Research on the Diffusion Behavior of Cu in Low-Carbon Steel under High Temperatures

The effective diffusion of Cu in Fe is the key to forming a stable transition layer between copper and low-carbon steel, but it is seriously affected by several factors, especially temperature, and the diffusion of Cu can only be completed at high temperatures. In order to analyze the diffusion coef...

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Main Authors: Huirong Li, Tao Ma, Yueying He, Yungang Li
Format: Article
Language:English
Published: MDPI AG 2022-01-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/12/2/207
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author Huirong Li
Tao Ma
Yueying He
Yungang Li
author_facet Huirong Li
Tao Ma
Yueying He
Yungang Li
author_sort Huirong Li
collection DOAJ
description The effective diffusion of Cu in Fe is the key to forming a stable transition layer between copper and low-carbon steel, but it is seriously affected by several factors, especially temperature, and the diffusion of Cu can only be completed at high temperatures. In order to analyze the diffusion coefficient of Cu in low-carbon steel under high temperatures, and to obtain the best diffusion temperature range of Cu in steel, the electrodeposition method was used to prepare the diffusion couple of copper and low-carbon steel, which would be annealed under different temperatures for 6 h; meanwhile, the MD models were also used to analyze the diffusion behavior of Cu in Fe at different temperatures. The results show that the diffusion of Cu in low-carbon steel could be realized by high-temperature annealing, and as the temperature increases, the thickness of the Cu/low-carbon steel transition layer shows an increasing trend. When the annealing temperature is between 900 °C and 1000 °C, the thickness of the transition layer increases the fastest. The results of the MD models show that, when the temperature is in the phase transition zone, the main restrictive link for the diffusion of Cu in Fe is the phase transition process of Fe; additionally, when the temperature is higher, the main restrictive link for the diffusion of Cu in Fe is the activity of the atom.
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spelling doaj.art-670fbb3058b644ef88fb94792cbcdae22023-11-23T19:24:39ZengMDPI AGCrystals2073-43522022-01-0112220710.3390/cryst12020207Research on the Diffusion Behavior of Cu in Low-Carbon Steel under High TemperaturesHuirong Li0Tao Ma1Yueying He2Yungang Li3College of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063009, ChinaCollege of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063009, ChinaCollege of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063009, ChinaCollege of Metallurgy and Energy, North China University of Science and Technology, Tangshan 063009, ChinaThe effective diffusion of Cu in Fe is the key to forming a stable transition layer between copper and low-carbon steel, but it is seriously affected by several factors, especially temperature, and the diffusion of Cu can only be completed at high temperatures. In order to analyze the diffusion coefficient of Cu in low-carbon steel under high temperatures, and to obtain the best diffusion temperature range of Cu in steel, the electrodeposition method was used to prepare the diffusion couple of copper and low-carbon steel, which would be annealed under different temperatures for 6 h; meanwhile, the MD models were also used to analyze the diffusion behavior of Cu in Fe at different temperatures. The results show that the diffusion of Cu in low-carbon steel could be realized by high-temperature annealing, and as the temperature increases, the thickness of the Cu/low-carbon steel transition layer shows an increasing trend. When the annealing temperature is between 900 °C and 1000 °C, the thickness of the transition layer increases the fastest. The results of the MD models show that, when the temperature is in the phase transition zone, the main restrictive link for the diffusion of Cu in Fe is the phase transition process of Fe; additionally, when the temperature is higher, the main restrictive link for the diffusion of Cu in Fe is the activity of the atom.https://www.mdpi.com/2073-4352/12/2/207Culow-carbon steeldiffusion coefficientmolecular dynamicshigh-temperature annealing
spellingShingle Huirong Li
Tao Ma
Yueying He
Yungang Li
Research on the Diffusion Behavior of Cu in Low-Carbon Steel under High Temperatures
Crystals
Cu
low-carbon steel
diffusion coefficient
molecular dynamics
high-temperature annealing
title Research on the Diffusion Behavior of Cu in Low-Carbon Steel under High Temperatures
title_full Research on the Diffusion Behavior of Cu in Low-Carbon Steel under High Temperatures
title_fullStr Research on the Diffusion Behavior of Cu in Low-Carbon Steel under High Temperatures
title_full_unstemmed Research on the Diffusion Behavior of Cu in Low-Carbon Steel under High Temperatures
title_short Research on the Diffusion Behavior of Cu in Low-Carbon Steel under High Temperatures
title_sort research on the diffusion behavior of cu in low carbon steel under high temperatures
topic Cu
low-carbon steel
diffusion coefficient
molecular dynamics
high-temperature annealing
url https://www.mdpi.com/2073-4352/12/2/207
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AT taoma researchonthediffusionbehaviorofcuinlowcarbonsteelunderhightemperatures
AT yueyinghe researchonthediffusionbehaviorofcuinlowcarbonsteelunderhightemperatures
AT yungangli researchonthediffusionbehaviorofcuinlowcarbonsteelunderhightemperatures