Rhodium-catalyzed asymmetric hydroamination of gem-difluoroallenes with anilines
A rhodium-catalyzed protocol has been established for the enantioselective hydroamination of gem-difluoroallenes with anilines. This strategy shows complete atom-efficiency to access a variety of enantioenriched gem-difluoroallylic amines in excellent branched selectivity (>99:1 for each case), w...
Main Authors: | Xiaowei Han, Yue Zhao, Zhuangzhi Shi, Minyan Wang |
---|---|
Format: | Article |
Language: | English |
Published: |
Elsevier
2022-08-01
|
Series: | Tetrahedron Chem |
Subjects: | |
Online Access: | http://www.sciencedirect.com/science/article/pii/S2666951X22000195 |
Similar Items
-
Rhodium-Catalyzed Dynamic Kinetic Resolution of Racemic Internal Allenes towards Chiral Allylated Triazoles and Tetrazoles
by: Simon V. Sieger, et al.
Published: (2022-10-01) -
Silver Dependent Enantiodivergent Gold(I) Catalysed Asymmetric Intramolecular Hydroamination of Alkenes: A Theoretical Study
by: Ruchi Dixit, et al.
Published: (2022-11-01) -
Jumping in the Chiral Pool: Asymmetric Hydroaminations with Early Metals
by: Sebastian Notz, et al.
Published: (2023-03-01) -
Ketone synthesis via rhodium-catalyzed traceless chelation-controlled hydroacylation reactions
by: Gao, M
Published: (2018) -
Ni(II)-PPP Complexes: From the Hydroamination of Activated Olefins to the Synthesis of ?-Amino Acids
by: Luca Fadini, et al.
Published: (2004-04-01)