Use of hydrogen peroxide and percarbonate to treat chlorinated aromatic hydrocarbon-contaminated soil

This study compared treatment methods that utilised a liquid carrier of hydrogen peroxide and a solid carrier, percarbonate, for p-dichlorobenzene, p-chloro-m-cresol and p-chlorothymol degradation in the soil. The targeted chlorinated aromatic contaminants in the soil degraded to a certain level whe...

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Main Authors: Marika Viisimaa, Anna Goi
Format: Article
Language:English
Published: Vilnius Gediminas Technical University 2014-03-01
Series:Journal of Environmental Engineering and Landscape Management
Subjects:
Online Access:http://journals.vgtu.lt/index.php/JEELM/article/view/1418
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author Marika Viisimaa
Anna Goi
author_facet Marika Viisimaa
Anna Goi
author_sort Marika Viisimaa
collection DOAJ
description This study compared treatment methods that utilised a liquid carrier of hydrogen peroxide and a solid carrier, percarbonate, for p-dichlorobenzene, p-chloro-m-cresol and p-chlorothymol degradation in the soil. The targeted chlorinated aromatic contaminants in the soil degraded to a certain level when treated with the liquid hydrogen peroxide, but the removal efficacy was not dependent on the dosage. In contrast, an increase in the percarbonate dosage enhanced the contaminant removal. Supplementary ferrous iron was more effective for the treatment that employed the liquid carrier of hydrogen peroxide than the treatment employing the solid carrier. Although acidic pH conditions (initial pH of 2.5) favoured contaminant degradation using liquid hydrogen peroxide, the treatment involving percarbonate resulted in more effective contaminant removal without any soil pH preadjustment. Therefore, the solid carrier of hydrogen peroxide, percarbonate, was concluded to be an effective alternative to the liquid carrier, resulting in greater contaminant removal at natural soil pH values.
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spelling doaj.art-668df3f80aa943a082f127de1ef7807c2022-12-21T20:48:19ZengVilnius Gediminas Technical UniversityJournal of Environmental Engineering and Landscape Management1648-68971822-41992014-03-0122110.3846/16486897.2013.804827Use of hydrogen peroxide and percarbonate to treat chlorinated aromatic hydrocarbon-contaminated soilMarika Viisimaa0Anna Goi1Department of Chemical Engineering, Tallinn University of Technology, Ehitajate tee 5, 19086 Tallinn, EstoniaDepartment of Chemical Engineering, Tallinn University of Technology, Ehitajate tee 5, 19086 Tallinn, EstoniaThis study compared treatment methods that utilised a liquid carrier of hydrogen peroxide and a solid carrier, percarbonate, for p-dichlorobenzene, p-chloro-m-cresol and p-chlorothymol degradation in the soil. The targeted chlorinated aromatic contaminants in the soil degraded to a certain level when treated with the liquid hydrogen peroxide, but the removal efficacy was not dependent on the dosage. In contrast, an increase in the percarbonate dosage enhanced the contaminant removal. Supplementary ferrous iron was more effective for the treatment that employed the liquid carrier of hydrogen peroxide than the treatment employing the solid carrier. Although acidic pH conditions (initial pH of 2.5) favoured contaminant degradation using liquid hydrogen peroxide, the treatment involving percarbonate resulted in more effective contaminant removal without any soil pH preadjustment. Therefore, the solid carrier of hydrogen peroxide, percarbonate, was concluded to be an effective alternative to the liquid carrier, resulting in greater contaminant removal at natural soil pH values.http://journals.vgtu.lt/index.php/JEELM/article/view/1418soil cleaning technologieschemical oxidationhydrogen peroxide carrieractivation aid
spellingShingle Marika Viisimaa
Anna Goi
Use of hydrogen peroxide and percarbonate to treat chlorinated aromatic hydrocarbon-contaminated soil
Journal of Environmental Engineering and Landscape Management
soil cleaning technologies
chemical oxidation
hydrogen peroxide carrier
activation aid
title Use of hydrogen peroxide and percarbonate to treat chlorinated aromatic hydrocarbon-contaminated soil
title_full Use of hydrogen peroxide and percarbonate to treat chlorinated aromatic hydrocarbon-contaminated soil
title_fullStr Use of hydrogen peroxide and percarbonate to treat chlorinated aromatic hydrocarbon-contaminated soil
title_full_unstemmed Use of hydrogen peroxide and percarbonate to treat chlorinated aromatic hydrocarbon-contaminated soil
title_short Use of hydrogen peroxide and percarbonate to treat chlorinated aromatic hydrocarbon-contaminated soil
title_sort use of hydrogen peroxide and percarbonate to treat chlorinated aromatic hydrocarbon contaminated soil
topic soil cleaning technologies
chemical oxidation
hydrogen peroxide carrier
activation aid
url http://journals.vgtu.lt/index.php/JEELM/article/view/1418
work_keys_str_mv AT marikaviisimaa useofhydrogenperoxideandpercarbonatetotreatchlorinatedaromatichydrocarboncontaminatedsoil
AT annagoi useofhydrogenperoxideandpercarbonatetotreatchlorinatedaromatichydrocarboncontaminatedsoil