Xylitol and Maltitol Improve the Rheological Property of Kappa-Carrageenan

To further extend the use of κ-carrageenan (κ-C) in real food systems (such as beverages), the understanding of gelation properties of κ-C with the presence of food ingredients is critical. The effects of xylitol and maltitol (up to 30 wt %) on the rheological and structural properties of κ-C were i...

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Main Authors: Min Huang, Yihan Mao, Yuzhu Mao, Hongshun Yang
Format: Article
Language:English
Published: MDPI AG 2021-12-01
Series:Foods
Subjects:
Online Access:https://www.mdpi.com/2304-8158/11/1/51
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author Min Huang
Yihan Mao
Yuzhu Mao
Hongshun Yang
author_facet Min Huang
Yihan Mao
Yuzhu Mao
Hongshun Yang
author_sort Min Huang
collection DOAJ
description To further extend the use of κ-carrageenan (κ-C) in real food systems (such as beverages), the understanding of gelation properties of κ-C with the presence of food ingredients is critical. The effects of xylitol and maltitol (up to 30 wt %) on the rheological and structural properties of κ-C were inspected by means of rheometer and Fourier transform infrared (FTIR). With the addition of xylitol, the gelation temperature increased from 44.1 to 57.3 °C, while the gelation temperature increased from 44.1 to 61.4 °C in maltitol systems. With the increasing concentration of both xylitol and maltitol, the values of fractal dimension <i>d<sub>f</sub></i> and complex modulus <i>G</i>* of κ-C increased, while the relaxation exponent <i>n</i> decreased from 0.87 to 0.39 of xylitol and 0.87 to 0.78 of maltitol, respectively. These indicated that the gel networks of aqueous κ-C were improved by the addition of xylitol and maltitol. The FTIR results showed that the interaction between κ-C and these polyols contributed to the increase of hydrogen bonds. The effects of maltitol on κ-C were stronger than those of xylitol because of more equatorial-OH bonds in maltitol. These findings contribute to a better understanding of the gelation processes of κ-C/polyols systems.
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spelling doaj.art-66a92cd498314275a12edfd58ef022ee2023-11-23T11:30:44ZengMDPI AGFoods2304-81582021-12-011115110.3390/foods11010051Xylitol and Maltitol Improve the Rheological Property of Kappa-CarrageenanMin Huang0Yihan Mao1Yuzhu Mao2Hongshun Yang3School of Food Science and Biotechnology, Zhejiang Gongshang University, Hangzhou 310018, ChinaDepartment of Food Science and Technology, National University of Singapore, Singapore 117542, SingaporeDepartment of Food Science and Technology, National University of Singapore, Singapore 117542, SingaporeDepartment of Food Science and Technology, National University of Singapore, Singapore 117542, SingaporeTo further extend the use of κ-carrageenan (κ-C) in real food systems (such as beverages), the understanding of gelation properties of κ-C with the presence of food ingredients is critical. The effects of xylitol and maltitol (up to 30 wt %) on the rheological and structural properties of κ-C were inspected by means of rheometer and Fourier transform infrared (FTIR). With the addition of xylitol, the gelation temperature increased from 44.1 to 57.3 °C, while the gelation temperature increased from 44.1 to 61.4 °C in maltitol systems. With the increasing concentration of both xylitol and maltitol, the values of fractal dimension <i>d<sub>f</sub></i> and complex modulus <i>G</i>* of κ-C increased, while the relaxation exponent <i>n</i> decreased from 0.87 to 0.39 of xylitol and 0.87 to 0.78 of maltitol, respectively. These indicated that the gel networks of aqueous κ-C were improved by the addition of xylitol and maltitol. The FTIR results showed that the interaction between κ-C and these polyols contributed to the increase of hydrogen bonds. The effects of maltitol on κ-C were stronger than those of xylitol because of more equatorial-OH bonds in maltitol. These findings contribute to a better understanding of the gelation processes of κ-C/polyols systems.https://www.mdpi.com/2304-8158/11/1/51carrageenanpolyolrheologythermoreversibilityFourier transform infrared (FTIR) spectroscopypolysaccharide
spellingShingle Min Huang
Yihan Mao
Yuzhu Mao
Hongshun Yang
Xylitol and Maltitol Improve the Rheological Property of Kappa-Carrageenan
Foods
carrageenan
polyol
rheology
thermoreversibility
Fourier transform infrared (FTIR) spectroscopy
polysaccharide
title Xylitol and Maltitol Improve the Rheological Property of Kappa-Carrageenan
title_full Xylitol and Maltitol Improve the Rheological Property of Kappa-Carrageenan
title_fullStr Xylitol and Maltitol Improve the Rheological Property of Kappa-Carrageenan
title_full_unstemmed Xylitol and Maltitol Improve the Rheological Property of Kappa-Carrageenan
title_short Xylitol and Maltitol Improve the Rheological Property of Kappa-Carrageenan
title_sort xylitol and maltitol improve the rheological property of kappa carrageenan
topic carrageenan
polyol
rheology
thermoreversibility
Fourier transform infrared (FTIR) spectroscopy
polysaccharide
url https://www.mdpi.com/2304-8158/11/1/51
work_keys_str_mv AT minhuang xylitolandmaltitolimprovetherheologicalpropertyofkappacarrageenan
AT yihanmao xylitolandmaltitolimprovetherheologicalpropertyofkappacarrageenan
AT yuzhumao xylitolandmaltitolimprovetherheologicalpropertyofkappacarrageenan
AT hongshunyang xylitolandmaltitolimprovetherheologicalpropertyofkappacarrageenan