CHEMICAL COMPOSITIONS OF PINE RESIN, ROSIN AND TURPENTINE OIL FROM WEST JAVA

This study was conducted to identify chemical composition of merkus pine resin, rosin and turpentine oil. Initially, pine resin was separated into neutral and acidic fractions with an aqueous 4% sodium hydroxide solution. After methylation, the fraction containing turpentine oil and rosin were analy...

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Main Authors: Bambang Wiyono, Sanro Tachibana, Djaban Tinambunan
Format: Article
Language:English
Published: Ministry of Environment and Forestry 2006-03-01
Series:Indonesian Journal of Forestry Research
Subjects:
Online Access:http://ejournal.forda-mof.org/ejournal-litbang/index.php/IJFR/article/view/443
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author Bambang Wiyono
Sanro Tachibana
Djaban Tinambunan
author_facet Bambang Wiyono
Sanro Tachibana
Djaban Tinambunan
author_sort Bambang Wiyono
collection DOAJ
description This study was conducted to identify chemical composition of merkus pine resin, rosin and turpentine oil. Initially, pine resin was separated into neutral and acidic fractions with an aqueous 4% sodium hydroxide solution. After methylation, the fraction containing turpentine oil and rosin were analyzed by gas chromatography (GC), and gas chromatograph mass spectrometry (GC-MS), respectively. The neutral fraction of pine resin and turpentine oil mainly consisted of a-pinene, D-3-carene and b-pinene. Based on mass spectral comparison, the major constituents of the acidic fraction and rosin were identified as sandaracopimaric acid, isopimaric acid, palustric acid, dehydroabietic acid, abietic acid, neoabietic acid, and merkusic acid. The major component of the acidic fractions was palustric acid, while that of rosin was abietic acid. Using TC (tough column) 1 and TC 5 columns, levopimaric acid could not be separated from rosin or acidic fraction of pine resin of Indonesian Pinus merkusii.
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spelling doaj.art-6706888b77b149d4b8d97a36f6e098742022-12-22T03:21:10ZengMinistry of Environment and ForestryIndonesian Journal of Forestry Research2355-70792406-81952006-03-013171710.20886/ijfr.2006.3.1.7-17443CHEMICAL COMPOSITIONS OF PINE RESIN, ROSIN AND TURPENTINE OIL FROM WEST JAVABambang Wiyono0Sanro Tachibana1Djaban Tinambunan2Forest Products Research and Development CenterFaculty of Agricuitw:e, Ehime University, 3-5-7 Tarumi, Matsuyama, Ehime, 790-8566Forest Products Research and Development CenterThis study was conducted to identify chemical composition of merkus pine resin, rosin and turpentine oil. Initially, pine resin was separated into neutral and acidic fractions with an aqueous 4% sodium hydroxide solution. After methylation, the fraction containing turpentine oil and rosin were analyzed by gas chromatography (GC), and gas chromatograph mass spectrometry (GC-MS), respectively. The neutral fraction of pine resin and turpentine oil mainly consisted of a-pinene, D-3-carene and b-pinene. Based on mass spectral comparison, the major constituents of the acidic fraction and rosin were identified as sandaracopimaric acid, isopimaric acid, palustric acid, dehydroabietic acid, abietic acid, neoabietic acid, and merkusic acid. The major component of the acidic fractions was palustric acid, while that of rosin was abietic acid. Using TC (tough column) 1 and TC 5 columns, levopimaric acid could not be separated from rosin or acidic fraction of pine resin of Indonesian Pinus merkusii.http://ejournal.forda-mof.org/ejournal-litbang/index.php/IJFR/article/view/443Pinus merkusii, turpentine oil, rosin, neutral fraction, acidic fraction
spellingShingle Bambang Wiyono
Sanro Tachibana
Djaban Tinambunan
CHEMICAL COMPOSITIONS OF PINE RESIN, ROSIN AND TURPENTINE OIL FROM WEST JAVA
Indonesian Journal of Forestry Research
Pinus merkusii, turpentine oil, rosin, neutral fraction, acidic fraction
title CHEMICAL COMPOSITIONS OF PINE RESIN, ROSIN AND TURPENTINE OIL FROM WEST JAVA
title_full CHEMICAL COMPOSITIONS OF PINE RESIN, ROSIN AND TURPENTINE OIL FROM WEST JAVA
title_fullStr CHEMICAL COMPOSITIONS OF PINE RESIN, ROSIN AND TURPENTINE OIL FROM WEST JAVA
title_full_unstemmed CHEMICAL COMPOSITIONS OF PINE RESIN, ROSIN AND TURPENTINE OIL FROM WEST JAVA
title_short CHEMICAL COMPOSITIONS OF PINE RESIN, ROSIN AND TURPENTINE OIL FROM WEST JAVA
title_sort chemical compositions of pine resin rosin and turpentine oil from west java
topic Pinus merkusii, turpentine oil, rosin, neutral fraction, acidic fraction
url http://ejournal.forda-mof.org/ejournal-litbang/index.php/IJFR/article/view/443
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AT sanrotachibana chemicalcompositionsofpineresinrosinandturpentineoilfromwestjava
AT djabantinambunan chemicalcompositionsofpineresinrosinandturpentineoilfromwestjava