Green Synthesis of Homogeneous Gold Nanoparticles Using <i>Sargassum</i> spp. Extracts and Their Enhanced Catalytic Activity for Organic Dyes

<i>Sargassum</i> species-based extracts were used to carry out the synthesis of homogeneous gold nanoparticles. Various techniques were used to determine the characteristics and composition of the nanoparticles. The UV-Vis results showed that the 50% water/ethanol extract had the most re...

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Main Authors: J. Luis López-Miranda, Gustavo A. Molina, Rodrigo Esparza, Marlen Alexis González-Reyna, Rodolfo Silva, Miriam Estévez
Format: Article
Language:English
Published: MDPI AG 2021-10-01
Series:Toxics
Subjects:
Online Access:https://www.mdpi.com/2305-6304/9/11/280
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author J. Luis López-Miranda
Gustavo A. Molina
Rodrigo Esparza
Marlen Alexis González-Reyna
Rodolfo Silva
Miriam Estévez
author_facet J. Luis López-Miranda
Gustavo A. Molina
Rodrigo Esparza
Marlen Alexis González-Reyna
Rodolfo Silva
Miriam Estévez
author_sort J. Luis López-Miranda
collection DOAJ
description <i>Sargassum</i> species-based extracts were used to carry out the synthesis of homogeneous gold nanoparticles. Various techniques were used to determine the characteristics and composition of the nanoparticles. The UV-Vis results showed that the 50% water/ethanol extract had the most reducing agents and stabilizers. Therefore, this type of extract was used to synthesize nanoparticles and for their subsequent characterization. Crystallinity and crystal size were evaluated using X-ray diffraction. Size and morphology were analyzed using scanning electron microscopy, showing that the gold nanoparticles were mostly spherical, with a size range of 15–30 nm. The catalytic activity of the gold nanoparticles was evaluated through the degradation of organic dyes: methylene blue, methyl orange, and methyl red. The degradation rates were different, depending on the nature of each dye, the simplest to degrade was methylene blue and methyl red was the most difficult to degrade. The results indicated that the use of <i>Sargassum</i> spp. for the synthesis of gold nanoparticles has potential in the remediation of water that is contaminated with organic dyes. Moreover, given the recent serious environmental and economic problems caused by the overpopulation of <i>Sargassum</i> spp. in the Mexican Caribbean, the findings hold promise for their practical and sustainable use in the synthesis of nanomaterials.
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spelling doaj.art-67b11ed561994bd79381f2ad4fd227c72023-11-23T01:47:39ZengMDPI AGToxics2305-63042021-10-0191128010.3390/toxics9110280Green Synthesis of Homogeneous Gold Nanoparticles Using <i>Sargassum</i> spp. Extracts and Their Enhanced Catalytic Activity for Organic DyesJ. Luis López-Miranda0Gustavo A. Molina1Rodrigo Esparza2Marlen Alexis González-Reyna3Rodolfo Silva4Miriam Estévez5Centro de Física Aplicada y Tecnología Avanzada, Universidad Nacional Autónoma de México, Boulevard Juriquilla 3001, Querétaro 76230, MexicoCentro de Física Aplicada y Tecnología Avanzada, Universidad Nacional Autónoma de México, Boulevard Juriquilla 3001, Querétaro 76230, MexicoCentro de Física Aplicada y Tecnología Avanzada, Universidad Nacional Autónoma de México, Boulevard Juriquilla 3001, Querétaro 76230, MexicoCentro de Física Aplicada y Tecnología Avanzada, Universidad Nacional Autónoma de México, Boulevard Juriquilla 3001, Querétaro 76230, MexicoInstituto de Ingeniería, Universidad Nacional Autónoma de México, Edificio 17, Ciudad Universitaria, Coyoacán, Mexico City 04510, MexicoCentro de Física Aplicada y Tecnología Avanzada, Universidad Nacional Autónoma de México, Boulevard Juriquilla 3001, Querétaro 76230, Mexico<i>Sargassum</i> species-based extracts were used to carry out the synthesis of homogeneous gold nanoparticles. Various techniques were used to determine the characteristics and composition of the nanoparticles. The UV-Vis results showed that the 50% water/ethanol extract had the most reducing agents and stabilizers. Therefore, this type of extract was used to synthesize nanoparticles and for their subsequent characterization. Crystallinity and crystal size were evaluated using X-ray diffraction. Size and morphology were analyzed using scanning electron microscopy, showing that the gold nanoparticles were mostly spherical, with a size range of 15–30 nm. The catalytic activity of the gold nanoparticles was evaluated through the degradation of organic dyes: methylene blue, methyl orange, and methyl red. The degradation rates were different, depending on the nature of each dye, the simplest to degrade was methylene blue and methyl red was the most difficult to degrade. The results indicated that the use of <i>Sargassum</i> spp. for the synthesis of gold nanoparticles has potential in the remediation of water that is contaminated with organic dyes. Moreover, given the recent serious environmental and economic problems caused by the overpopulation of <i>Sargassum</i> spp. in the Mexican Caribbean, the findings hold promise for their practical and sustainable use in the synthesis of nanomaterials.https://www.mdpi.com/2305-6304/9/11/280gold nanoparticlesgreen synthesis<i>Sargassum</i> spp.organic dyewater treatment
spellingShingle J. Luis López-Miranda
Gustavo A. Molina
Rodrigo Esparza
Marlen Alexis González-Reyna
Rodolfo Silva
Miriam Estévez
Green Synthesis of Homogeneous Gold Nanoparticles Using <i>Sargassum</i> spp. Extracts and Their Enhanced Catalytic Activity for Organic Dyes
Toxics
gold nanoparticles
green synthesis
<i>Sargassum</i> spp.
organic dye
water treatment
title Green Synthesis of Homogeneous Gold Nanoparticles Using <i>Sargassum</i> spp. Extracts and Their Enhanced Catalytic Activity for Organic Dyes
title_full Green Synthesis of Homogeneous Gold Nanoparticles Using <i>Sargassum</i> spp. Extracts and Their Enhanced Catalytic Activity for Organic Dyes
title_fullStr Green Synthesis of Homogeneous Gold Nanoparticles Using <i>Sargassum</i> spp. Extracts and Their Enhanced Catalytic Activity for Organic Dyes
title_full_unstemmed Green Synthesis of Homogeneous Gold Nanoparticles Using <i>Sargassum</i> spp. Extracts and Their Enhanced Catalytic Activity for Organic Dyes
title_short Green Synthesis of Homogeneous Gold Nanoparticles Using <i>Sargassum</i> spp. Extracts and Their Enhanced Catalytic Activity for Organic Dyes
title_sort green synthesis of homogeneous gold nanoparticles using i sargassum i spp extracts and their enhanced catalytic activity for organic dyes
topic gold nanoparticles
green synthesis
<i>Sargassum</i> spp.
organic dye
water treatment
url https://www.mdpi.com/2305-6304/9/11/280
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