Status Quo on Graphene Electrode Catalysts for Improved Oxygen Reduction and Evolution Reactions in Li-Air Batteries

Reduced global warming is the goal of carbon neutrality. Therefore, batteries are considered to be the best alternatives to current fossil fuels and an icon of the emerging energy industry. Voltaic cells are one of the power sources more frequently employed than photovoltaic cells in vehicles, consu...

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Main Authors: Ganesh Gollavelli, Gangaraju Gedda, Raja Mohan, Yong-Chien Ling
Format: Article
Language:English
Published: MDPI AG 2022-11-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/27/22/7851
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author Ganesh Gollavelli
Gangaraju Gedda
Raja Mohan
Yong-Chien Ling
author_facet Ganesh Gollavelli
Gangaraju Gedda
Raja Mohan
Yong-Chien Ling
author_sort Ganesh Gollavelli
collection DOAJ
description Reduced global warming is the goal of carbon neutrality. Therefore, batteries are considered to be the best alternatives to current fossil fuels and an icon of the emerging energy industry. Voltaic cells are one of the power sources more frequently employed than photovoltaic cells in vehicles, consumer electronics, energy storage systems, and medical equipment. The most adaptable voltaic cells are lithium-ion batteries, which have the potential to meet the eagerly anticipated demands of the power sector. Working to increase their power generating and storage capability is therefore a challenging area of scientific focus. Apart from typical Li-ion batteries, Li-Air (Li-O<sub>2</sub>) batteries are expected to produce high theoretical power densities (3505 W h kg<sup>−1</sup>), which are ten times greater than that of Li-ion batteries (387 W h kg<sup>−1</sup>). On the other hand, there are many challenges to reaching their maximum power capacity. Due to the oxygen reduction reaction (ORR) and oxygen evolution reaction (OES), the cathode usually faces many problems. Designing robust structured catalytic electrode materials and optimizing the electrolytes to improve their ability is highly challenging. Graphene is a 2D material with a stable hexagonal carbon network with high surface area, electrical, thermal conductivity, and flexibility with excellent chemical stability that could be a robust electrode material for Li-O<sub>2</sub> batteries. In this review, we covered graphene-based Li-O<sub>2</sub> batteries along with their existing problems and updated advantages, with conclusions and future perspectives.
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spelling doaj.art-66697ba77f0d41c891a8f7093fc1b9d92023-11-24T09:22:17ZengMDPI AGMolecules1420-30492022-11-012722785110.3390/molecules27227851Status Quo on Graphene Electrode Catalysts for Improved Oxygen Reduction and Evolution Reactions in Li-Air BatteriesGanesh Gollavelli0Gangaraju Gedda1Raja Mohan2Yong-Chien Ling3Department of Humanities and Basic Sciences, Aditya Engineering College, Surampalem, Jawaharlal Nehru Technological University Kakinada, Kakinada 533437, IndiaDepartment of Chemistry, Presidency University, Banglore 560064, IndiaDepartment of Chemistry, Presidency University, Banglore 560064, IndiaDepartment of Chemistry, National Tsing Hua University, Hsinchu 30013, TaiwanReduced global warming is the goal of carbon neutrality. Therefore, batteries are considered to be the best alternatives to current fossil fuels and an icon of the emerging energy industry. Voltaic cells are one of the power sources more frequently employed than photovoltaic cells in vehicles, consumer electronics, energy storage systems, and medical equipment. The most adaptable voltaic cells are lithium-ion batteries, which have the potential to meet the eagerly anticipated demands of the power sector. Working to increase their power generating and storage capability is therefore a challenging area of scientific focus. Apart from typical Li-ion batteries, Li-Air (Li-O<sub>2</sub>) batteries are expected to produce high theoretical power densities (3505 W h kg<sup>−1</sup>), which are ten times greater than that of Li-ion batteries (387 W h kg<sup>−1</sup>). On the other hand, there are many challenges to reaching their maximum power capacity. Due to the oxygen reduction reaction (ORR) and oxygen evolution reaction (OES), the cathode usually faces many problems. Designing robust structured catalytic electrode materials and optimizing the electrolytes to improve their ability is highly challenging. Graphene is a 2D material with a stable hexagonal carbon network with high surface area, electrical, thermal conductivity, and flexibility with excellent chemical stability that could be a robust electrode material for Li-O<sub>2</sub> batteries. In this review, we covered graphene-based Li-O<sub>2</sub> batteries along with their existing problems and updated advantages, with conclusions and future perspectives.https://www.mdpi.com/1420-3049/27/22/7851Li-O<sub>2</sub>batterygrapheneelectrodescatalysts
spellingShingle Ganesh Gollavelli
Gangaraju Gedda
Raja Mohan
Yong-Chien Ling
Status Quo on Graphene Electrode Catalysts for Improved Oxygen Reduction and Evolution Reactions in Li-Air Batteries
Molecules
Li-O<sub>2</sub>
battery
graphene
electrodes
catalysts
title Status Quo on Graphene Electrode Catalysts for Improved Oxygen Reduction and Evolution Reactions in Li-Air Batteries
title_full Status Quo on Graphene Electrode Catalysts for Improved Oxygen Reduction and Evolution Reactions in Li-Air Batteries
title_fullStr Status Quo on Graphene Electrode Catalysts for Improved Oxygen Reduction and Evolution Reactions in Li-Air Batteries
title_full_unstemmed Status Quo on Graphene Electrode Catalysts for Improved Oxygen Reduction and Evolution Reactions in Li-Air Batteries
title_short Status Quo on Graphene Electrode Catalysts for Improved Oxygen Reduction and Evolution Reactions in Li-Air Batteries
title_sort status quo on graphene electrode catalysts for improved oxygen reduction and evolution reactions in li air batteries
topic Li-O<sub>2</sub>
battery
graphene
electrodes
catalysts
url https://www.mdpi.com/1420-3049/27/22/7851
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AT gangarajugedda statusquoongrapheneelectrodecatalystsforimprovedoxygenreductionandevolutionreactionsinliairbatteries
AT rajamohan statusquoongrapheneelectrodecatalystsforimprovedoxygenreductionandevolutionreactionsinliairbatteries
AT yongchienling statusquoongrapheneelectrodecatalystsforimprovedoxygenreductionandevolutionreactionsinliairbatteries