Extensibility governs the flow-induced alignment of polymers and rod-like colloids

Polymers and rod-like colloids (PaRC) adopt a favorable orientation under sufficiently strong flows. However, how the flow kinematics affect the alignment of such nanostructures according to their extensibility remains unclear. By analyzing the shear- and extension-induced alignment of chemically an...

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Bibliographic Details
Main Authors: Vincenzo Calabrese, Tatiana Porto Santos, Carlos G. Lopez, Minne Paul Lettinga, Simon J. Haward, Amy Q. Shen
Format: Article
Language:English
Published: American Physical Society 2024-02-01
Series:Physical Review Research
Online Access:http://doi.org/10.1103/PhysRevResearch.6.L012042
Description
Summary:Polymers and rod-like colloids (PaRC) adopt a favorable orientation under sufficiently strong flows. However, how the flow kinematics affect the alignment of such nanostructures according to their extensibility remains unclear. By analyzing the shear- and extension-induced alignment of chemically and structurally different PaRC, we show that extensibility is a key determinant of the structural response to the imposed kinematics. We propose a unified description of the effectiveness of extensional flow, compared to shearing flow, at aligning PaRC of different extensibility.
ISSN:2643-1564