Microwave dielectric properties of Li2M2(MoO4)3 (M = Co, Ni) for LTCC applications

Abstract Two low‐firing Li2M2(MoO4)3 (M = Co, Ni) dielectrics were prepared, and their microwave dielectric properties were investigated. The XRD patterns indicated both samples crystallized in an orthorhombic structure with different space groups. The microstructures, lattice parameters, and Raman...

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Main Authors: Cheng‐Liang Huang, Jie‐Ning Liou, Meng‐Hung Tsai, Wen‐Chiao Huang
Format: Article
Language:English
Published: Wiley 2020-05-01
Series:International Journal of Ceramic Engineering & Science
Subjects:
Online Access:https://doi.org/10.1002/ces2.10044
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author Cheng‐Liang Huang
Jie‐Ning Liou
Meng‐Hung Tsai
Wen‐Chiao Huang
author_facet Cheng‐Liang Huang
Jie‐Ning Liou
Meng‐Hung Tsai
Wen‐Chiao Huang
author_sort Cheng‐Liang Huang
collection DOAJ
description Abstract Two low‐firing Li2M2(MoO4)3 (M = Co, Ni) dielectrics were prepared, and their microwave dielectric properties were investigated. The XRD patterns indicated both samples crystallized in an orthorhombic structure with different space groups. The microstructures, lattice parameters, and Raman spectra of these ceramics were also systematically studied. The microwave dielectric properties were obtained with εr ~ 9.1, Q × f ~ 34 000 GHz and τf ~ −72 ppm/°C for Li2Co2(MoO4)3 at 840°C, εr ~ 9.6, Q × f ~ 28 000 GHz and τf ~ −71 ppm/°C for Li2Ni2(MoO4)3 at 660°C. With 0.05 mol% Zn substitution, excellent microwave dielectric properties (εr ~ 10.9, Q × f ~ 56 000 GHz and τf ~ −62 ppm/°C) can be obtained for Li2(Ni0.95Zn0.05)2(MoO4)3 at 660°C, indicating a very promising dielectric for LTCC or ULTCC applications at high frequencies.
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spelling doaj.art-67be261875ad4b9585d7833f5ddcf1a82022-12-22T01:59:30ZengWileyInternational Journal of Ceramic Engineering & Science2578-32702020-05-012313013910.1002/ces2.10044Microwave dielectric properties of Li2M2(MoO4)3 (M = Co, Ni) for LTCC applicationsCheng‐Liang Huang0Jie‐Ning Liou1Meng‐Hung Tsai2Wen‐Chiao Huang3Department of Electrical Engineering National Cheng Kung University Tainan City TaiwanDepartment of Electrical Engineering National Cheng Kung University Tainan City TaiwanDepartment of Electrical Engineering National Cheng Kung University Tainan City TaiwanDepartment of Resource Engineering National Cheng Kung University Tainan City TaiwanAbstract Two low‐firing Li2M2(MoO4)3 (M = Co, Ni) dielectrics were prepared, and their microwave dielectric properties were investigated. The XRD patterns indicated both samples crystallized in an orthorhombic structure with different space groups. The microstructures, lattice parameters, and Raman spectra of these ceramics were also systematically studied. The microwave dielectric properties were obtained with εr ~ 9.1, Q × f ~ 34 000 GHz and τf ~ −72 ppm/°C for Li2Co2(MoO4)3 at 840°C, εr ~ 9.6, Q × f ~ 28 000 GHz and τf ~ −71 ppm/°C for Li2Ni2(MoO4)3 at 660°C. With 0.05 mol% Zn substitution, excellent microwave dielectric properties (εr ~ 10.9, Q × f ~ 56 000 GHz and τf ~ −62 ppm/°C) can be obtained for Li2(Ni0.95Zn0.05)2(MoO4)3 at 660°C, indicating a very promising dielectric for LTCC or ULTCC applications at high frequencies.https://doi.org/10.1002/ces2.10044dielectric materials/propertieselectroceramicsmicrowaves
spellingShingle Cheng‐Liang Huang
Jie‐Ning Liou
Meng‐Hung Tsai
Wen‐Chiao Huang
Microwave dielectric properties of Li2M2(MoO4)3 (M = Co, Ni) for LTCC applications
International Journal of Ceramic Engineering & Science
dielectric materials/properties
electroceramics
microwaves
title Microwave dielectric properties of Li2M2(MoO4)3 (M = Co, Ni) for LTCC applications
title_full Microwave dielectric properties of Li2M2(MoO4)3 (M = Co, Ni) for LTCC applications
title_fullStr Microwave dielectric properties of Li2M2(MoO4)3 (M = Co, Ni) for LTCC applications
title_full_unstemmed Microwave dielectric properties of Li2M2(MoO4)3 (M = Co, Ni) for LTCC applications
title_short Microwave dielectric properties of Li2M2(MoO4)3 (M = Co, Ni) for LTCC applications
title_sort microwave dielectric properties of li2m2 moo4 3 m co ni for ltcc applications
topic dielectric materials/properties
electroceramics
microwaves
url https://doi.org/10.1002/ces2.10044
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AT menghungtsai microwavedielectricpropertiesofli2m2moo43mconiforltccapplications
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