Thermal Properties of Eco-Friendly Earthen Materials Stabilized with Bio-Based Polymers: Experimental Data and Modeling Procedure for Improving Mix-Design

The fight against climate change has delineated new objectives, among which one of the most crucial is the replacement of high-energy-intensity materials in the construction sector with more sustainable and thermally efficient alternatives to reduce indirect emissions. Consequently, the thermal prop...

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Main Authors: Marta Cappai, Rizwan Shoukat, Luca Pilia, Roberto Ricciu, Daniele Lai, Gianluca Marongiu, Giorgio Pia
Format: Article
Language:English
Published: MDPI AG 2024-02-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/17/5/1035
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author Marta Cappai
Rizwan Shoukat
Luca Pilia
Roberto Ricciu
Daniele Lai
Gianluca Marongiu
Giorgio Pia
author_facet Marta Cappai
Rizwan Shoukat
Luca Pilia
Roberto Ricciu
Daniele Lai
Gianluca Marongiu
Giorgio Pia
author_sort Marta Cappai
collection DOAJ
description The fight against climate change has delineated new objectives, among which one of the most crucial is the replacement of high-energy-intensity materials in the construction sector with more sustainable and thermally efficient alternatives to reduce indirect emissions. Consequently, the thermal properties of materials assume fundamental importance. In this regard, the large-scale use of earth represents a promising option, not only due to its widespread availability but especially for its minimal embodied energy. However, to enhance its durability, it is necessary to stabilize the mixtures of raw materials. This study analyzes experimental systems based on earth stabilized with bio-based polymers to evaluate their thermal properties and how these vary depending on the selected mix-design. The experimental measurements showed thermal properties comparable to conventional materials. As expected, thermal conductivity increases when porosity decreases. The minimum value is equal to 0.216 W/m·K vs. a porosity of 43.5%, while the maximum is 0.507 W/m·K vs. a porosity of 33.2%. However, the data obtained for individual systems may vary depending on the topological characteristics, which were analyzed through a model for granular materials. The modeling suggests correlations between microstructures and thermal behaviour, which can be useful to develop tools for the mix-design procedure.
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spelling doaj.art-67f5477c7d6a44f08965314de5d9e3582024-03-12T16:49:01ZengMDPI AGMaterials1996-19442024-02-01175103510.3390/ma17051035Thermal Properties of Eco-Friendly Earthen Materials Stabilized with Bio-Based Polymers: Experimental Data and Modeling Procedure for Improving Mix-DesignMarta Cappai0Rizwan Shoukat1Luca Pilia2Roberto Ricciu3Daniele Lai4Gianluca Marongiu5Giorgio Pia6Dipartimento di Ingegneria Meccanica, Chimica e dei Materiali, Università degli Studi di Cagliari, Via Marengo 2, 09123 Cagliari, ItalyDipartimento di Ingegneria Meccanica, Chimica e dei Materiali, Università degli Studi di Cagliari, Via Marengo 2, 09123 Cagliari, ItalyDipartimento di Ingegneria Meccanica, Chimica e dei Materiali, Università degli Studi di Cagliari, Via Marengo 2, 09123 Cagliari, ItalyDipartimento di Ingegneria Civile, Ambientale e Architettura, Università degli Studi di Cagliari, Via Marengo 2, 09123 Cagliari, ItalyDipartimento di Ingegneria Meccanica, Chimica e dei Materiali, Università degli Studi di Cagliari, Via Marengo 2, 09123 Cagliari, ItalyDipartimento di Ingegneria Meccanica, Chimica e dei Materiali, Università degli Studi di Cagliari, Via Marengo 2, 09123 Cagliari, ItalyDipartimento di Ingegneria Meccanica, Chimica e dei Materiali, Università degli Studi di Cagliari, Via Marengo 2, 09123 Cagliari, ItalyThe fight against climate change has delineated new objectives, among which one of the most crucial is the replacement of high-energy-intensity materials in the construction sector with more sustainable and thermally efficient alternatives to reduce indirect emissions. Consequently, the thermal properties of materials assume fundamental importance. In this regard, the large-scale use of earth represents a promising option, not only due to its widespread availability but especially for its minimal embodied energy. However, to enhance its durability, it is necessary to stabilize the mixtures of raw materials. This study analyzes experimental systems based on earth stabilized with bio-based polymers to evaluate their thermal properties and how these vary depending on the selected mix-design. The experimental measurements showed thermal properties comparable to conventional materials. As expected, thermal conductivity increases when porosity decreases. The minimum value is equal to 0.216 W/m·K vs. a porosity of 43.5%, while the maximum is 0.507 W/m·K vs. a porosity of 33.2%. However, the data obtained for individual systems may vary depending on the topological characteristics, which were analyzed through a model for granular materials. The modeling suggests correlations between microstructures and thermal behaviour, which can be useful to develop tools for the mix-design procedure.https://www.mdpi.com/1996-1944/17/5/1035bio-based polymerearth-based materialseco-friendly materialsmix-designmodelingthermal properties
spellingShingle Marta Cappai
Rizwan Shoukat
Luca Pilia
Roberto Ricciu
Daniele Lai
Gianluca Marongiu
Giorgio Pia
Thermal Properties of Eco-Friendly Earthen Materials Stabilized with Bio-Based Polymers: Experimental Data and Modeling Procedure for Improving Mix-Design
Materials
bio-based polymer
earth-based materials
eco-friendly materials
mix-design
modeling
thermal properties
title Thermal Properties of Eco-Friendly Earthen Materials Stabilized with Bio-Based Polymers: Experimental Data and Modeling Procedure for Improving Mix-Design
title_full Thermal Properties of Eco-Friendly Earthen Materials Stabilized with Bio-Based Polymers: Experimental Data and Modeling Procedure for Improving Mix-Design
title_fullStr Thermal Properties of Eco-Friendly Earthen Materials Stabilized with Bio-Based Polymers: Experimental Data and Modeling Procedure for Improving Mix-Design
title_full_unstemmed Thermal Properties of Eco-Friendly Earthen Materials Stabilized with Bio-Based Polymers: Experimental Data and Modeling Procedure for Improving Mix-Design
title_short Thermal Properties of Eco-Friendly Earthen Materials Stabilized with Bio-Based Polymers: Experimental Data and Modeling Procedure for Improving Mix-Design
title_sort thermal properties of eco friendly earthen materials stabilized with bio based polymers experimental data and modeling procedure for improving mix design
topic bio-based polymer
earth-based materials
eco-friendly materials
mix-design
modeling
thermal properties
url https://www.mdpi.com/1996-1944/17/5/1035
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