Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes
Actinide electronic structure determination is fundamentally challenging. Here, the authors assemble a family of uranium(V)-nitrides and quantify the electronic structure of the molecules, defining the relative importance of spin orbit coupling and crystal field interactions.
| Main Authors: | , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Portfolio
2016-12-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/ncomms13773 |
| _version_ | 1818842127151398912 |
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| author | David M. King Peter A. Cleaves Ashley J. Wooles Benedict M. Gardner Nicholas F. Chilton Floriana Tuna William Lewis Eric J. L. McInnes Stephen T. Liddle |
| author_facet | David M. King Peter A. Cleaves Ashley J. Wooles Benedict M. Gardner Nicholas F. Chilton Floriana Tuna William Lewis Eric J. L. McInnes Stephen T. Liddle |
| author_sort | David M. King |
| collection | DOAJ |
| description | Actinide electronic structure determination is fundamentally challenging. Here, the authors assemble a family of uranium(V)-nitrides and quantify the electronic structure of the molecules, defining the relative importance of spin orbit coupling and crystal field interactions. |
| first_indexed | 2024-12-19T04:37:02Z |
| format | Article |
| id | doaj.art-66f8a8d3e96e426c8bc9a7569f50dc52 |
| institution | Directory Open Access Journal |
| issn | 2041-1723 |
| language | English |
| last_indexed | 2024-12-19T04:37:02Z |
| publishDate | 2016-12-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Nature Communications |
| spelling | doaj.art-66f8a8d3e96e426c8bc9a7569f50dc522022-12-21T20:35:43ZengNature PortfolioNature Communications2041-17232016-12-017111410.1038/ncomms13773Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexesDavid M. King0Peter A. Cleaves1Ashley J. Wooles2Benedict M. Gardner3Nicholas F. Chilton4Floriana Tuna5William Lewis6Eric J. L. McInnes7Stephen T. Liddle8School of Chemistry, University of NottinghamSchool of Chemistry, University of ManchesterSchool of Chemistry, University of ManchesterSchool of Chemistry, University of ManchesterSchool of Chemistry, University of ManchesterSchool of Chemistry and Photon Science Institute, University of ManchesterSchool of Chemistry, University of NottinghamSchool of Chemistry and Photon Science Institute, University of ManchesterSchool of Chemistry, University of ManchesterActinide electronic structure determination is fundamentally challenging. Here, the authors assemble a family of uranium(V)-nitrides and quantify the electronic structure of the molecules, defining the relative importance of spin orbit coupling and crystal field interactions.https://doi.org/10.1038/ncomms13773 |
| spellingShingle | David M. King Peter A. Cleaves Ashley J. Wooles Benedict M. Gardner Nicholas F. Chilton Floriana Tuna William Lewis Eric J. L. McInnes Stephen T. Liddle Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes Nature Communications |
| title | Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes |
| title_full | Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes |
| title_fullStr | Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes |
| title_full_unstemmed | Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes |
| title_short | Molecular and electronic structure of terminal and alkali metal-capped uranium(V) nitride complexes |
| title_sort | molecular and electronic structure of terminal and alkali metal capped uranium v nitride complexes |
| url | https://doi.org/10.1038/ncomms13773 |
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