Multifunctional Chemical Sensing Platform Based on Dual‐Resonant Infrared Plasmonic Perfect Absorber for On‐Chip Detection of Poly(ethyl cyanoacrylate)
Abstract Multifunctional chemical sensing is highly desirable in industry, agriculture, and environmental sciences, but remains challenging due to the diversity of chemical substances and reactions. Surface‐enhanced infrared absorption (SEIRA) spectroscopy can potentially address the above problems...
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2021-10-01
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| Series: | Advanced Science |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/advs.202101879 |
| _version_ | 1818405905972068352 |
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| author | Dongxiao Li Hong Zhou Xindan Hui Xianming He He Huang Jiajia Zhang Xiaojing Mu Chengkuo Lee Ya Yang |
| author_facet | Dongxiao Li Hong Zhou Xindan Hui Xianming He He Huang Jiajia Zhang Xiaojing Mu Chengkuo Lee Ya Yang |
| author_sort | Dongxiao Li |
| collection | DOAJ |
| description | Abstract Multifunctional chemical sensing is highly desirable in industry, agriculture, and environmental sciences, but remains challenging due to the diversity of chemical substances and reactions. Surface‐enhanced infrared absorption (SEIRA) spectroscopy can potentially address the above problems by ultra‐sensitive detection of molecular fingerprint vibrations. Here, a multifunctional chemical sensing platform based on dual‐resonant SEIRA device for sensitive and multifunctional on‐chip detection of poly(ethyl cyanoacrylate) (PECA) is reported. It is experimentally demonstrated that the SEIRA sensing platform achieves multiple functions required by the PECA glue industry, including vibrational detection, thickness measurement, and in situ observation of polymerization and curing, which are usually realized by separately using a spectrometer, a viscometer, and an ellipsometer in the past. Specifically, the all‐in‐one sensor offers a dual‐band fingerprint vibration identification, sub‐nm level detection limit, and ultrahigh sensitivity of 0.76%/nm in thickness measurement, and second‐level resolution in real‐time observation of polymerization and curing. This work not only provides a valuable toolkit for ultra‐sensitive and multifunctional on‐chip detection of PECA, but also gives new insights into the SEIRA technology for multi‐band, multi‐functional, and on‐chip chemical sensing. |
| first_indexed | 2024-12-14T09:03:29Z |
| format | Article |
| id | doaj.art-66887a894d25408c8fee313c54ad9d78 |
| institution | Directory Open Access Journal |
| issn | 2198-3844 |
| language | English |
| last_indexed | 2024-12-14T09:03:29Z |
| publishDate | 2021-10-01 |
| publisher | Wiley |
| record_format | Article |
| series | Advanced Science |
| spelling | doaj.art-66887a894d25408c8fee313c54ad9d782022-12-21T23:08:45ZengWileyAdvanced Science2198-38442021-10-01820n/an/a10.1002/advs.202101879Multifunctional Chemical Sensing Platform Based on Dual‐Resonant Infrared Plasmonic Perfect Absorber for On‐Chip Detection of Poly(ethyl cyanoacrylate)Dongxiao Li0Hong Zhou1Xindan Hui2Xianming He3He Huang4Jiajia Zhang5Xiaojing Mu6Chengkuo Lee7Ya Yang8Key Laboratory of Optoelectronic Technology & Systems of Ministry of Education International R & D center of Micro‐nano Systems and New Materials Technology Chongqing University Chongqing 400044 P. R. ChinaKey Laboratory of Optoelectronic Technology & Systems of Ministry of Education International R & D center of Micro‐nano Systems and New Materials Technology Chongqing University Chongqing 400044 P. R. ChinaKey Laboratory of Optoelectronic Technology & Systems of Ministry of Education International R & D center of Micro‐nano Systems and New Materials Technology Chongqing University Chongqing 400044 P. R. ChinaKey Laboratory of Optoelectronic Technology & Systems of Ministry of Education International R & D center of Micro‐nano Systems and New Materials Technology Chongqing University Chongqing 400044 P. R. ChinaKey Laboratory of Optoelectronic Technology & Systems of Ministry of Education International R & D center of Micro‐nano Systems and New Materials Technology Chongqing University Chongqing 400044 P. R. ChinaKey Laboratory of Optoelectronic Technology & Systems of Ministry of Education International R & D center of Micro‐nano Systems and New Materials Technology Chongqing University Chongqing 400044 P. R. ChinaKey Laboratory of Optoelectronic Technology & Systems of Ministry of Education International R & D center of Micro‐nano Systems and New Materials Technology Chongqing University Chongqing 400044 P. R. ChinaDepartment of Electrical and Computer Engineering Center for Intelligent Sensors and MEMS (CISM) and NUS Graduate School for Integrative Sciences and Engineering National University of Singapore Singapore 117576 SingaporeCAS Center for Excellence in Nanoscience Beijing Key Laboratory of Micro‐nano Energy and Sensor Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of Sciences Beijing 100083 P. R. ChinaAbstract Multifunctional chemical sensing is highly desirable in industry, agriculture, and environmental sciences, but remains challenging due to the diversity of chemical substances and reactions. Surface‐enhanced infrared absorption (SEIRA) spectroscopy can potentially address the above problems by ultra‐sensitive detection of molecular fingerprint vibrations. Here, a multifunctional chemical sensing platform based on dual‐resonant SEIRA device for sensitive and multifunctional on‐chip detection of poly(ethyl cyanoacrylate) (PECA) is reported. It is experimentally demonstrated that the SEIRA sensing platform achieves multiple functions required by the PECA glue industry, including vibrational detection, thickness measurement, and in situ observation of polymerization and curing, which are usually realized by separately using a spectrometer, a viscometer, and an ellipsometer in the past. Specifically, the all‐in‐one sensor offers a dual‐band fingerprint vibration identification, sub‐nm level detection limit, and ultrahigh sensitivity of 0.76%/nm in thickness measurement, and second‐level resolution in real‐time observation of polymerization and curing. This work not only provides a valuable toolkit for ultra‐sensitive and multifunctional on‐chip detection of PECA, but also gives new insights into the SEIRA technology for multi‐band, multi‐functional, and on‐chip chemical sensing.https://doi.org/10.1002/advs.202101879infrared spectroscopymetamaterial absorbersmultifunctional sensorspoly(ethyl cyanoacrylate) sensingsurface‐enhanced infrared absorption |
| spellingShingle | Dongxiao Li Hong Zhou Xindan Hui Xianming He He Huang Jiajia Zhang Xiaojing Mu Chengkuo Lee Ya Yang Multifunctional Chemical Sensing Platform Based on Dual‐Resonant Infrared Plasmonic Perfect Absorber for On‐Chip Detection of Poly(ethyl cyanoacrylate) Advanced Science infrared spectroscopy metamaterial absorbers multifunctional sensors poly(ethyl cyanoacrylate) sensing surface‐enhanced infrared absorption |
| title | Multifunctional Chemical Sensing Platform Based on Dual‐Resonant Infrared Plasmonic Perfect Absorber for On‐Chip Detection of Poly(ethyl cyanoacrylate) |
| title_full | Multifunctional Chemical Sensing Platform Based on Dual‐Resonant Infrared Plasmonic Perfect Absorber for On‐Chip Detection of Poly(ethyl cyanoacrylate) |
| title_fullStr | Multifunctional Chemical Sensing Platform Based on Dual‐Resonant Infrared Plasmonic Perfect Absorber for On‐Chip Detection of Poly(ethyl cyanoacrylate) |
| title_full_unstemmed | Multifunctional Chemical Sensing Platform Based on Dual‐Resonant Infrared Plasmonic Perfect Absorber for On‐Chip Detection of Poly(ethyl cyanoacrylate) |
| title_short | Multifunctional Chemical Sensing Platform Based on Dual‐Resonant Infrared Plasmonic Perfect Absorber for On‐Chip Detection of Poly(ethyl cyanoacrylate) |
| title_sort | multifunctional chemical sensing platform based on dual resonant infrared plasmonic perfect absorber for on chip detection of poly ethyl cyanoacrylate |
| topic | infrared spectroscopy metamaterial absorbers multifunctional sensors poly(ethyl cyanoacrylate) sensing surface‐enhanced infrared absorption |
| url | https://doi.org/10.1002/advs.202101879 |
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