[μ-Bis(diphenylphosphino)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)arsine-3κAs]-triangulo-triruthenium(0)
In the title triangulo-triruthenium compound, [Ru3(C21H21As)(C25H22P2)(CO)9], the bis(diphenylphosphino)methane ligand bridges an Ru—Ru bond and the monodentate arsine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru3 triang...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809046704 |
| _version_ | 1818999172012965888 |
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| author | Hoong-Kun Fun Chin Sing Yeap Imthyaz Ahmed Khan Omar bin Shawkataly |
| author_facet | Hoong-Kun Fun Chin Sing Yeap Imthyaz Ahmed Khan Omar bin Shawkataly |
| author_sort | Hoong-Kun Fun |
| collection | DOAJ |
| description | In the title triangulo-triruthenium compound, [Ru3(C21H21As)(C25H22P2)(CO)9], the bis(diphenylphosphino)methane ligand bridges an Ru—Ru bond and the monodentate arsine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru3 triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three arsine-substituted phenyl rings make dihedral angles of 87.36 (10), 81.96 (10) and 73.37 (11)° with each other. The dihedral angles between the two phenyl rings are 88.08 (12) and 80.15 (10)° for the two diphenylphosphino groups. In the crystal packing, the molecules are linked together as dimers via intermolecular C—H...O hydrogen bonds. These dimers are stacked down b axis. Intermolecular C—H...π and π–π interactions [centroid–centroid distance = 3.6383 (13) Å] further stabilize the crystal structure. |
| first_indexed | 2024-12-20T22:13:11Z |
| format | Article |
| id | doaj.art-67144787cac34905b198b4a577bb9156 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T22:13:11Z |
| publishDate | 2009-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-67144787cac34905b198b4a577bb91562022-12-21T19:25:06ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-12-016512m1622m162310.1107/S1600536809046704[μ-Bis(diphenylphosphino)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)arsine-3κAs]-triangulo-triruthenium(0)Hoong-Kun FunChin Sing YeapImthyaz Ahmed KhanOmar bin ShawkatalyIn the title triangulo-triruthenium compound, [Ru3(C21H21As)(C25H22P2)(CO)9], the bis(diphenylphosphino)methane ligand bridges an Ru—Ru bond and the monodentate arsine ligand bonds to the third Ru atom. Both the phosphine and arsine ligands are equatorial with respect to the Ru3 triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three arsine-substituted phenyl rings make dihedral angles of 87.36 (10), 81.96 (10) and 73.37 (11)° with each other. The dihedral angles between the two phenyl rings are 88.08 (12) and 80.15 (10)° for the two diphenylphosphino groups. In the crystal packing, the molecules are linked together as dimers via intermolecular C—H...O hydrogen bonds. These dimers are stacked down b axis. Intermolecular C—H...π and π–π interactions [centroid–centroid distance = 3.6383 (13) Å] further stabilize the crystal structure.http://scripts.iucr.org/cgi-bin/paper?S1600536809046704 |
| spellingShingle | Hoong-Kun Fun Chin Sing Yeap Imthyaz Ahmed Khan Omar bin Shawkataly [μ-Bis(diphenylphosphino)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)arsine-3κAs]-triangulo-triruthenium(0) Acta Crystallographica Section E |
| title | [μ-Bis(diphenylphosphino)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)arsine-3κAs]-triangulo-triruthenium(0) |
| title_full | [μ-Bis(diphenylphosphino)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)arsine-3κAs]-triangulo-triruthenium(0) |
| title_fullStr | [μ-Bis(diphenylphosphino)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)arsine-3κAs]-triangulo-triruthenium(0) |
| title_full_unstemmed | [μ-Bis(diphenylphosphino)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)arsine-3κAs]-triangulo-triruthenium(0) |
| title_short | [μ-Bis(diphenylphosphino)methane-1:2κ2P:P′]nonacarbonyl-1κ3C,2κ3C,3κ3C-[tris(4-methylphenyl)arsine-3κAs]-triangulo-triruthenium(0) |
| title_sort | amp 956 bis diphenylphosphino methane 1 2 amp 954 2p p amp 8242 nonacarbonyl 1 amp 954 3c 2 amp 954 3c 3 amp 954 3c tris 4 methylphenyl arsine 3 amp 954 as triangulo triruthenium 0 |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809046704 |
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