Three-component reactions of kojic acid: Efficient synthesis of Dihydropyrano[3,2-b]chromenediones and aminopyranopyrans catalyzed with Nano-Bi2O3-ZnO and Nano-ZnO

Synthesis of pyrano-chromenes and pyrano-pyrans was developed by three-component reactions of kojic acid and aromatic aldehydes with dimethone and malononitrile, catalyzed with nano-Bi2O3-ZnO and nano-ZnO, respectively. Reactions proceeded smoothly and the corresponding heterocyclic products were ob...

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Main Authors: Maryam Zirak, Mostafa Azinfar, Mosleh Khalili
Format: Article
Language:English
Published: Growing Science 2017-05-01
Series:Current Chemistry Letters
Subjects:
Online Access:http://www.growingscience.com/ccl/Vol6/ccl_2017_6.pdf
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author Maryam Zirak
Mostafa Azinfar
Mosleh Khalili
author_facet Maryam Zirak
Mostafa Azinfar
Mosleh Khalili
author_sort Maryam Zirak
collection DOAJ
description Synthesis of pyrano-chromenes and pyrano-pyrans was developed by three-component reactions of kojic acid and aromatic aldehydes with dimethone and malononitrile, catalyzed with nano-Bi2O3-ZnO and nano-ZnO, respectively. Reactions proceeded smoothly and the corresponding heterocyclic products were obtained in good to high yields. Nano ZnO and nano Bi2O3-ZnO were prepared by sol-gel method and characterized by X-ray diffraction (XRD), energy-dispersive X-ray analysis (EDX), Fourier transform infrared (FT-IR), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) techniques. Supporting Bi3+ on ZnO nanoparticles as Bi2O3, is the main novelty of this work. The simple reaction procedure, easy separation of products, low catalyst loading, reusability of the catalyst are some advantageous of this protocol.
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spelling doaj.art-657bc031e00e4815b457a582737fa44a2022-12-22T03:55:37ZengGrowing ScienceCurrent Chemistry Letters1927-72961927-730X2017-05-016310511610.5267/j.ccl.2017.4.001Three-component reactions of kojic acid: Efficient synthesis of Dihydropyrano[3,2-b]chromenediones and aminopyranopyrans catalyzed with Nano-Bi2O3-ZnO and Nano-ZnOMaryam ZirakMostafa AzinfarMosleh Khalili Synthesis of pyrano-chromenes and pyrano-pyrans was developed by three-component reactions of kojic acid and aromatic aldehydes with dimethone and malononitrile, catalyzed with nano-Bi2O3-ZnO and nano-ZnO, respectively. Reactions proceeded smoothly and the corresponding heterocyclic products were obtained in good to high yields. Nano ZnO and nano Bi2O3-ZnO were prepared by sol-gel method and characterized by X-ray diffraction (XRD), energy-dispersive X-ray analysis (EDX), Fourier transform infrared (FT-IR), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) techniques. Supporting Bi3+ on ZnO nanoparticles as Bi2O3, is the main novelty of this work. The simple reaction procedure, easy separation of products, low catalyst loading, reusability of the catalyst are some advantageous of this protocol.http://www.growingscience.com/ccl/Vol6/ccl_2017_6.pdfKojic acidHeterogeneous catalysisMulticomponent reactionSolvent-freeNano-ZnO
spellingShingle Maryam Zirak
Mostafa Azinfar
Mosleh Khalili
Three-component reactions of kojic acid: Efficient synthesis of Dihydropyrano[3,2-b]chromenediones and aminopyranopyrans catalyzed with Nano-Bi2O3-ZnO and Nano-ZnO
Current Chemistry Letters
Kojic acid
Heterogeneous catalysis
Multicomponent reaction
Solvent-free
Nano-ZnO
title Three-component reactions of kojic acid: Efficient synthesis of Dihydropyrano[3,2-b]chromenediones and aminopyranopyrans catalyzed with Nano-Bi2O3-ZnO and Nano-ZnO
title_full Three-component reactions of kojic acid: Efficient synthesis of Dihydropyrano[3,2-b]chromenediones and aminopyranopyrans catalyzed with Nano-Bi2O3-ZnO and Nano-ZnO
title_fullStr Three-component reactions of kojic acid: Efficient synthesis of Dihydropyrano[3,2-b]chromenediones and aminopyranopyrans catalyzed with Nano-Bi2O3-ZnO and Nano-ZnO
title_full_unstemmed Three-component reactions of kojic acid: Efficient synthesis of Dihydropyrano[3,2-b]chromenediones and aminopyranopyrans catalyzed with Nano-Bi2O3-ZnO and Nano-ZnO
title_short Three-component reactions of kojic acid: Efficient synthesis of Dihydropyrano[3,2-b]chromenediones and aminopyranopyrans catalyzed with Nano-Bi2O3-ZnO and Nano-ZnO
title_sort three component reactions of kojic acid efficient synthesis of dihydropyrano 3 2 b chromenediones and aminopyranopyrans catalyzed with nano bi2o3 zno and nano zno
topic Kojic acid
Heterogeneous catalysis
Multicomponent reaction
Solvent-free
Nano-ZnO
url http://www.growingscience.com/ccl/Vol6/ccl_2017_6.pdf
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AT mostafaazinfar threecomponentreactionsofkojicacidefficientsynthesisofdihydropyrano32bchromenedionesandaminopyranopyranscatalyzedwithnanobi2o3znoandnanozno
AT moslehkhalili threecomponentreactionsofkojicacidefficientsynthesisofdihydropyrano32bchromenedionesandaminopyranopyranscatalyzedwithnanobi2o3znoandnanozno