Impact of high volume E.M.D. residue on the corrosion resistance and mechanical properties of construction materials in sulfate environment

This study examines the potential use of Electrolytic Manganese Dioxide (EMD) residue as a replacement of cement (20%wt by cement weight) in construction materials to provide anticorrosion protection on reinforcing steel and improve the strength of cementitious materials under sulfate attack. To ass...

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Main Authors: Nikolaos Chousidis, Stylianos Polymenis, George Batis
Format: Article
Language:English
Published: IOP Publishing 2023-01-01
Series:Materials Research Express
Subjects:
Online Access:https://doi.org/10.1088/2053-1591/acd61c
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author Nikolaos Chousidis
Stylianos Polymenis
George Batis
author_facet Nikolaos Chousidis
Stylianos Polymenis
George Batis
author_sort Nikolaos Chousidis
collection DOAJ
description This study examines the potential use of Electrolytic Manganese Dioxide (EMD) residue as a replacement of cement (20%wt by cement weight) in construction materials to provide anticorrosion protection on reinforcing steel and improve the strength of cementitious materials under sulfate attack. To assess the corrosion parameters, the constructed building materials were immersed in a 5%wt sulfate salt (Na _2 SO _4 ), while concrete samples incorporating 20%wt EMD were prepared and subjected to mechanical, porosity and thermal tests. Moreover, SEM images were obtained in order to examine the microstructure of concrete and the extent of damage caused by sulfate ions. The results demonstrate that the inclusion of EMD caused a notable rise in the corrosion of steel bars within cement mortars, as well as a decrease in the mechanical strength of the building materials. Overall, the experimental outcomes of the study suggest that the incorporation of high volume (20%wt) EMD residue leads to the degradation of all measured properties.
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spelling doaj.art-6786d2e4ad6346e88f65ef22b85db7d82023-08-09T16:09:25ZengIOP PublishingMaterials Research Express2053-15912023-01-0110505650810.1088/2053-1591/acd61cImpact of high volume E.M.D. residue on the corrosion resistance and mechanical properties of construction materials in sulfate environmentNikolaos Chousidis0https://orcid.org/0000-0002-8160-7028Stylianos Polymenis1George Batis2https://orcid.org/0000-0001-7764-8604School of Chemical Engineering, Department of Materials Science and Engineering, National Technical University of Athens , Iroon Polytechneiou 9, Zografou 157 72, Athens, GreeceSchool of Chemical Engineering, Department of Materials Science and Engineering, National Technical University of Athens , Iroon Polytechneiou 9, Zografou 157 72, Athens, GreeceSchool of Chemical Engineering, Department of Materials Science and Engineering, National Technical University of Athens , Iroon Polytechneiou 9, Zografou 157 72, Athens, GreeceThis study examines the potential use of Electrolytic Manganese Dioxide (EMD) residue as a replacement of cement (20%wt by cement weight) in construction materials to provide anticorrosion protection on reinforcing steel and improve the strength of cementitious materials under sulfate attack. To assess the corrosion parameters, the constructed building materials were immersed in a 5%wt sulfate salt (Na _2 SO _4 ), while concrete samples incorporating 20%wt EMD were prepared and subjected to mechanical, porosity and thermal tests. Moreover, SEM images were obtained in order to examine the microstructure of concrete and the extent of damage caused by sulfate ions. The results demonstrate that the inclusion of EMD caused a notable rise in the corrosion of steel bars within cement mortars, as well as a decrease in the mechanical strength of the building materials. Overall, the experimental outcomes of the study suggest that the incorporation of high volume (20%wt) EMD residue leads to the degradation of all measured properties.https://doi.org/10.1088/2053-1591/acd61ccorrosion monitoringcement mortarswaste materialsmechanical propertiesporositymicrostructure of mortars
spellingShingle Nikolaos Chousidis
Stylianos Polymenis
George Batis
Impact of high volume E.M.D. residue on the corrosion resistance and mechanical properties of construction materials in sulfate environment
Materials Research Express
corrosion monitoring
cement mortars
waste materials
mechanical properties
porosity
microstructure of mortars
title Impact of high volume E.M.D. residue on the corrosion resistance and mechanical properties of construction materials in sulfate environment
title_full Impact of high volume E.M.D. residue on the corrosion resistance and mechanical properties of construction materials in sulfate environment
title_fullStr Impact of high volume E.M.D. residue on the corrosion resistance and mechanical properties of construction materials in sulfate environment
title_full_unstemmed Impact of high volume E.M.D. residue on the corrosion resistance and mechanical properties of construction materials in sulfate environment
title_short Impact of high volume E.M.D. residue on the corrosion resistance and mechanical properties of construction materials in sulfate environment
title_sort impact of high volume e m d residue on the corrosion resistance and mechanical properties of construction materials in sulfate environment
topic corrosion monitoring
cement mortars
waste materials
mechanical properties
porosity
microstructure of mortars
url https://doi.org/10.1088/2053-1591/acd61c
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AT stylianospolymenis impactofhighvolumeemdresidueonthecorrosionresistanceandmechanicalpropertiesofconstructionmaterialsinsulfateenvironment
AT georgebatis impactofhighvolumeemdresidueonthecorrosionresistanceandmechanicalpropertiesofconstructionmaterialsinsulfateenvironment