Field-Induced Slow Magnetic Relaxation of Mono- and Dinuclear Dysprosium(III) Complexes Coordinated by a Chloranilate with Different Resonance Forms

Field-Induced Slow Magnetic Relaxation of Mono- and Dinuclear Dysprosium(III) Complexes Coordinated by a Chloranilate with Different Resonance Forms

We synthesized the dinuclear and mononuclear dysprosium(III) complexes [{Dy(Tp)2}2(Cl2An)]·2CH2Cl2 (1) and [Co(Cp)2][Dy(Tp)2(Cl2An)] (3), where Cl2An2− and Tp− are the chloranilate and hydrotris(pyrazolyl)borate ligand, respectively. In addition, the magnitude of the magnetic coupling between the la...

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Bibliographic Details
Main Authors: Ryuta Ishikawa, Shoichi Michiwaki, Takeshi Noda, Keiichi Katoh, Masahiro Yamashita, Kouki Matsubara, Satoshi Kawata
Format: Article
Language:English
Published: MDPI AG 2017-12-01
Series:Inorganics
Subjects:
single-ion magnets
single-molecule magnets
lanthanide ions
slow magnetic relaxation
Online Access:https://www.mdpi.com/2304-6740/6/1/7

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