Synthesis and Spectroscopic Studies of Mixed Ligand Complexes of Pt(II) and Pd(II) with Ethyl-α-Isonitrosoacetoacetate and Dienes
The mixed ligand complexes of the kind [M(L1) (L2)] where M= Pt(II), Pd(II).L1 = primary ligand ethyl-α-isonitrosoacetoacetate derived from reaction between ethyl acetoacetate, acetic acid and sodium nitrite and L2=secondary ligand para-phenyldiamine (PPD) are synthesized. All the prepared complexes...
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| Format: | Article |
| Language: | English |
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Universidade Federal de Mato Grosso do Sul
2015-12-01
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| Series: | Orbital: The Electronic Journal of Chemistry |
| Subjects: | |
| Online Access: | https://periodicos.ufms.br/index.php/orbital/article/view/17842 |
| _version_ | 1797946774639345664 |
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| author | Anita Krishankant Taksande Ravishankar D. Raut Mahendra D. Choudhary |
| author_facet | Anita Krishankant Taksande Ravishankar D. Raut Mahendra D. Choudhary |
| author_sort | Anita Krishankant Taksande |
| collection | DOAJ |
| description | The mixed ligand complexes of the kind [M(L1) (L2)] where M= Pt(II), Pd(II).L1 = primary ligand ethyl-α-isonitrosoacetoacetate derived from reaction between ethyl acetoacetate, acetic acid and sodium nitrite and L2=secondary ligand para-phenyldiamine (PPD) are synthesized. All the prepared complexes were identified and confirmed by elemental analysis, molar conductance measurements, and infrared electronic absorption. Their complexes has been made based on elemental analysis, molar conductivity, UV-Vis, FT-IR and 1HNMR spectroscopy and magnetic moment measurements as well as thermal analysis (TGA and DTA). The elemental analysis information recommends that the stoichiometry of the complexes to be 1:2:1. The molar conductance measurements of the complexes indicate their non-electrolytic nature. The infrared spectral information showed the coordination sites of the free ligand with the central metal particle. The electronic absorption spectral information disclosed the existence of an octahedral geometry for Pt(II) and Pd(II) complexes.
DOI: http://dx.doi.org/10.17807/orbital.v7i4.633
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| first_indexed | 2024-04-10T21:17:25Z |
| format | Article |
| id | doaj.art-654d9d4d7f6a40bd924c8beb08faeb2a |
| institution | Directory Open Access Journal |
| issn | 1984-6428 |
| language | English |
| last_indexed | 2024-04-10T21:17:25Z |
| publishDate | 2015-12-01 |
| publisher | Universidade Federal de Mato Grosso do Sul |
| record_format | Article |
| series | Orbital: The Electronic Journal of Chemistry |
| spelling | doaj.art-654d9d4d7f6a40bd924c8beb08faeb2a2023-01-20T11:03:04ZengUniversidade Federal de Mato Grosso do SulOrbital: The Electronic Journal of Chemistry1984-64282015-12-0174Synthesis and Spectroscopic Studies of Mixed Ligand Complexes of Pt(II) and Pd(II) with Ethyl-α-Isonitrosoacetoacetate and DienesAnita Krishankant Taksande0Ravishankar D. Raut1Mahendra D. Choudhary2Department of chemistry , SDCE, Selukate , WardhaDepartment of chemistry J.B. Science College Wardha MaharastraDepartment of chemistry BDCE Sevagram,Wardha MaharashtraThe mixed ligand complexes of the kind [M(L1) (L2)] where M= Pt(II), Pd(II).L1 = primary ligand ethyl-α-isonitrosoacetoacetate derived from reaction between ethyl acetoacetate, acetic acid and sodium nitrite and L2=secondary ligand para-phenyldiamine (PPD) are synthesized. All the prepared complexes were identified and confirmed by elemental analysis, molar conductance measurements, and infrared electronic absorption. Their complexes has been made based on elemental analysis, molar conductivity, UV-Vis, FT-IR and 1HNMR spectroscopy and magnetic moment measurements as well as thermal analysis (TGA and DTA). The elemental analysis information recommends that the stoichiometry of the complexes to be 1:2:1. The molar conductance measurements of the complexes indicate their non-electrolytic nature. The infrared spectral information showed the coordination sites of the free ligand with the central metal particle. The electronic absorption spectral information disclosed the existence of an octahedral geometry for Pt(II) and Pd(II) complexes. DOI: http://dx.doi.org/10.17807/orbital.v7i4.633 https://periodicos.ufms.br/index.php/orbital/article/view/17842mixed ligandethyl-α- isonitrosoacetoacetatePt(II)Pd(II) |
| spellingShingle | Anita Krishankant Taksande Ravishankar D. Raut Mahendra D. Choudhary Synthesis and Spectroscopic Studies of Mixed Ligand Complexes of Pt(II) and Pd(II) with Ethyl-α-Isonitrosoacetoacetate and Dienes Orbital: The Electronic Journal of Chemistry mixed ligand ethyl-α- isonitrosoacetoacetate Pt(II) Pd(II) |
| title | Synthesis and Spectroscopic Studies of Mixed Ligand Complexes of Pt(II) and Pd(II) with Ethyl-α-Isonitrosoacetoacetate and Dienes |
| title_full | Synthesis and Spectroscopic Studies of Mixed Ligand Complexes of Pt(II) and Pd(II) with Ethyl-α-Isonitrosoacetoacetate and Dienes |
| title_fullStr | Synthesis and Spectroscopic Studies of Mixed Ligand Complexes of Pt(II) and Pd(II) with Ethyl-α-Isonitrosoacetoacetate and Dienes |
| title_full_unstemmed | Synthesis and Spectroscopic Studies of Mixed Ligand Complexes of Pt(II) and Pd(II) with Ethyl-α-Isonitrosoacetoacetate and Dienes |
| title_short | Synthesis and Spectroscopic Studies of Mixed Ligand Complexes of Pt(II) and Pd(II) with Ethyl-α-Isonitrosoacetoacetate and Dienes |
| title_sort | synthesis and spectroscopic studies of mixed ligand complexes of pt ii and pd ii with ethyl α isonitrosoacetoacetate and dienes |
| topic | mixed ligand ethyl-α- isonitrosoacetoacetate Pt(II) Pd(II) |
| url | https://periodicos.ufms.br/index.php/orbital/article/view/17842 |
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