Surface modification of Pigment Blue 15:3 with aminosilsesquioxane oligomers for enhanced textile printing

Aminopropylsilsesquioxane oligomers (APS) encapsulated PB15:3 are formulated for in situ printing of cellulosic fabric and its blend. The encapsulation was developed by using various APS terminated groups; vinyl-sesquioxane (APSV) and methylsilsesquioxane (APSM) using the liquid-phase separation met...

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Main Authors: H.A Diab, S.A Rashad, O.A Hakeim
Format: Article
Language:Arabic
Published: Arab Association for Islamic Civilization and Art 2017-10-01
Series:Journal of Architecture, Art & Humanistic Science
Subjects:
Online Access:https://mjaf.journals.ekb.eg/article_21735.html
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author H.A Diab
S.A Rashad
O.A Hakeim
author_facet H.A Diab
S.A Rashad
O.A Hakeim
author_sort H.A Diab
collection DOAJ
description Aminopropylsilsesquioxane oligomers (APS) encapsulated PB15:3 are formulated for in situ printing of cellulosic fabric and its blend. The encapsulation was developed by using various APS terminated groups; vinyl-sesquioxane (APSV) and methylsilsesquioxane (APSM) using the liquid-phase separation method. The characters of APSV- encapsulated pigments were examined by using thermal gravimetric analysis (TGA), Atomic force microscopy and electron microscope (SEM/TEM), Fourier transform infrared spectroscopy (FTIR) , dynamic light scattering (DLS), X-ray photoelectron (XPS). The characterization confirmed the successful encapsulation of PB15:3 into APSV. The vinyl terminated group in APSV provide a silicone formulations can be rabidly cured and crosslinked by UV or low thermal initiation to accelerate the driving force of the pigment printing process on cotton and polyester\cotton blend fabrics.The results showed that the encapsulated pigments improved the pigment print fixation on cellulosic fabric and its blend and decreased the requested amount of the binder and fixation temperature relative to the control sample.  The colour strength and light fastness were greatly influenced by the mode of fixation and APS type.
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spelling doaj.art-67f966560c0144bea34b4d0bc6e6df292022-12-22T04:07:50ZaraArab Association for Islamic Civilization and ArtJournal of Architecture, Art & Humanistic Science2356-96542357-03422017-10-0128335510.12816/0040839Surface modification of Pigment Blue 15:3 with aminosilsesquioxane oligomers for enhanced textile printingH.A Diab0S.A Rashad1O.A Hakeim2Textile Research Division, National Research Centre, Dokki, Cairo, EgyptTextile Research Division, National Research Centre, Dokki, Cairo, EgyptBeni-suef University, Faculty of Industrial Education, Textile Technology Department, Beni-suef, EgyptAminopropylsilsesquioxane oligomers (APS) encapsulated PB15:3 are formulated for in situ printing of cellulosic fabric and its blend. The encapsulation was developed by using various APS terminated groups; vinyl-sesquioxane (APSV) and methylsilsesquioxane (APSM) using the liquid-phase separation method. The characters of APSV- encapsulated pigments were examined by using thermal gravimetric analysis (TGA), Atomic force microscopy and electron microscope (SEM/TEM), Fourier transform infrared spectroscopy (FTIR) , dynamic light scattering (DLS), X-ray photoelectron (XPS). The characterization confirmed the successful encapsulation of PB15:3 into APSV. The vinyl terminated group in APSV provide a silicone formulations can be rabidly cured and crosslinked by UV or low thermal initiation to accelerate the driving force of the pigment printing process on cotton and polyester\cotton blend fabrics.The results showed that the encapsulated pigments improved the pigment print fixation on cellulosic fabric and its blend and decreased the requested amount of the binder and fixation temperature relative to the control sample.  The colour strength and light fastness were greatly influenced by the mode of fixation and APS type.https://mjaf.journals.ekb.eg/article_21735.htmlaminopropylsilsesquioxane oligomers (aps); vinyl terminated group; cellulosic fabrics; uv irradiation and pigment fixation
spellingShingle H.A Diab
S.A Rashad
O.A Hakeim
Surface modification of Pigment Blue 15:3 with aminosilsesquioxane oligomers for enhanced textile printing
Journal of Architecture, Art & Humanistic Science
aminopropylsilsesquioxane oligomers (aps); vinyl terminated group; cellulosic fabrics; uv irradiation and pigment fixation
title Surface modification of Pigment Blue 15:3 with aminosilsesquioxane oligomers for enhanced textile printing
title_full Surface modification of Pigment Blue 15:3 with aminosilsesquioxane oligomers for enhanced textile printing
title_fullStr Surface modification of Pigment Blue 15:3 with aminosilsesquioxane oligomers for enhanced textile printing
title_full_unstemmed Surface modification of Pigment Blue 15:3 with aminosilsesquioxane oligomers for enhanced textile printing
title_short Surface modification of Pigment Blue 15:3 with aminosilsesquioxane oligomers for enhanced textile printing
title_sort surface modification of pigment blue 15 3 with aminosilsesquioxane oligomers for enhanced textile printing
topic aminopropylsilsesquioxane oligomers (aps); vinyl terminated group; cellulosic fabrics; uv irradiation and pigment fixation
url https://mjaf.journals.ekb.eg/article_21735.html
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AT sarashad surfacemodificationofpigmentblue153withaminosilsesquioxaneoligomersforenhancedtextileprinting
AT oahakeim surfacemodificationofpigmentblue153withaminosilsesquioxaneoligomersforenhancedtextileprinting