonium trivanadate(V)/nitrogen doped carbon composites with high catalytic activity for the selective oxidation of 5-hydroxymethylfurfural |
| title_fullStr | Facile synthesis of ammonium trivanadate(V)/nitrogen doped carbon composites with high catalytic activity for the selective oxidation of 5-hydroxymethylfurfural |
| title_full_unstemmed | Facile synthesis of ammonium trivanadate(V)/nitrogen doped carbon composites with high catalytic activity for the selective oxidation of 5-hydroxymethylfurfural |
| title_short | Facile synthesis of ammonium trivanadate(V)/nitrogen doped carbon composites with high catalytic activity for the selective oxidation of 5-hydroxymethylfurfural |
| title_sort | facile synthesis of ammonium trivanadate v nitrogen doped carbon composites with high catalytic activity for the selective oxidation of 5 hydroxymethylfurfural |
| topic | Nitrogen-doped carbon Ammonium trivanadate 5-Hydroxymethylfurfural 2, 5-Diformylfuran Selective oxidation |
| url | http://www.sciencedirect.com/science/article/pii/S1566736723001942 |
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