Extensibility governs the flow-induced alignment of polymers and rod-like colloids
Polymers and rod-like colloids (PaRC) adopt a favorable orientation under sufficiently strong flows. However, how the flow kinematics affect the alignment of such nanostructures according to their extensibility remains unclear. By analyzing the shear- and extension-induced alignment of chemically an...
Main Authors: | , , , , , |
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Format: | Article |
Language: | English |
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American Physical Society
2024-02-01
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Series: | Physical Review Research |
Online Access: | http://doi.org/10.1103/PhysRevResearch.6.L012042 |
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author | Vincenzo Calabrese Tatiana Porto Santos Carlos G. Lopez Minne Paul Lettinga Simon J. Haward Amy Q. Shen |
author_facet | Vincenzo Calabrese Tatiana Porto Santos Carlos G. Lopez Minne Paul Lettinga Simon J. Haward Amy Q. Shen |
author_sort | Vincenzo Calabrese |
collection | DOAJ |
description | Polymers and rod-like colloids (PaRC) adopt a favorable orientation under sufficiently strong flows. However, how the flow kinematics affect the alignment of such nanostructures according to their extensibility remains unclear. By analyzing the shear- and extension-induced alignment of chemically and structurally different PaRC, we show that extensibility is a key determinant of the structural response to the imposed kinematics. We propose a unified description of the effectiveness of extensional flow, compared to shearing flow, at aligning PaRC of different extensibility. |
first_indexed | 2024-04-24T10:07:21Z |
format | Article |
id | doaj.art-65d6174503194274a14db5369055d0ff |
institution | Directory Open Access Journal |
issn | 2643-1564 |
language | English |
last_indexed | 2024-04-24T10:07:21Z |
publishDate | 2024-02-01 |
publisher | American Physical Society |
record_format | Article |
series | Physical Review Research |
spelling | doaj.art-65d6174503194274a14db5369055d0ff2024-04-12T17:39:40ZengAmerican Physical SocietyPhysical Review Research2643-15642024-02-0161L01204210.1103/PhysRevResearch.6.L012042Extensibility governs the flow-induced alignment of polymers and rod-like colloidsVincenzo CalabreseTatiana Porto SantosCarlos G. LopezMinne Paul LettingaSimon J. HawardAmy Q. ShenPolymers and rod-like colloids (PaRC) adopt a favorable orientation under sufficiently strong flows. However, how the flow kinematics affect the alignment of such nanostructures according to their extensibility remains unclear. By analyzing the shear- and extension-induced alignment of chemically and structurally different PaRC, we show that extensibility is a key determinant of the structural response to the imposed kinematics. We propose a unified description of the effectiveness of extensional flow, compared to shearing flow, at aligning PaRC of different extensibility.http://doi.org/10.1103/PhysRevResearch.6.L012042 |
spellingShingle | Vincenzo Calabrese Tatiana Porto Santos Carlos G. Lopez Minne Paul Lettinga Simon J. Haward Amy Q. Shen Extensibility governs the flow-induced alignment of polymers and rod-like colloids Physical Review Research |
title | Extensibility governs the flow-induced alignment of polymers and rod-like colloids |
title_full | Extensibility governs the flow-induced alignment of polymers and rod-like colloids |
title_fullStr | Extensibility governs the flow-induced alignment of polymers and rod-like colloids |
title_full_unstemmed | Extensibility governs the flow-induced alignment of polymers and rod-like colloids |
title_short | Extensibility governs the flow-induced alignment of polymers and rod-like colloids |
title_sort | extensibility governs the flow induced alignment of polymers and rod like colloids |
url | http://doi.org/10.1103/PhysRevResearch.6.L012042 |
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