Ionic Liquids-Assisted Ring Opening of Three-Membered Heterocycles with Thio- and Seleno-Silanes
Ring opening reactions of strained heterocycles (epoxides, aziridines, thiiranes) by silyl chalcogenides, such as thiosilanes and selenosilanes, can be efficiently performed in a variety of ionic liquids, which can behave as reaction media and in some cases also as catalysts. This protocol enables a...
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| Format: | Article |
| Language: | English |
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MDPI AG
2022-10-01
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| Series: | Catalysts |
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| Online Access: | https://www.mdpi.com/2073-4344/12/10/1259 |
| _version_ | 1797474373339185152 |
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| author | Damiano Tanini Tommaso Pecchi Nikolai V. Ignat’ev Antonella Capperucci |
| author_facet | Damiano Tanini Tommaso Pecchi Nikolai V. Ignat’ev Antonella Capperucci |
| author_sort | Damiano Tanini |
| collection | DOAJ |
| description | Ring opening reactions of strained heterocycles (epoxides, aziridines, thiiranes) by silyl chalcogenides, such as thiosilanes and selenosilanes, can be efficiently performed in a variety of ionic liquids, which can behave as reaction media and in some cases also as catalysts. This protocol enables an alternative access to β-functionalized sulfides and selenides under mild conditions. |
| first_indexed | 2024-03-09T20:30:06Z |
| format | Article |
| id | doaj.art-67e391d3d39542efb8acb0f798a2b33e |
| institution | Directory Open Access Journal |
| issn | 2073-4344 |
| language | English |
| last_indexed | 2024-03-09T20:30:06Z |
| publishDate | 2022-10-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Catalysts |
| spelling | doaj.art-67e391d3d39542efb8acb0f798a2b33e2023-11-23T23:26:19ZengMDPI AGCatalysts2073-43442022-10-011210125910.3390/catal12101259Ionic Liquids-Assisted Ring Opening of Three-Membered Heterocycles with Thio- and Seleno-SilanesDamiano Tanini0Tommaso Pecchi1Nikolai V. Ignat’ev2Antonella Capperucci3Department of Chemistry “Ugo Schiff”, University of Florence, Sesto Fiorentino, 50019 Florence, ItalyDepartment of Chemistry “Ugo Schiff”, University of Florence, Sesto Fiorentino, 50019 Florence, ItalyInstitut für Anorganische Chemie, Institut für Nachhaltige Chemie & Kataylse mit Bor (ICB), Universität Würzburg, Am Hubland, 97074 Würzburg, GermanyDepartment of Chemistry “Ugo Schiff”, University of Florence, Sesto Fiorentino, 50019 Florence, ItalyRing opening reactions of strained heterocycles (epoxides, aziridines, thiiranes) by silyl chalcogenides, such as thiosilanes and selenosilanes, can be efficiently performed in a variety of ionic liquids, which can behave as reaction media and in some cases also as catalysts. This protocol enables an alternative access to β-functionalized sulfides and selenides under mild conditions.https://www.mdpi.com/2073-4344/12/10/1259ring opening reactionsionic liquidssilyl sulfidessilyl selenidesthiolysisselenolysis |
| spellingShingle | Damiano Tanini Tommaso Pecchi Nikolai V. Ignat’ev Antonella Capperucci Ionic Liquids-Assisted Ring Opening of Three-Membered Heterocycles with Thio- and Seleno-Silanes Catalysts ring opening reactions ionic liquids silyl sulfides silyl selenides thiolysis selenolysis |
| title | Ionic Liquids-Assisted Ring Opening of Three-Membered Heterocycles with Thio- and Seleno-Silanes |
| title_full | Ionic Liquids-Assisted Ring Opening of Three-Membered Heterocycles with Thio- and Seleno-Silanes |
| title_fullStr | Ionic Liquids-Assisted Ring Opening of Three-Membered Heterocycles with Thio- and Seleno-Silanes |
| title_full_unstemmed | Ionic Liquids-Assisted Ring Opening of Three-Membered Heterocycles with Thio- and Seleno-Silanes |
| title_short | Ionic Liquids-Assisted Ring Opening of Three-Membered Heterocycles with Thio- and Seleno-Silanes |
| title_sort | ionic liquids assisted ring opening of three membered heterocycles with thio and seleno silanes |
| topic | ring opening reactions ionic liquids silyl sulfides silyl selenides thiolysis selenolysis |
| url | https://www.mdpi.com/2073-4344/12/10/1259 |
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