A Continuous Fixed Bed Adsorption Process for Fez City Urban Wastewater Using Almond Shell Powder: Experimental and Optimization Study
This study deals with the valorization of a biomaterial, almond shell, for the treatment of urban effluents of the city of Fez by a fixed bed column adsorption process. A parametric analysis of the process is carried out with conditions such as particle size, pH and height of the adsorbent bed to ev...
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2022-11-01
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author | Ibtissame Elmansouri Amal Lahkimi Mohammed Kara Anouar Hmamou Ghita El Mouhri Amine Assouguem Mehdi Chaouch Abdulwahed Fahad Alrefaei Mohamed Kamel Lotfi Aleya Mohamed M. Abdel-Daim Noureddine Eloutassi Abderrazzak Adachi Hicham Bekkari |
author_facet | Ibtissame Elmansouri Amal Lahkimi Mohammed Kara Anouar Hmamou Ghita El Mouhri Amine Assouguem Mehdi Chaouch Abdulwahed Fahad Alrefaei Mohamed Kamel Lotfi Aleya Mohamed M. Abdel-Daim Noureddine Eloutassi Abderrazzak Adachi Hicham Bekkari |
author_sort | Ibtissame Elmansouri |
collection | DOAJ |
description | This study deals with the valorization of a biomaterial, almond shell, for the treatment of urban effluents of the city of Fez by a fixed bed column adsorption process. A parametric analysis of the process is carried out with conditions such as particle size, pH and height of the adsorbent bed to evaluate the optimal removal percent and obtain an optimal removal capacity of the adsorbent load. Characterization of the adsorbent prior to continuous adsorption was carried out by X-ray diffraction, Fourier-transform infrared spectrometry and scanning electron microscopy. The adsorption treatment seems to be influenced by certain parameters, such as the particle size of the biomaterial used, the height of the adsorption bed and the pH. The results suggest that this biomaterial can be used as a less expensive, available, biodegradable and very effective adsorbent to eliminate the load of urban waters on a small scale and why not on a large scale to replace chemicals in the treatment and to recover waste such as almond shell. The parameters measured reached maximum values varying between 82% for COD, 79% for EC and 71% for nitrite under well-defined operating conditions, with a particle size of 0.063 mm, a height column height of 7 cm and a pH of 6.5. |
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spelling | doaj.art-66c8a8a443ff45f5add69c690e55fbd42023-11-24T13:50:38ZengMDPI AGCatalysts2073-43442022-11-011212153510.3390/catal12121535A Continuous Fixed Bed Adsorption Process for Fez City Urban Wastewater Using Almond Shell Powder: Experimental and Optimization StudyIbtissame Elmansouri0Amal Lahkimi1Mohammed Kara2Anouar Hmamou3Ghita El Mouhri4Amine Assouguem5Mehdi Chaouch6Abdulwahed Fahad Alrefaei7Mohamed Kamel8Lotfi Aleya9Mohamed M. Abdel-Daim10Noureddine Eloutassi11Abderrazzak Adachi12Hicham Bekkari13Laboratory of Environmental Biotechnology, Agri-Food, Health, Faculty of Sciences, Sidi Mohamed Ben Abdellah University, Fez 30000, MoroccoLaboratory of Engineering, Electrochemistry, Modeling and Environment, Faculty of Sciences Dhar El Mahraz, Sidi Mohamed Ben Abdellah University, B.P. 1796 Atlas, Fez 30000, MoroccoLaboratory of Engineering, Electrochemistry, Modeling and Environment, Faculty of Sciences Dhar El Mahraz, Sidi Mohamed Ben Abdellah University, B.P. 1796 Atlas, Fez 30000, MoroccoLaboratory of Engineering, Electrochemistry, Modeling and Environment, Faculty of Sciences Dhar El Mahraz, Sidi Mohamed Ben Abdellah University, B.P. 1796 Atlas, Fez 30000, MoroccoLaboratory of Biochemistry, Faculty of Medicine and Pharmacy, University of Sidi Mohammed Ben Abdellah, B.P. 1893, Km 22, Road of Sidi Harazem, Fez 30070, MoroccoLaboratory of Functional Ecology and Environment, Faculty of Sciences and Technology, Sidi Mohamed Ben Abdellah University, Imouzzer Street, P.O. Box 2202, Fez 30000, MoroccoLaboratory of Engineering, Electrochemistry, Modeling and Environment, Faculty of Sciences Dhar El Mahraz, Sidi Mohamed Ben Abdellah University, B.P. 1796 Atlas, Fez 30000, MoroccoDepartment of Zoology, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi ArabiaDepartment of Medicine and Infectious Diseases, Faculty of Veterinary Medicine, Cairo University, Giza 12211, EgyptChrono-Environnement Laboratory, UMR CNRS 6249, Franche-Comté University, CEDEX, F-25030 Besançon, FrancePharmacology Department, Faculty of Veterinary Medicine, Suez Canal University, Ismailia 41522, EgyptLaboratory of Engineering, Electrochemistry, Modeling and Environment, Faculty of Sciences Dhar El Mahraz, Sidi Mohamed Ben Abdellah University, B.P. 1796 Atlas, Fez 30000, MoroccoLaboratory of Engineering, Electrochemistry, Modeling and Environment, Faculty of Sciences Dhar El Mahraz, Sidi Mohamed Ben Abdellah University, B.P. 1796 Atlas, Fez 30000, MoroccoLaboratory of Environmental Biotechnology, Agri-Food, Health, Faculty of Sciences, Sidi Mohamed Ben Abdellah University, Fez 30000, MoroccoThis study deals with the valorization of a biomaterial, almond shell, for the treatment of urban effluents of the city of Fez by a fixed bed column adsorption process. A parametric analysis of the process is carried out with conditions such as particle size, pH and height of the adsorbent bed to evaluate the optimal removal percent and obtain an optimal removal capacity of the adsorbent load. Characterization of the adsorbent prior to continuous adsorption was carried out by X-ray diffraction, Fourier-transform infrared spectrometry and scanning electron microscopy. The adsorption treatment seems to be influenced by certain parameters, such as the particle size of the biomaterial used, the height of the adsorption bed and the pH. The results suggest that this biomaterial can be used as a less expensive, available, biodegradable and very effective adsorbent to eliminate the load of urban waters on a small scale and why not on a large scale to replace chemicals in the treatment and to recover waste such as almond shell. The parameters measured reached maximum values varying between 82% for COD, 79% for EC and 71% for nitrite under well-defined operating conditions, with a particle size of 0.063 mm, a height column height of 7 cm and a pH of 6.5.https://www.mdpi.com/2073-4344/12/12/1535biomaterialalmond shellurban effluentsadsorptionFTIRXRD |
spellingShingle | Ibtissame Elmansouri Amal Lahkimi Mohammed Kara Anouar Hmamou Ghita El Mouhri Amine Assouguem Mehdi Chaouch Abdulwahed Fahad Alrefaei Mohamed Kamel Lotfi Aleya Mohamed M. Abdel-Daim Noureddine Eloutassi Abderrazzak Adachi Hicham Bekkari A Continuous Fixed Bed Adsorption Process for Fez City Urban Wastewater Using Almond Shell Powder: Experimental and Optimization Study Catalysts biomaterial almond shell urban effluents adsorption FTIR XRD |
title | A Continuous Fixed Bed Adsorption Process for Fez City Urban Wastewater Using Almond Shell Powder: Experimental and Optimization Study |
title_full | A Continuous Fixed Bed Adsorption Process for Fez City Urban Wastewater Using Almond Shell Powder: Experimental and Optimization Study |
title_fullStr | A Continuous Fixed Bed Adsorption Process for Fez City Urban Wastewater Using Almond Shell Powder: Experimental and Optimization Study |
title_full_unstemmed | A Continuous Fixed Bed Adsorption Process for Fez City Urban Wastewater Using Almond Shell Powder: Experimental and Optimization Study |
title_short | A Continuous Fixed Bed Adsorption Process for Fez City Urban Wastewater Using Almond Shell Powder: Experimental and Optimization Study |
title_sort | continuous fixed bed adsorption process for fez city urban wastewater using almond shell powder experimental and optimization study |
topic | biomaterial almond shell urban effluents adsorption FTIR XRD |
url | https://www.mdpi.com/2073-4344/12/12/1535 |
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