Tetrakis(acetonitrile)copper(I) hydrogen oxalate–oxalic acid–acetonitrile (1/0.5/0.5)
In the title compound, [Cu(CH3CN)4](C2HO4)·0.5C2H2O4·0.5CH3CN, the CuI ion is coordinated by the N atoms of four acetonitrile ligands in a slightly distorted tetrahedral environment. The oxalic acid molecule lies across an inversion center. The acetonitrile solvent molecule is diso...
| Main Authors: | , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2013-10-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813024914 |
| _version_ | 1819110813309337600 |
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| author | A. Timothy Royappa Jacob R. Stepherson Oliver D. Vu Andrew D. Royappa Charlotte L. Stern Peter Müller |
| author_facet | A. Timothy Royappa Jacob R. Stepherson Oliver D. Vu Andrew D. Royappa Charlotte L. Stern Peter Müller |
| author_sort | A. Timothy Royappa |
| collection | DOAJ |
| description | In the title compound, [Cu(CH3CN)4](C2HO4)·0.5C2H2O4·0.5CH3CN, the CuI ion is coordinated by the N atoms of four acetonitrile ligands in a slightly distorted tetrahedral environment. The oxalic acid molecule lies across an inversion center. The acetonitrile solvent molecule is disordered across an inversion center and was refined with half occupancy. In the crystal, the hydrogen oxalate anions and oxalic acid molecules are linked via O—H...O hydrogen bonds, forming chains along [010]. |
| first_indexed | 2024-12-22T03:47:41Z |
| format | Article |
| id | doaj.art-659a52a2cca94cc3a5e4ab8fda459ffb |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T03:47:41Z |
| publishDate | 2013-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-659a52a2cca94cc3a5e4ab8fda459ffb2022-12-21T18:40:05ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-10-016910m544m54410.1107/S1600536813024914Tetrakis(acetonitrile)copper(I) hydrogen oxalate–oxalic acid–acetonitrile (1/0.5/0.5)A. Timothy RoyappaJacob R. StephersonOliver D. VuAndrew D. RoyappaCharlotte L. SternPeter MüllerIn the title compound, [Cu(CH3CN)4](C2HO4)·0.5C2H2O4·0.5CH3CN, the CuI ion is coordinated by the N atoms of four acetonitrile ligands in a slightly distorted tetrahedral environment. The oxalic acid molecule lies across an inversion center. The acetonitrile solvent molecule is disordered across an inversion center and was refined with half occupancy. In the crystal, the hydrogen oxalate anions and oxalic acid molecules are linked via O—H...O hydrogen bonds, forming chains along [010].http://scripts.iucr.org/cgi-bin/paper?S1600536813024914 |
| spellingShingle | A. Timothy Royappa Jacob R. Stepherson Oliver D. Vu Andrew D. Royappa Charlotte L. Stern Peter Müller Tetrakis(acetonitrile)copper(I) hydrogen oxalate–oxalic acid–acetonitrile (1/0.5/0.5) Acta Crystallographica Section E |
| title | Tetrakis(acetonitrile)copper(I) hydrogen oxalate–oxalic acid–acetonitrile (1/0.5/0.5) |
| title_full | Tetrakis(acetonitrile)copper(I) hydrogen oxalate–oxalic acid–acetonitrile (1/0.5/0.5) |
| title_fullStr | Tetrakis(acetonitrile)copper(I) hydrogen oxalate–oxalic acid–acetonitrile (1/0.5/0.5) |
| title_full_unstemmed | Tetrakis(acetonitrile)copper(I) hydrogen oxalate–oxalic acid–acetonitrile (1/0.5/0.5) |
| title_short | Tetrakis(acetonitrile)copper(I) hydrogen oxalate–oxalic acid–acetonitrile (1/0.5/0.5) |
| title_sort | tetrakis acetonitrile copper i hydrogen oxalate 8211 oxalic acid 8211 acetonitrile 1 0 5 0 5 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813024914 |
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