A polymeric oxovanadium(IV) pyromellitate complex
The reaction of oxovanadium(IV) sulphate with 1,2,4,5-benzenetetracarboxylic acid (pyromellitic acid) in the presence of potassium carbonate yields a polymeric complex, K2[VO(pyr)]·6H2O (I) [pyr = pyromellitate(4-) ion]. The PM3(tm) calculations and IR spectroscopy suggest that the polymeric structu...
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| Format: | Article |
| Language: | English |
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Serbian Chemical Society
1999-09-01
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| Series: | Journal of the Serbian Chemical Society |
| Subjects: | |
| Online Access: | http://www.shd.org.yu/HtDocs/SHD/Vol64/No9-Pdf/V64-no9-03.zip |
| _version_ | 1818346267328118784 |
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| author | DJORDJE STOJAKOVIC DUSANKA D. VASOVIC |
| author_facet | DJORDJE STOJAKOVIC DUSANKA D. VASOVIC |
| author_sort | DJORDJE STOJAKOVIC |
| collection | DOAJ |
| description | The reaction of oxovanadium(IV) sulphate with 1,2,4,5-benzenetetracarboxylic acid (pyromellitic acid) in the presence of potassium carbonate yields a polymeric complex, K2[VO(pyr)]·6H2O (I) [pyr = pyromellitate(4-) ion]. The PM3(tm) calculations and IR spectroscopy suggest that the polymeric structure of I consists of -V-pyr-V-pyr- chains formed by the 1,4- or 1,5-bridging by the pyr ions. The chains are additionally cross-linked by the chelate function of one of the COO- groups of the pyr ion. Magnetic measurements do not reveal the presence of antiferromagnetic coupling between the V centers. |
| first_indexed | 2024-12-13T17:15:33Z |
| format | Article |
| id | doaj.art-677ccc407a61414c814704a66ece0fc5 |
| institution | Directory Open Access Journal |
| issn | 0352-5139 |
| language | English |
| last_indexed | 2024-12-13T17:15:33Z |
| publishDate | 1999-09-01 |
| publisher | Serbian Chemical Society |
| record_format | Article |
| series | Journal of the Serbian Chemical Society |
| spelling | doaj.art-677ccc407a61414c814704a66ece0fc52022-12-21T23:37:26ZengSerbian Chemical SocietyJournal of the Serbian Chemical Society0352-51391999-09-01649513518A polymeric oxovanadium(IV) pyromellitate complexDJORDJE STOJAKOVICDUSANKA D. VASOVICThe reaction of oxovanadium(IV) sulphate with 1,2,4,5-benzenetetracarboxylic acid (pyromellitic acid) in the presence of potassium carbonate yields a polymeric complex, K2[VO(pyr)]·6H2O (I) [pyr = pyromellitate(4-) ion]. The PM3(tm) calculations and IR spectroscopy suggest that the polymeric structure of I consists of -V-pyr-V-pyr- chains formed by the 1,4- or 1,5-bridging by the pyr ions. The chains are additionally cross-linked by the chelate function of one of the COO- groups of the pyr ion. Magnetic measurements do not reveal the presence of antiferromagnetic coupling between the V centers.http://www.shd.org.yu/HtDocs/SHD/Vol64/No9-Pdf/V64-no9-03.zipoxovanadium(IV) complexespyromellitic acidpolymeric structurePM3(tm) calculations |
| spellingShingle | DJORDJE STOJAKOVIC DUSANKA D. VASOVIC A polymeric oxovanadium(IV) pyromellitate complex Journal of the Serbian Chemical Society oxovanadium(IV) complexes pyromellitic acid polymeric structure PM3(tm) calculations |
| title | A polymeric oxovanadium(IV) pyromellitate complex |
| title_full | A polymeric oxovanadium(IV) pyromellitate complex |
| title_fullStr | A polymeric oxovanadium(IV) pyromellitate complex |
| title_full_unstemmed | A polymeric oxovanadium(IV) pyromellitate complex |
| title_short | A polymeric oxovanadium(IV) pyromellitate complex |
| title_sort | polymeric oxovanadium iv pyromellitate complex |
| topic | oxovanadium(IV) complexes pyromellitic acid polymeric structure PM3(tm) calculations |
| url | http://www.shd.org.yu/HtDocs/SHD/Vol64/No9-Pdf/V64-no9-03.zip |
| work_keys_str_mv | AT djordjestojakovic apolymericoxovanadiumivpyromellitatecomplex AT dusankadvasovic apolymericoxovanadiumivpyromellitatecomplex AT djordjestojakovic polymericoxovanadiumivpyromellitatecomplex AT dusankadvasovic polymericoxovanadiumivpyromellitatecomplex |