Tetragonal BiFeO3 on yttria-stabilized zirconia
High structural susceptibility of multiferroic BiFeO3 (BFO) makes it a potential replacement of current Pb-based piezoelectrics. In this study, a tetragonal phase is identified based on a combination of x-ray diffraction, scanning transmission electronic microscopy, x-ray absorption spectroscopy, an...
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Language: | English |
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AIP Publishing LLC
2015-11-01
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Series: | APL Materials |
Online Access: | http://dx.doi.org/10.1063/1.4935310 |
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author | Heng-Jui Liu Yu-Hao Du Peng Gao Yen-Chin Huang Hsiao-Wen Chen Yi-Chun Chen Hsiang-Lin Liu Qing He Yuichi Ikuhara Ying-Hao Chu |
author_facet | Heng-Jui Liu Yu-Hao Du Peng Gao Yen-Chin Huang Hsiao-Wen Chen Yi-Chun Chen Hsiang-Lin Liu Qing He Yuichi Ikuhara Ying-Hao Chu |
author_sort | Heng-Jui Liu |
collection | DOAJ |
description | High structural susceptibility of multiferroic BiFeO3 (BFO) makes it a potential replacement of current Pb-based piezoelectrics. In this study, a tetragonal phase is identified based on a combination of x-ray diffraction, scanning transmission electronic microscopy, x-ray absorption spectroscopy, and Raman spectroscopy when BFO is grown on yttria-stabilized zirconia (YSZ) substrates. To distinguish the discrepancy between this tetragonal phase and common cases of monoclinic BFO, piezoelectric force microscopy images and optical property are also performed. It shows a lower electrostatic energy of ferroelectric domains and a large reduction of band gap for BFO grown on YSZ substrate comparing to the well-known one grown on LaAlO3 substrate. Our findings in this work can provide more insights to understand the structural diversity of multiferroic BFO system for further applications. |
first_indexed | 2024-12-19T19:59:36Z |
format | Article |
id | doaj.art-661a859266cb4dbf8e58de30b6e7b5eb |
institution | Directory Open Access Journal |
issn | 2166-532X |
language | English |
last_indexed | 2024-12-19T19:59:36Z |
publishDate | 2015-11-01 |
publisher | AIP Publishing LLC |
record_format | Article |
series | APL Materials |
spelling | doaj.art-661a859266cb4dbf8e58de30b6e7b5eb2022-12-21T20:07:43ZengAIP Publishing LLCAPL Materials2166-532X2015-11-01311116104116104-810.1063/1.4935310006511APMTetragonal BiFeO3 on yttria-stabilized zirconiaHeng-Jui Liu0Yu-Hao Du1Peng Gao2Yen-Chin Huang3Hsiao-Wen Chen4Yi-Chun Chen5Hsiang-Lin Liu6Qing He7Yuichi Ikuhara8Ying-Hao Chu9Department of Materials Science Engineering, National Chiao Tung University, Hsinchu 30010, TaiwanDepartment of Materials Science Engineering, National Chiao Tung University, Hsinchu 30010, TaiwanInstitute of Engineering Innovation, The University of Tokyo, Tokyo 113-8656, JapanDepartment of Physics, National Cheng Kung University, Tainan 70101, TaiwanDepartment of Physics, National Taiwan Normal University, Taipei 11677, TaiwanDepartment of Physics, National Cheng Kung University, Tainan 70101, TaiwanDepartment of Physics, National Taiwan Normal University, Taipei 11677, TaiwanDepartment of Physics, Durham University, Durham DH1 3LE, United KingdomInstitute of Engineering Innovation, The University of Tokyo, Tokyo 113-8656, JapanDepartment of Materials Science Engineering, National Chiao Tung University, Hsinchu 30010, TaiwanHigh structural susceptibility of multiferroic BiFeO3 (BFO) makes it a potential replacement of current Pb-based piezoelectrics. In this study, a tetragonal phase is identified based on a combination of x-ray diffraction, scanning transmission electronic microscopy, x-ray absorption spectroscopy, and Raman spectroscopy when BFO is grown on yttria-stabilized zirconia (YSZ) substrates. To distinguish the discrepancy between this tetragonal phase and common cases of monoclinic BFO, piezoelectric force microscopy images and optical property are also performed. It shows a lower electrostatic energy of ferroelectric domains and a large reduction of band gap for BFO grown on YSZ substrate comparing to the well-known one grown on LaAlO3 substrate. Our findings in this work can provide more insights to understand the structural diversity of multiferroic BFO system for further applications.http://dx.doi.org/10.1063/1.4935310 |
spellingShingle | Heng-Jui Liu Yu-Hao Du Peng Gao Yen-Chin Huang Hsiao-Wen Chen Yi-Chun Chen Hsiang-Lin Liu Qing He Yuichi Ikuhara Ying-Hao Chu Tetragonal BiFeO3 on yttria-stabilized zirconia APL Materials |
title | Tetragonal BiFeO3 on yttria-stabilized zirconia |
title_full | Tetragonal BiFeO3 on yttria-stabilized zirconia |
title_fullStr | Tetragonal BiFeO3 on yttria-stabilized zirconia |
title_full_unstemmed | Tetragonal BiFeO3 on yttria-stabilized zirconia |
title_short | Tetragonal BiFeO3 on yttria-stabilized zirconia |
title_sort | tetragonal bifeo3 on yttria stabilized zirconia |
url | http://dx.doi.org/10.1063/1.4935310 |
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