Synthesis of Betaine Copolymer for Surface Modification of Cotton Fabric by Enhancing Temperature-Sensitive and Anti-Protein Specific Absorption Performance

The growth and reproduction of microorganisms on fabrics could not only affect the wearability of textiles but also cause harm to human health, and it is an important problem that should be solved to reduce the adsorption and growth of microorganisms on the surface of the fabric. A series of ω-vinyl...

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Main Authors: Xiaofei Yan, Chenkai Zhu, Ju Huang, Dongmin Qi, Jiawei Li
Format: Article
Language:English
Published: MDPI AG 2021-11-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/14/22/6793
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author Xiaofei Yan
Chenkai Zhu
Ju Huang
Dongmin Qi
Jiawei Li
author_facet Xiaofei Yan
Chenkai Zhu
Ju Huang
Dongmin Qi
Jiawei Li
author_sort Xiaofei Yan
collection DOAJ
description The growth and reproduction of microorganisms on fabrics could not only affect the wearability of textiles but also cause harm to human health, and it is an important problem that should be solved to reduce the adsorption and growth of microorganisms on the surface of the fabric. A series of ω-vinyl betaine copolymers were synthesized by catalytic chain transfer polymerization (CCTP) and were modified by mercapto-vinyl click chemistry to synthesize silane-modified betaine copolymers, which were used to treat the cotton fabric. The hydrophilic–hydrophobic transition performance and anti-protein specific adhesion performance of cotton fabric with the betaine copolymer were systematically investigated. The copolymer was confirmed to be successfully finished on the cotton fabric via <sup>1</sup>H–NMR and FTIR. The cotton fabric, which was treated by the betaine copolymer, presented temperature response performance in the range of 30–55 °C and had excellent anti-protein adsorption performance. The treated fabric had the best temperature-sensitive and anti-protein specific absorption performance among all the specimens when the mass fraction of G06B in DMAPS was 6 wt.%.
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spelling doaj.art-6682cbddab4c46109c785f9edafba2a72023-11-23T00:08:53ZengMDPI AGMaterials1996-19442021-11-011422679310.3390/ma14226793Synthesis of Betaine Copolymer for Surface Modification of Cotton Fabric by Enhancing Temperature-Sensitive and Anti-Protein Specific Absorption PerformanceXiaofei Yan0Chenkai Zhu1Ju Huang2Dongmin Qi3Jiawei Li4Key Laboratory of Advanced Textile Materials and Manufacturing Technology, Ministry of Education, Zhejiang Sci-Tech University, Hangzhou 310018, ChinaNingbo Institute of Technology, Beihang University, Ningbo 315800, ChinaCollege of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou 310018, ChinaCollege of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou 310018, ChinaCollege of Textile Science and Engineering (International Institute of Silk), Zhejiang Sci-Tech University, Hangzhou 310018, ChinaThe growth and reproduction of microorganisms on fabrics could not only affect the wearability of textiles but also cause harm to human health, and it is an important problem that should be solved to reduce the adsorption and growth of microorganisms on the surface of the fabric. A series of ω-vinyl betaine copolymers were synthesized by catalytic chain transfer polymerization (CCTP) and were modified by mercapto-vinyl click chemistry to synthesize silane-modified betaine copolymers, which were used to treat the cotton fabric. The hydrophilic–hydrophobic transition performance and anti-protein specific adhesion performance of cotton fabric with the betaine copolymer were systematically investigated. The copolymer was confirmed to be successfully finished on the cotton fabric via <sup>1</sup>H–NMR and FTIR. The cotton fabric, which was treated by the betaine copolymer, presented temperature response performance in the range of 30–55 °C and had excellent anti-protein adsorption performance. The treated fabric had the best temperature-sensitive and anti-protein specific absorption performance among all the specimens when the mass fraction of G06B in DMAPS was 6 wt.%.https://www.mdpi.com/1996-1944/14/22/6793betaine copolymercotton fabrictemperature-sensitive responseanti-protein specific adhesion
spellingShingle Xiaofei Yan
Chenkai Zhu
Ju Huang
Dongmin Qi
Jiawei Li
Synthesis of Betaine Copolymer for Surface Modification of Cotton Fabric by Enhancing Temperature-Sensitive and Anti-Protein Specific Absorption Performance
Materials
betaine copolymer
cotton fabric
temperature-sensitive response
anti-protein specific adhesion
title Synthesis of Betaine Copolymer for Surface Modification of Cotton Fabric by Enhancing Temperature-Sensitive and Anti-Protein Specific Absorption Performance
title_full Synthesis of Betaine Copolymer for Surface Modification of Cotton Fabric by Enhancing Temperature-Sensitive and Anti-Protein Specific Absorption Performance
title_fullStr Synthesis of Betaine Copolymer for Surface Modification of Cotton Fabric by Enhancing Temperature-Sensitive and Anti-Protein Specific Absorption Performance
title_full_unstemmed Synthesis of Betaine Copolymer for Surface Modification of Cotton Fabric by Enhancing Temperature-Sensitive and Anti-Protein Specific Absorption Performance
title_short Synthesis of Betaine Copolymer for Surface Modification of Cotton Fabric by Enhancing Temperature-Sensitive and Anti-Protein Specific Absorption Performance
title_sort synthesis of betaine copolymer for surface modification of cotton fabric by enhancing temperature sensitive and anti protein specific absorption performance
topic betaine copolymer
cotton fabric
temperature-sensitive response
anti-protein specific adhesion
url https://www.mdpi.com/1996-1944/14/22/6793
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AT juhuang synthesisofbetainecopolymerforsurfacemodificationofcottonfabricbyenhancingtemperaturesensitiveandantiproteinspecificabsorptionperformance
AT dongminqi synthesisofbetainecopolymerforsurfacemodificationofcottonfabricbyenhancingtemperaturesensitiveandantiproteinspecificabsorptionperformance
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