Extensibility governs the flow-induced alignment of polymers and rod-like colloids

Polymers and rod-like colloids (PaRC) adopt a favorable orientation under sufficiently strong flows. However, how the flow kinematics affect the alignment of such nanostructures according to their extensibility remains unclear. By analyzing the shear- and extension-induced alignment of chemically an...

Full description

Bibliographic Details
Main Authors: Vincenzo Calabrese, Tatiana Porto Santos, Carlos G. Lopez, Minne Paul Lettinga, Simon J. Haward, Amy Q. Shen
Format: Article
Language:English
Published: American Physical Society 2024-02-01
Series:Physical Review Research
Online Access:http://doi.org/10.1103/PhysRevResearch.6.L012042
_version_ 1797210234484162560
author Vincenzo Calabrese
Tatiana Porto Santos
Carlos G. Lopez
Minne Paul Lettinga
Simon J. Haward
Amy Q. Shen
author_facet Vincenzo Calabrese
Tatiana Porto Santos
Carlos G. Lopez
Minne Paul Lettinga
Simon J. Haward
Amy Q. Shen
author_sort Vincenzo Calabrese
collection DOAJ
description Polymers and rod-like colloids (PaRC) adopt a favorable orientation under sufficiently strong flows. However, how the flow kinematics affect the alignment of such nanostructures according to their extensibility remains unclear. By analyzing the shear- and extension-induced alignment of chemically and structurally different PaRC, we show that extensibility is a key determinant of the structural response to the imposed kinematics. We propose a unified description of the effectiveness of extensional flow, compared to shearing flow, at aligning PaRC of different extensibility.
first_indexed 2024-04-24T10:07:21Z
format Article
id doaj.art-65d6174503194274a14db5369055d0ff
institution Directory Open Access Journal
issn 2643-1564
language English
last_indexed 2024-04-24T10:07:21Z
publishDate 2024-02-01
publisher American Physical Society
record_format Article
series Physical Review Research
spelling doaj.art-65d6174503194274a14db5369055d0ff2024-04-12T17:39:40ZengAmerican Physical SocietyPhysical Review Research2643-15642024-02-0161L01204210.1103/PhysRevResearch.6.L012042Extensibility governs the flow-induced alignment of polymers and rod-like colloidsVincenzo CalabreseTatiana Porto SantosCarlos G. LopezMinne Paul LettingaSimon J. HawardAmy Q. ShenPolymers and rod-like colloids (PaRC) adopt a favorable orientation under sufficiently strong flows. However, how the flow kinematics affect the alignment of such nanostructures according to their extensibility remains unclear. By analyzing the shear- and extension-induced alignment of chemically and structurally different PaRC, we show that extensibility is a key determinant of the structural response to the imposed kinematics. We propose a unified description of the effectiveness of extensional flow, compared to shearing flow, at aligning PaRC of different extensibility.http://doi.org/10.1103/PhysRevResearch.6.L012042
spellingShingle Vincenzo Calabrese
Tatiana Porto Santos
Carlos G. Lopez
Minne Paul Lettinga
Simon J. Haward
Amy Q. Shen
Extensibility governs the flow-induced alignment of polymers and rod-like colloids
Physical Review Research
title Extensibility governs the flow-induced alignment of polymers and rod-like colloids
title_full Extensibility governs the flow-induced alignment of polymers and rod-like colloids
title_fullStr Extensibility governs the flow-induced alignment of polymers and rod-like colloids
title_full_unstemmed Extensibility governs the flow-induced alignment of polymers and rod-like colloids
title_short Extensibility governs the flow-induced alignment of polymers and rod-like colloids
title_sort extensibility governs the flow induced alignment of polymers and rod like colloids
url http://doi.org/10.1103/PhysRevResearch.6.L012042
work_keys_str_mv AT vincenzocalabrese extensibilitygovernstheflowinducedalignmentofpolymersandrodlikecolloids
AT tatianaportosantos extensibilitygovernstheflowinducedalignmentofpolymersandrodlikecolloids
AT carlosglopez extensibilitygovernstheflowinducedalignmentofpolymersandrodlikecolloids
AT minnepaullettinga extensibilitygovernstheflowinducedalignmentofpolymersandrodlikecolloids
AT simonjhaward extensibilitygovernstheflowinducedalignmentofpolymersandrodlikecolloids
AT amyqshen extensibilitygovernstheflowinducedalignmentofpolymersandrodlikecolloids