Glycols in the Synthesis of Zinc-Anilato Coordination Polymers
We report the synthesis, structural investigation, and thermal behavior for three zinc-based 1D-coordination polymers with 3,6-di-tert-butyl-2,5-dihydroxy-p-benzoquinone, which were synthesized in the presence of different glycols. The interaction of zinc nitrate with glycols, followed by using the...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2022-03-01
|
| Series: | Crystals |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2073-4352/12/3/370 |
| _version_ | 1797472146755158016 |
|---|---|
| author | Olesya Y. Trofimova Arina V. Maleeva Kseniya V. Arsenyeva Anastasiya V. Klimashevskaya Il’ya A. Yakushev Alexandr V. Piskunov |
| author_facet | Olesya Y. Trofimova Arina V. Maleeva Kseniya V. Arsenyeva Anastasiya V. Klimashevskaya Il’ya A. Yakushev Alexandr V. Piskunov |
| author_sort | Olesya Y. Trofimova |
| collection | DOAJ |
| description | We report the synthesis, structural investigation, and thermal behavior for three zinc-based 1D-coordination polymers with 3,6-di-tert-butyl-2,5-dihydroxy-p-benzoquinone, which were synthesized in the presence of different glycols. The interaction of zinc nitrate with glycols, followed by using the resulting solution in solvothermal synthesis with the anilate ligand in DMF, makes it possible to obtain linear polymer structures with 1,2-ethylene or 1,2-propylene glycols coordinated to the metal. The reaction involving 1,3-propylene glycol under similar conditions gives a crystal structure that does not contain a diol. The crystal and molecular structures of the synthesized compounds were determined using single crystal by X-ray structural analysis. The influence of glycol molecules coordinated to the metal on the thermal destruction of synthesized compounds is shown. |
| first_indexed | 2024-03-09T19:58:01Z |
| format | Article |
| id | doaj.art-66789c5a39224662a9af79744b1cc2de |
| institution | Directory Open Access Journal |
| issn | 2073-4352 |
| language | English |
| last_indexed | 2024-03-09T19:58:01Z |
| publishDate | 2022-03-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Crystals |
| spelling | doaj.art-66789c5a39224662a9af79744b1cc2de2023-11-24T00:51:42ZengMDPI AGCrystals2073-43522022-03-0112337010.3390/cryst12030370Glycols in the Synthesis of Zinc-Anilato Coordination PolymersOlesya Y. Trofimova0Arina V. Maleeva1Kseniya V. Arsenyeva2Anastasiya V. Klimashevskaya3Il’ya A. Yakushev4Alexandr V. Piskunov5Laboratory of Metal Complexes with Redox-Active Ligands, G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137 Nizhny Novgorod, RussiaLaboratory of Metal Complexes with Redox-Active Ligands, G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137 Nizhny Novgorod, RussiaLaboratory of Metal Complexes with Redox-Active Ligands, G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137 Nizhny Novgorod, RussiaLaboratory of Metal Complexes with Redox-Active Ligands, G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137 Nizhny Novgorod, RussiaN.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, RussiaLaboratory of Metal Complexes with Redox-Active Ligands, G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137 Nizhny Novgorod, RussiaWe report the synthesis, structural investigation, and thermal behavior for three zinc-based 1D-coordination polymers with 3,6-di-tert-butyl-2,5-dihydroxy-p-benzoquinone, which were synthesized in the presence of different glycols. The interaction of zinc nitrate with glycols, followed by using the resulting solution in solvothermal synthesis with the anilate ligand in DMF, makes it possible to obtain linear polymer structures with 1,2-ethylene or 1,2-propylene glycols coordinated to the metal. The reaction involving 1,3-propylene glycol under similar conditions gives a crystal structure that does not contain a diol. The crystal and molecular structures of the synthesized compounds were determined using single crystal by X-ray structural analysis. The influence of glycol molecules coordinated to the metal on the thermal destruction of synthesized compounds is shown.https://www.mdpi.com/2073-4352/12/3/370anilate ligandcoordination polymerzincX-raydifferential thermal analysis |
| spellingShingle | Olesya Y. Trofimova Arina V. Maleeva Kseniya V. Arsenyeva Anastasiya V. Klimashevskaya Il’ya A. Yakushev Alexandr V. Piskunov Glycols in the Synthesis of Zinc-Anilato Coordination Polymers Crystals anilate ligand coordination polymer zinc X-ray differential thermal analysis |
| title | Glycols in the Synthesis of Zinc-Anilato Coordination Polymers |
| title_full | Glycols in the Synthesis of Zinc-Anilato Coordination Polymers |
| title_fullStr | Glycols in the Synthesis of Zinc-Anilato Coordination Polymers |
| title_full_unstemmed | Glycols in the Synthesis of Zinc-Anilato Coordination Polymers |
| title_short | Glycols in the Synthesis of Zinc-Anilato Coordination Polymers |
| title_sort | glycols in the synthesis of zinc anilato coordination polymers |
| topic | anilate ligand coordination polymer zinc X-ray differential thermal analysis |
| url | https://www.mdpi.com/2073-4352/12/3/370 |
| work_keys_str_mv | AT olesyaytrofimova glycolsinthesynthesisofzincanilatocoordinationpolymers AT arinavmaleeva glycolsinthesynthesisofzincanilatocoordinationpolymers AT kseniyavarsenyeva glycolsinthesynthesisofzincanilatocoordinationpolymers AT anastasiyavklimashevskaya glycolsinthesynthesisofzincanilatocoordinationpolymers AT ilyaayakushev glycolsinthesynthesisofzincanilatocoordinationpolymers AT alexandrvpiskunov glycolsinthesynthesisofzincanilatocoordinationpolymers |