Interactions on the Interface between Two Liquid Crystal Materials

In liquid crystal applications, boundary conditions are essential to ensuring suitable bulk molecular orientation and a deterministic response to external fields. Be it confinement to a droplet or a shell, a glass plate, or an interface with air or another liquid, proper surface alignment must be en...

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Main Authors: Rok Geršak, Simon Čopar
Format: Article
Language:English
Published: MDPI AG 2020-05-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/10/5/393
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author Rok Geršak
Simon Čopar
author_facet Rok Geršak
Simon Čopar
author_sort Rok Geršak
collection DOAJ
description In liquid crystal applications, boundary conditions are essential to ensuring suitable bulk molecular orientation and a deterministic response to external fields. Be it confinement to a droplet or a shell, a glass plate, or an interface with air or another liquid, proper surface alignment must be ensured—mechanically by rubbing, by chemical treatment that adds a layer of aligning molecules, by using photoalignment or even by leaving the surface untreated, using the intrinsic properties of the substrate itself. The anchoring can be classified as unidirectional (perpendicular homeotropic, or at oblique angles), or degenerate (planar or pre-tilted). However, if both substances at the interface are anisotropic, more diverse behaviour is expected. Here, we present a numerical simulation of a nematic droplet in a nematic host, and investigate behaviour of the director field and defects at the interface for different interfacial couplings. Finally, we compare the simulations to experimental images of discotic droplets in a calamitic nematic host.
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spelling doaj.art-65dc9728bbb041e9b4ec8e9c41f294c62023-11-20T00:25:34ZengMDPI AGCrystals2073-43522020-05-0110539310.3390/cryst10050393Interactions on the Interface between Two Liquid Crystal MaterialsRok Geršak0Simon Čopar1Faculty of Mathematics and Physics, University of Ljubljana, 1000 Ljubljana, SloveniaFaculty of Mathematics and Physics, University of Ljubljana, 1000 Ljubljana, SloveniaIn liquid crystal applications, boundary conditions are essential to ensuring suitable bulk molecular orientation and a deterministic response to external fields. Be it confinement to a droplet or a shell, a glass plate, or an interface with air or another liquid, proper surface alignment must be ensured—mechanically by rubbing, by chemical treatment that adds a layer of aligning molecules, by using photoalignment or even by leaving the surface untreated, using the intrinsic properties of the substrate itself. The anchoring can be classified as unidirectional (perpendicular homeotropic, or at oblique angles), or degenerate (planar or pre-tilted). However, if both substances at the interface are anisotropic, more diverse behaviour is expected. Here, we present a numerical simulation of a nematic droplet in a nematic host, and investigate behaviour of the director field and defects at the interface for different interfacial couplings. Finally, we compare the simulations to experimental images of discotic droplets in a calamitic nematic host.https://www.mdpi.com/2073-4352/10/5/393surface anchoringanisotropic interfaceLandau-de Gennes
spellingShingle Rok Geršak
Simon Čopar
Interactions on the Interface between Two Liquid Crystal Materials
Crystals
surface anchoring
anisotropic interface
Landau-de Gennes
title Interactions on the Interface between Two Liquid Crystal Materials
title_full Interactions on the Interface between Two Liquid Crystal Materials
title_fullStr Interactions on the Interface between Two Liquid Crystal Materials
title_full_unstemmed Interactions on the Interface between Two Liquid Crystal Materials
title_short Interactions on the Interface between Two Liquid Crystal Materials
title_sort interactions on the interface between two liquid crystal materials
topic surface anchoring
anisotropic interface
Landau-de Gennes
url https://www.mdpi.com/2073-4352/10/5/393
work_keys_str_mv AT rokgersak interactionsontheinterfacebetweentwoliquidcrystalmaterials
AT simoncopar interactionsontheinterfacebetweentwoliquidcrystalmaterials