Solid state transformation of non-equilibrium Ni-Sn powder with a eutectic composition

Solid state transformation of supersaturated solid solution to anomalous Ni-Sn eutectic has been studied. The metastableNi-Sn solid solution was prepared via mechanical alloying of a mixed Ni+Sn powder containing 32.5 wt-% Sn powder.The milling conditions included ball to powder ratio (BPR) of 5:1 a...

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Main Authors: Ruangdaj Tongsri, Nattaya Tosangthum
Format: Article
Language:English
Published: Prince of Songkla University 2011-04-01
Series:Songklanakarin Journal of Science and Technology (SJST)
Subjects:
Online Access:http://rdo.psu.ac.th/sjstweb/journal/33-2/0125-3395-33-2-209-214.pdf
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author Ruangdaj Tongsri
Nattaya Tosangthum
author_facet Ruangdaj Tongsri
Nattaya Tosangthum
author_sort Ruangdaj Tongsri
collection DOAJ
description Solid state transformation of supersaturated solid solution to anomalous Ni-Sn eutectic has been studied. The metastableNi-Sn solid solution was prepared via mechanical alloying of a mixed Ni+Sn powder containing 32.5 wt-% Sn powder.The milling conditions included ball to powder ratio (BPR) of 5:1 and milling speed of 300 rpm. Milling times were varied as5, 15, and 25 hours. Milling the mixed powder for longer than 15 hours resulted in formation of supersaturated Ni-Sn solidsolution. Differential thermal analysis of the supersaturated Ni-Sn solid solution revealed two reactions, namely peritectoidand peritectic reactions, occurring at 945 and 1,141°C, respectively. Heating of the supersaturated Ni-Sn solid solution todifferent temperatures such as 800, 850, 900, 950, 1,100, and 1,140°C with holding time of 10 minutes resulted in developmentof anomalous eutectic with Ni3Sn phase matrix embedded with Ni solution particles. Sintering and coarsening of the eutecticwas depending on heating temperatures.
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spelling doaj.art-67858e2013c74036920a3eb5314581142022-12-21T17:43:05ZengPrince of Songkla UniversitySongklanakarin Journal of Science and Technology (SJST)0125-33952011-04-01332209214Solid state transformation of non-equilibrium Ni-Sn powder with a eutectic compositionRuangdaj TongsriNattaya TosangthumSolid state transformation of supersaturated solid solution to anomalous Ni-Sn eutectic has been studied. The metastableNi-Sn solid solution was prepared via mechanical alloying of a mixed Ni+Sn powder containing 32.5 wt-% Sn powder.The milling conditions included ball to powder ratio (BPR) of 5:1 and milling speed of 300 rpm. Milling times were varied as5, 15, and 25 hours. Milling the mixed powder for longer than 15 hours resulted in formation of supersaturated Ni-Sn solidsolution. Differential thermal analysis of the supersaturated Ni-Sn solid solution revealed two reactions, namely peritectoidand peritectic reactions, occurring at 945 and 1,141°C, respectively. Heating of the supersaturated Ni-Sn solid solution todifferent temperatures such as 800, 850, 900, 950, 1,100, and 1,140°C with holding time of 10 minutes resulted in developmentof anomalous eutectic with Ni3Sn phase matrix embedded with Ni solution particles. Sintering and coarsening of the eutecticwas depending on heating temperatures.http://rdo.psu.ac.th/sjstweb/journal/33-2/0125-3395-33-2-209-214.pdfmechanical millinganomalous N-Sn eutecticsolid state transformation
spellingShingle Ruangdaj Tongsri
Nattaya Tosangthum
Solid state transformation of non-equilibrium Ni-Sn powder with a eutectic composition
Songklanakarin Journal of Science and Technology (SJST)
mechanical milling
anomalous N-Sn eutectic
solid state transformation
title Solid state transformation of non-equilibrium Ni-Sn powder with a eutectic composition
title_full Solid state transformation of non-equilibrium Ni-Sn powder with a eutectic composition
title_fullStr Solid state transformation of non-equilibrium Ni-Sn powder with a eutectic composition
title_full_unstemmed Solid state transformation of non-equilibrium Ni-Sn powder with a eutectic composition
title_short Solid state transformation of non-equilibrium Ni-Sn powder with a eutectic composition
title_sort solid state transformation of non equilibrium ni sn powder with a eutectic composition
topic mechanical milling
anomalous N-Sn eutectic
solid state transformation
url http://rdo.psu.ac.th/sjstweb/journal/33-2/0125-3395-33-2-209-214.pdf
work_keys_str_mv AT ruangdajtongsri solidstatetransformationofnonequilibriumnisnpowderwithaeutecticcomposition
AT nattayatosangthum solidstatetransformationofnonequilibriumnisnpowderwithaeutecticcomposition