Preparation and Application of Water-in-Oil Emulsions Stabilized by Modified Graphene Oxide

A series of alkyl chain modified graphene oxides (AmGO) with different alkyl chain length and content was fabricated using a reducing reaction between graphene oxide (GO) and alkyl amine. Then AmGO was used as a graphene-based particle emulsifier to stabilize Pickering emulsion. Compared with the em...

Full description

Bibliographic Details
Main Authors: Xiaoma Fei, Lei Xia, Mingqing Chen, Wei Wei, Jing Luo, Xiaoya Liu
Format: Article
Language:English
Published: MDPI AG 2016-08-01
Series:Materials
Subjects:
Online Access:http://www.mdpi.com/1996-1944/9/9/731
_version_ 1811258723061989376
author Xiaoma Fei
Lei Xia
Mingqing Chen
Wei Wei
Jing Luo
Xiaoya Liu
author_facet Xiaoma Fei
Lei Xia
Mingqing Chen
Wei Wei
Jing Luo
Xiaoya Liu
author_sort Xiaoma Fei
collection DOAJ
description A series of alkyl chain modified graphene oxides (AmGO) with different alkyl chain length and content was fabricated using a reducing reaction between graphene oxide (GO) and alkyl amine. Then AmGO was used as a graphene-based particle emulsifier to stabilize Pickering emulsion. Compared with the emulsion stabilized by GO, which was oil-in-water type, all the emulsions stabilized by AmGO were water-in-oil type. The effects of alkyl chain length and alkyl chain content on the emulsion properties of AmGO were investigated. The emulsions stabilized by AmGO showed good stability within a wide range of pH (from pH = 1 to pH = 13) and salt concentrations (from 0.1 to 1000 mM). In addition, the application of water-in-oil emulsions stabilized by AmGO was investigated. AmGO/polyaniline nanocomposite (AmGO/PANi) was prepared through an emulsion approach, and its supercapacitor performance was investigated. This research broadens the application of AmGO as a water-in-oil type emulsion stabilizer and in preparing graphene-based functional materials.
first_indexed 2024-04-12T18:17:47Z
format Article
id doaj.art-6660157f58b4432883f699f41a6f7b21
institution Directory Open Access Journal
issn 1996-1944
language English
last_indexed 2024-04-12T18:17:47Z
publishDate 2016-08-01
publisher MDPI AG
record_format Article
series Materials
spelling doaj.art-6660157f58b4432883f699f41a6f7b212022-12-22T03:21:32ZengMDPI AGMaterials1996-19442016-08-019973110.3390/ma9090731ma9090731Preparation and Application of Water-in-Oil Emulsions Stabilized by Modified Graphene OxideXiaoma Fei0Lei Xia1Mingqing Chen2Wei Wei3Jing Luo4Xiaoya Liu5The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, ChinaThe Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, ChinaThe Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, ChinaThe Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, ChinaThe Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, ChinaThe Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, ChinaA series of alkyl chain modified graphene oxides (AmGO) with different alkyl chain length and content was fabricated using a reducing reaction between graphene oxide (GO) and alkyl amine. Then AmGO was used as a graphene-based particle emulsifier to stabilize Pickering emulsion. Compared with the emulsion stabilized by GO, which was oil-in-water type, all the emulsions stabilized by AmGO were water-in-oil type. The effects of alkyl chain length and alkyl chain content on the emulsion properties of AmGO were investigated. The emulsions stabilized by AmGO showed good stability within a wide range of pH (from pH = 1 to pH = 13) and salt concentrations (from 0.1 to 1000 mM). In addition, the application of water-in-oil emulsions stabilized by AmGO was investigated. AmGO/polyaniline nanocomposite (AmGO/PANi) was prepared through an emulsion approach, and its supercapacitor performance was investigated. This research broadens the application of AmGO as a water-in-oil type emulsion stabilizer and in preparing graphene-based functional materials.http://www.mdpi.com/1996-1944/9/9/731modified graphene oxidePickering emulsionwater-in-oil emulsionsnanocomposite
spellingShingle Xiaoma Fei
Lei Xia
Mingqing Chen
Wei Wei
Jing Luo
Xiaoya Liu
Preparation and Application of Water-in-Oil Emulsions Stabilized by Modified Graphene Oxide
Materials
modified graphene oxide
Pickering emulsion
water-in-oil emulsions
nanocomposite
title Preparation and Application of Water-in-Oil Emulsions Stabilized by Modified Graphene Oxide
title_full Preparation and Application of Water-in-Oil Emulsions Stabilized by Modified Graphene Oxide
title_fullStr Preparation and Application of Water-in-Oil Emulsions Stabilized by Modified Graphene Oxide
title_full_unstemmed Preparation and Application of Water-in-Oil Emulsions Stabilized by Modified Graphene Oxide
title_short Preparation and Application of Water-in-Oil Emulsions Stabilized by Modified Graphene Oxide
title_sort preparation and application of water in oil emulsions stabilized by modified graphene oxide
topic modified graphene oxide
Pickering emulsion
water-in-oil emulsions
nanocomposite
url http://www.mdpi.com/1996-1944/9/9/731
work_keys_str_mv AT xiaomafei preparationandapplicationofwaterinoilemulsionsstabilizedbymodifiedgrapheneoxide
AT leixia preparationandapplicationofwaterinoilemulsionsstabilizedbymodifiedgrapheneoxide
AT mingqingchen preparationandapplicationofwaterinoilemulsionsstabilizedbymodifiedgrapheneoxide
AT weiwei preparationandapplicationofwaterinoilemulsionsstabilizedbymodifiedgrapheneoxide
AT jingluo preparationandapplicationofwaterinoilemulsionsstabilizedbymodifiedgrapheneoxide
AT xiaoyaliu preparationandapplicationofwaterinoilemulsionsstabilizedbymodifiedgrapheneoxide