Tetragonal BiFeO3 on yttria-stabilized zirconia

High structural susceptibility of multiferroic BiFeO3 (BFO) makes it a potential replacement of current Pb-based piezoelectrics. In this study, a tetragonal phase is identified based on a combination of x-ray diffraction, scanning transmission electronic microscopy, x-ray absorption spectroscopy, an...

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Main Authors: Heng-Jui Liu, Yu-Hao Du, Peng Gao, Yen-Chin Huang, Hsiao-Wen Chen, Yi-Chun Chen, Hsiang-Lin Liu, Qing He, Yuichi Ikuhara, Ying-Hao Chu
Format: Article
Language:English
Published: AIP Publishing LLC 2015-11-01
Series:APL Materials
Online Access:http://dx.doi.org/10.1063/1.4935310
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author Heng-Jui Liu
Yu-Hao Du
Peng Gao
Yen-Chin Huang
Hsiao-Wen Chen
Yi-Chun Chen
Hsiang-Lin Liu
Qing He
Yuichi Ikuhara
Ying-Hao Chu
author_facet Heng-Jui Liu
Yu-Hao Du
Peng Gao
Yen-Chin Huang
Hsiao-Wen Chen
Yi-Chun Chen
Hsiang-Lin Liu
Qing He
Yuichi Ikuhara
Ying-Hao Chu
author_sort Heng-Jui Liu
collection DOAJ
description High structural susceptibility of multiferroic BiFeO3 (BFO) makes it a potential replacement of current Pb-based piezoelectrics. In this study, a tetragonal phase is identified based on a combination of x-ray diffraction, scanning transmission electronic microscopy, x-ray absorption spectroscopy, and Raman spectroscopy when BFO is grown on yttria-stabilized zirconia (YSZ) substrates. To distinguish the discrepancy between this tetragonal phase and common cases of monoclinic BFO, piezoelectric force microscopy images and optical property are also performed. It shows a lower electrostatic energy of ferroelectric domains and a large reduction of band gap for BFO grown on YSZ substrate comparing to the well-known one grown on LaAlO3 substrate. Our findings in this work can provide more insights to understand the structural diversity of multiferroic BFO system for further applications.
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spelling doaj.art-661a859266cb4dbf8e58de30b6e7b5eb2022-12-21T20:07:43ZengAIP Publishing LLCAPL Materials2166-532X2015-11-01311116104116104-810.1063/1.4935310006511APMTetragonal BiFeO3 on yttria-stabilized zirconiaHeng-Jui Liu0Yu-Hao Du1Peng Gao2Yen-Chin Huang3Hsiao-Wen Chen4Yi-Chun Chen5Hsiang-Lin Liu6Qing He7Yuichi Ikuhara8Ying-Hao Chu9Department of Materials Science Engineering, National Chiao Tung University, Hsinchu 30010, TaiwanDepartment of Materials Science Engineering, National Chiao Tung University, Hsinchu 30010, TaiwanInstitute of Engineering Innovation, The University of Tokyo, Tokyo 113-8656, JapanDepartment of Physics, National Cheng Kung University, Tainan 70101, TaiwanDepartment of Physics, National Taiwan Normal University, Taipei 11677, TaiwanDepartment of Physics, National Cheng Kung University, Tainan 70101, TaiwanDepartment of Physics, National Taiwan Normal University, Taipei 11677, TaiwanDepartment of Physics, Durham University, Durham DH1 3LE, United KingdomInstitute of Engineering Innovation, The University of Tokyo, Tokyo 113-8656, JapanDepartment of Materials Science Engineering, National Chiao Tung University, Hsinchu 30010, TaiwanHigh structural susceptibility of multiferroic BiFeO3 (BFO) makes it a potential replacement of current Pb-based piezoelectrics. In this study, a tetragonal phase is identified based on a combination of x-ray diffraction, scanning transmission electronic microscopy, x-ray absorption spectroscopy, and Raman spectroscopy when BFO is grown on yttria-stabilized zirconia (YSZ) substrates. To distinguish the discrepancy between this tetragonal phase and common cases of monoclinic BFO, piezoelectric force microscopy images and optical property are also performed. It shows a lower electrostatic energy of ferroelectric domains and a large reduction of band gap for BFO grown on YSZ substrate comparing to the well-known one grown on LaAlO3 substrate. Our findings in this work can provide more insights to understand the structural diversity of multiferroic BFO system for further applications.http://dx.doi.org/10.1063/1.4935310
spellingShingle Heng-Jui Liu
Yu-Hao Du
Peng Gao
Yen-Chin Huang
Hsiao-Wen Chen
Yi-Chun Chen
Hsiang-Lin Liu
Qing He
Yuichi Ikuhara
Ying-Hao Chu
Tetragonal BiFeO3 on yttria-stabilized zirconia
APL Materials
title Tetragonal BiFeO3 on yttria-stabilized zirconia
title_full Tetragonal BiFeO3 on yttria-stabilized zirconia
title_fullStr Tetragonal BiFeO3 on yttria-stabilized zirconia
title_full_unstemmed Tetragonal BiFeO3 on yttria-stabilized zirconia
title_short Tetragonal BiFeO3 on yttria-stabilized zirconia
title_sort tetragonal bifeo3 on yttria stabilized zirconia
url http://dx.doi.org/10.1063/1.4935310
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