Efficiency of Photocatalytic Ozone Process Combined with Zinc Oxide in Removal of Amoxicillin from Hospital Wastewater

Background and purpose: One of the main problems of pollution of aquatic environments is hardly biodegradable chemicals with high toxicity such as antibiotics. If they are not removed from the wastewater, particularly the hospital wastewater, many health and environmental hazards are created. Theref...

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Main Authors: Mohammad Ali Zazouli, Ehsan Abouee Mehrizi, Jamshid Yazdani Charati, Reza Ghorbanpour
Format: Article
Language:English
Published: Mazandaran University of Medical Sciences 2019-09-01
Series:Journal of Mazandaran University of Medical Sciences
Subjects:
Online Access:http://jmums.mazums.ac.ir/article-1-13480-en.html
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author Mohammad Ali Zazouli
Ehsan Abouee Mehrizi
Jamshid Yazdani Charati
Reza Ghorbanpour
author_facet Mohammad Ali Zazouli
Ehsan Abouee Mehrizi
Jamshid Yazdani Charati
Reza Ghorbanpour
author_sort Mohammad Ali Zazouli
collection DOAJ
description Background and purpose: One of the main problems of pollution of aquatic environments is hardly biodegradable chemicals with high toxicity such as antibiotics. If they are not removed from the wastewater, particularly the hospital wastewater, many health and environmental hazards are created. Therefore, appropriate management and treatment of this type of wastewater is highly necessary. This research aimed at investigating the efficiency of advanced oxidation process by ozone photocatalytic method combined with zinc oxide in removal of amoxicillin from wastewater. Materials and methods: The present study was conducted on laboratory scale in a pre-designed reactor. The effects of ozone concentration (5-10 mg/min), catalyst concentration (0.25-1.5mg/l), amoxicillin concentration (10-100 mg/l), and pH (3-11) were investigated on the process efficiency by HPLC. Thirty specimens were studied using central composite design method and the information was evaluated by surface response method using Design Expert7. Data analysis was done applying ANOVA and regression analysis. Results: The removal efficiency of amoxicillin was 93% under optimal conditions (ozone dose: 3 mg/min, pH 11, catalyst dose: 0.875 mg/l, and amoxicillin concentration: 55mg/l). ANOVA and regression analysis showed that the fitted model properly matched with laboratory results. Conclusion: This study showed that the ozone photocatalytic process along with zinc oxide could be applied as a suitable and effective method in treatment of antibiotics in aqueous environments.
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spelling doaj.art-6673a175ba834e1883c55ab0205d8afb2023-01-25T06:18:58ZengMazandaran University of Medical SciencesJournal of Mazandaran University of Medical Sciences1735-92601735-92792019-09-0129176126139Efficiency of Photocatalytic Ozone Process Combined with Zinc Oxide in Removal of Amoxicillin from Hospital WastewaterMohammad Ali Zazouli0Ehsan Abouee Mehrizi1Jamshid Yazdani Charati2Reza Ghorbanpour3 Professor, Department of Environmental Health Engineering, Faculty of Health, Mazandaran University of Medical Sciences, Sari, Iran Assistant Professor, Department of Environmental Health Engineering, School of Public Health, Shahid Sadoughi University of Medical Sciences, Yazd, Iran Associate Professor, Department of Biostatistics, Health Sciences Research Center, Addiction Institute, Mazandaran University of Medical Sciences, Sari, Iran MSc in Environmental Health Engineering, Faculty of Health, Mazandaran University of Medical Sciences, Sari, Iran Background and purpose: One of the main problems of pollution of aquatic environments is hardly biodegradable chemicals with high toxicity such as antibiotics. If they are not removed from the wastewater, particularly the hospital wastewater, many health and environmental hazards are created. Therefore, appropriate management and treatment of this type of wastewater is highly necessary. This research aimed at investigating the efficiency of advanced oxidation process by ozone photocatalytic method combined with zinc oxide in removal of amoxicillin from wastewater. Materials and methods: The present study was conducted on laboratory scale in a pre-designed reactor. The effects of ozone concentration (5-10 mg/min), catalyst concentration (0.25-1.5mg/l), amoxicillin concentration (10-100 mg/l), and pH (3-11) were investigated on the process efficiency by HPLC. Thirty specimens were studied using central composite design method and the information was evaluated by surface response method using Design Expert7. Data analysis was done applying ANOVA and regression analysis. Results: The removal efficiency of amoxicillin was 93% under optimal conditions (ozone dose: 3 mg/min, pH 11, catalyst dose: 0.875 mg/l, and amoxicillin concentration: 55mg/l). ANOVA and regression analysis showed that the fitted model properly matched with laboratory results. Conclusion: This study showed that the ozone photocatalytic process along with zinc oxide could be applied as a suitable and effective method in treatment of antibiotics in aqueous environments.http://jmums.mazums.ac.ir/article-1-13480-en.htmlamoxicillinadvanced oxidationhospital wastewatercentral composite design
spellingShingle Mohammad Ali Zazouli
Ehsan Abouee Mehrizi
Jamshid Yazdani Charati
Reza Ghorbanpour
Efficiency of Photocatalytic Ozone Process Combined with Zinc Oxide in Removal of Amoxicillin from Hospital Wastewater
Journal of Mazandaran University of Medical Sciences
amoxicillin
advanced oxidation
hospital wastewater
central composite design
title Efficiency of Photocatalytic Ozone Process Combined with Zinc Oxide in Removal of Amoxicillin from Hospital Wastewater
title_full Efficiency of Photocatalytic Ozone Process Combined with Zinc Oxide in Removal of Amoxicillin from Hospital Wastewater
title_fullStr Efficiency of Photocatalytic Ozone Process Combined with Zinc Oxide in Removal of Amoxicillin from Hospital Wastewater
title_full_unstemmed Efficiency of Photocatalytic Ozone Process Combined with Zinc Oxide in Removal of Amoxicillin from Hospital Wastewater
title_short Efficiency of Photocatalytic Ozone Process Combined with Zinc Oxide in Removal of Amoxicillin from Hospital Wastewater
title_sort efficiency of photocatalytic ozone process combined with zinc oxide in removal of amoxicillin from hospital wastewater
topic amoxicillin
advanced oxidation
hospital wastewater
central composite design
url http://jmums.mazums.ac.ir/article-1-13480-en.html
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AT jamshidyazdanicharati efficiencyofphotocatalyticozoneprocesscombinedwithzincoxideinremovalofamoxicillinfromhospitalwastewater
AT rezaghorbanpour efficiencyofphotocatalyticozoneprocesscombinedwithzincoxideinremovalofamoxicillinfromhospitalwastewater