[1,4-Phenylenebis(methylene)]bis(triphenylphosphonium) bis(tetrafluoroborate)
The crystal structure of the title salt, C44H38P22+2BF4−, consists of discrete dications interlaced with the BF4− counter-ions. In each cation, both phosphonium groups lie on the same side of the plane of the central benzene ring. The tetrafluoroborate anions are involved...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2011-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811048975 |
| _version_ | 1828429341766189056 |
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| author | Hamisu Ibrahim Neil Koorbanally Deresh Ramjugernath Muhammad D. Bala Vincent O. Nyamori |
| author_facet | Hamisu Ibrahim Neil Koorbanally Deresh Ramjugernath Muhammad D. Bala Vincent O. Nyamori |
| author_sort | Hamisu Ibrahim |
| collection | DOAJ |
| description | The crystal structure of the title salt, C44H38P22+2BF4−, consists of discrete dications interlaced with the BF4− counter-ions. In each cation, both phosphonium groups lie on the same side of the plane of the central benzene ring. The tetrafluoroborate anions are involved in intensive thermal motion, thus some B—F bond lengths [range 1.329 (6) to 1.391 (6) Å] deviate significantly from their standard values. |
| first_indexed | 2024-12-10T17:31:54Z |
| format | Article |
| id | doaj.art-659876a15fcd454cabf9ff91de9509fd |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T17:31:54Z |
| publishDate | 2011-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-659876a15fcd454cabf9ff91de9509fd2022-12-22T01:39:39ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-12-016712o3391o339110.1107/S1600536811048975[1,4-Phenylenebis(methylene)]bis(triphenylphosphonium) bis(tetrafluoroborate)Hamisu IbrahimNeil KoorbanallyDeresh RamjugernathMuhammad D. BalaVincent O. NyamoriThe crystal structure of the title salt, C44H38P22+2BF4−, consists of discrete dications interlaced with the BF4− counter-ions. In each cation, both phosphonium groups lie on the same side of the plane of the central benzene ring. The tetrafluoroborate anions are involved in intensive thermal motion, thus some B—F bond lengths [range 1.329 (6) to 1.391 (6) Å] deviate significantly from their standard values.http://scripts.iucr.org/cgi-bin/paper?S1600536811048975 |
| spellingShingle | Hamisu Ibrahim Neil Koorbanally Deresh Ramjugernath Muhammad D. Bala Vincent O. Nyamori [1,4-Phenylenebis(methylene)]bis(triphenylphosphonium) bis(tetrafluoroborate) Acta Crystallographica Section E |
| title | [1,4-Phenylenebis(methylene)]bis(triphenylphosphonium) bis(tetrafluoroborate) |
| title_full | [1,4-Phenylenebis(methylene)]bis(triphenylphosphonium) bis(tetrafluoroborate) |
| title_fullStr | [1,4-Phenylenebis(methylene)]bis(triphenylphosphonium) bis(tetrafluoroborate) |
| title_full_unstemmed | [1,4-Phenylenebis(methylene)]bis(triphenylphosphonium) bis(tetrafluoroborate) |
| title_short | [1,4-Phenylenebis(methylene)]bis(triphenylphosphonium) bis(tetrafluoroborate) |
| title_sort | 1 4 phenylenebis methylene bis triphenylphosphonium bis tetrafluoroborate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811048975 |
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