Correlation between Nonlinear Optical Effects and Structural Features of Aurone-Based Methacrylic Polymeric Thin Films
In this study, new photonics architectures and aurone-based methacrylic polymers were designed and synthesized for their optical and nonlinear optical properties. The studied polymeric thin films were deposited by spin coating method. SHG and THG effects were measured via Maker fringe technique in t...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-09-01
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| Series: | Materials |
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| Online Access: | https://www.mdpi.com/1996-1944/15/17/6076 |
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| author | Karolina Waszkowska Anastasiia Krupka Vitaliy Smokal Oksana Kharchenko Anna Migalska-Zalas Mykhaylo Frasinyuk Robert Wielgosz Anatoliy Andrushchak Bouchta Sahraoui |
| author_facet | Karolina Waszkowska Anastasiia Krupka Vitaliy Smokal Oksana Kharchenko Anna Migalska-Zalas Mykhaylo Frasinyuk Robert Wielgosz Anatoliy Andrushchak Bouchta Sahraoui |
| author_sort | Karolina Waszkowska |
| collection | DOAJ |
| description | In this study, new photonics architectures and aurone-based methacrylic polymers were designed and synthesized for their optical and nonlinear optical properties. The studied polymeric thin films were deposited by spin coating method. SHG and THG effects were measured via Maker fringe technique in transmission mode and determined using theoretical models. Investigations involved the theoretical quantum chemical calculation of dipole moments, frontier molecular orbital HOMO and LUMO energies, and first (β) and second (γ) hyperpolarizabilities. We determined the impact of the substitution in the para position of the phenyl ring and at the dipole moment of the chromophore on the nonlinear optical properties of the investigated polymers. The presented theoretical and experimental studies provide important information with respect to the design of methacrylic-based polymeric thin film devices and supplement existing knowledge with respect to their nonlinear behaviour. |
| first_indexed | 2024-03-10T01:34:33Z |
| format | Article |
| id | doaj.art-6586ef9df0934486bf40ccb5dbc8c204 |
| institution | Directory Open Access Journal |
| issn | 1996-1944 |
| language | English |
| last_indexed | 2024-03-10T01:34:33Z |
| publishDate | 2022-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Materials |
| spelling | doaj.art-6586ef9df0934486bf40ccb5dbc8c2042023-11-23T13:35:10ZengMDPI AGMaterials1996-19442022-09-011517607610.3390/ma15176076Correlation between Nonlinear Optical Effects and Structural Features of Aurone-Based Methacrylic Polymeric Thin FilmsKarolina Waszkowska0Anastasiia Krupka1Vitaliy Smokal2Oksana Kharchenko3Anna Migalska-Zalas4Mykhaylo Frasinyuk5Robert Wielgosz6Anatoliy Andrushchak7Bouchta Sahraoui8Laboratory MOLTECH-Anjou, University of Angers, CNRS UMR 6200, 2 Bd Lavoisier, CEDEX 01, 49045 Angers, FranceFaculty of Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska, 01033 Kiev, UkraineFaculty of Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska, 01033 Kiev, UkraineFaculty of Chemistry, Taras Shevchenko National University of Kyiv, 60 Volodymyrska, 01033 Kiev, UkraineFaculty of Science and Technology, Jan Długosz University in Częstochowa, Al. Armii Krajowej 13/15, 42-201 Częstochowa, PolandV.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry, National Academy of Sciences of Ukraine, 1 Murmanskaya St., 02094 Kiev, UkraineEnergia Oze Sp. z o.o., ul. Częstochowska 7, 42-274 Konopiska, PolandDepartment of Applied Physics and Nanomaterials Science, Lviv Polytechnic National University, 12 Bandery Street, 79013 Lviv, UkraineLPHIA, SFR MATRIX, University of Angers, 49000 Angers, FranceIn this study, new photonics architectures and aurone-based methacrylic polymers were designed and synthesized for their optical and nonlinear optical properties. The studied polymeric thin films were deposited by spin coating method. SHG and THG effects were measured via Maker fringe technique in transmission mode and determined using theoretical models. Investigations involved the theoretical quantum chemical calculation of dipole moments, frontier molecular orbital HOMO and LUMO energies, and first (β) and second (γ) hyperpolarizabilities. We determined the impact of the substitution in the para position of the phenyl ring and at the dipole moment of the chromophore on the nonlinear optical properties of the investigated polymers. The presented theoretical and experimental studies provide important information with respect to the design of methacrylic-based polymeric thin film devices and supplement existing knowledge with respect to their nonlinear behaviour.https://www.mdpi.com/1996-1944/15/17/6076methacrylic polymersaurone-containing polymerssecond harmonic generationthird harmonic generationnonlinear optical susceptibilityfirst (β) and second (γ) hyperpolarizabilities |
| spellingShingle | Karolina Waszkowska Anastasiia Krupka Vitaliy Smokal Oksana Kharchenko Anna Migalska-Zalas Mykhaylo Frasinyuk Robert Wielgosz Anatoliy Andrushchak Bouchta Sahraoui Correlation between Nonlinear Optical Effects and Structural Features of Aurone-Based Methacrylic Polymeric Thin Films Materials methacrylic polymers aurone-containing polymers second harmonic generation third harmonic generation nonlinear optical susceptibility first (β) and second (γ) hyperpolarizabilities |
| title | Correlation between Nonlinear Optical Effects and Structural Features of Aurone-Based Methacrylic Polymeric Thin Films |
| title_full | Correlation between Nonlinear Optical Effects and Structural Features of Aurone-Based Methacrylic Polymeric Thin Films |
| title_fullStr | Correlation between Nonlinear Optical Effects and Structural Features of Aurone-Based Methacrylic Polymeric Thin Films |
| title_full_unstemmed | Correlation between Nonlinear Optical Effects and Structural Features of Aurone-Based Methacrylic Polymeric Thin Films |
| title_short | Correlation between Nonlinear Optical Effects and Structural Features of Aurone-Based Methacrylic Polymeric Thin Films |
| title_sort | correlation between nonlinear optical effects and structural features of aurone based methacrylic polymeric thin films |
| topic | methacrylic polymers aurone-containing polymers second harmonic generation third harmonic generation nonlinear optical susceptibility first (β) and second (γ) hyperpolarizabilities |
| url | https://www.mdpi.com/1996-1944/15/17/6076 |
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