N-[3-(Dimethylamino)propyl]-N,N′,N′,N′′,N′′-pentamethylguanidinium tetraphenylborate
In the title salt, C11H27N4+·C24H20B−, the C—N bond lengths in the central CN3 unit of the guanidinium ion are 1.333 (4), 1.334 (4) and 1.351 (4) Å, indicating partial double-bond character. The C atom of this unit is bond...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2013-07-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536813014906 |
| _version_ | 1819002748421537792 |
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| author | Ioannis Tiritiris |
| author_facet | Ioannis Tiritiris |
| author_sort | Ioannis Tiritiris |
| collection | DOAJ |
| description | In the title salt, C11H27N4+·C24H20B−, the C—N bond lengths in the central CN3 unit of the guanidinium ion are 1.333 (4), 1.334 (4) and 1.351 (4) Å, indicating partial double-bond character. The C atom of this unit is bonded to the three N atoms in a nearly ideal trigonal-planar geometry [N—C—N angles = 118.8 (3), 120.0 (3) and 121.2 (3)°] and the positive charge is delocalized in the CN3 plane. The bonds between the N atoms and the terminal C-methyl groups of the guanidinium moiety have values in the range 1.459 (4)–1.478 (4) Å, close to a typical single bond. In the crystal, there are C—H...π interactions between the guanidinium H atoms and the phenyl rings of the tetraphenylborate ion. These interactions combine to form a ladder of linked chains of ions which runs parallel to the c axis. |
| first_indexed | 2024-12-20T23:10:02Z |
| format | Article |
| id | doaj.art-666d54b9d2c14c3b9569fe134815ad3e |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T23:10:02Z |
| publishDate | 2013-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-666d54b9d2c14c3b9569fe134815ad3e2022-12-21T19:23:46ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682013-07-01697o1040o104010.1107/S1600536813014906N-[3-(Dimethylamino)propyl]-N,N′,N′,N′′,N′′-pentamethylguanidinium tetraphenylborateIoannis TiritirisIn the title salt, C11H27N4+·C24H20B−, the C—N bond lengths in the central CN3 unit of the guanidinium ion are 1.333 (4), 1.334 (4) and 1.351 (4) Å, indicating partial double-bond character. The C atom of this unit is bonded to the three N atoms in a nearly ideal trigonal-planar geometry [N—C—N angles = 118.8 (3), 120.0 (3) and 121.2 (3)°] and the positive charge is delocalized in the CN3 plane. The bonds between the N atoms and the terminal C-methyl groups of the guanidinium moiety have values in the range 1.459 (4)–1.478 (4) Å, close to a typical single bond. In the crystal, there are C—H...π interactions between the guanidinium H atoms and the phenyl rings of the tetraphenylborate ion. These interactions combine to form a ladder of linked chains of ions which runs parallel to the c axis.http://scripts.iucr.org/cgi-bin/paper?S1600536813014906 |
| spellingShingle | Ioannis Tiritiris N-[3-(Dimethylamino)propyl]-N,N′,N′,N′′,N′′-pentamethylguanidinium tetraphenylborate Acta Crystallographica Section E |
| title | N-[3-(Dimethylamino)propyl]-N,N′,N′,N′′,N′′-pentamethylguanidinium tetraphenylborate |
| title_full | N-[3-(Dimethylamino)propyl]-N,N′,N′,N′′,N′′-pentamethylguanidinium tetraphenylborate |
| title_fullStr | N-[3-(Dimethylamino)propyl]-N,N′,N′,N′′,N′′-pentamethylguanidinium tetraphenylborate |
| title_full_unstemmed | N-[3-(Dimethylamino)propyl]-N,N′,N′,N′′,N′′-pentamethylguanidinium tetraphenylborate |
| title_short | N-[3-(Dimethylamino)propyl]-N,N′,N′,N′′,N′′-pentamethylguanidinium tetraphenylborate |
| title_sort | n 3 dimethylamino propyl n n 8242 n 8242 n 8242 8242 n 8242 8242 pentamethylguanidinium tetraphenylborate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536813014906 |
| work_keys_str_mv | AT ioannistiritiris n3dimethylaminopropylnn8242n8242n82428242n82428242pentamethylguanidiniumtetraphenylborate |