Use of carbon and aluminosilicate nanofillers in XNBR composites designed for protective materials against oils
The objective of the work was to investigate the possibility of application of carbon and bentonite nanoparticles in carboxylated acrylonitrile-butadiene rubber (XNBR) and the related effects of the nanofillers on the structure, as well as mechanical and barrier properties, of the resulting composit...
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| Format: | Article |
| Language: | English |
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Sciendo
2018-06-01
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| Series: | Polish Journal of Chemical Technology |
| Subjects: | |
| Online Access: | https://doi.org/10.2478/pjct-2018-0018 |
| _version_ | 1818584670147706880 |
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| author | Krzemińska Sylwia M. Smejda-Krzewicka Aleksandra A. Leniart Andrzej |
| author_facet | Krzemińska Sylwia M. Smejda-Krzewicka Aleksandra A. Leniart Andrzej |
| author_sort | Krzemińska Sylwia M. |
| collection | DOAJ |
| description | The objective of the work was to investigate the possibility of application of carbon and bentonite nanoparticles in carboxylated acrylonitrile-butadiene rubber (XNBR) and the related effects of the nanofillers on the structure, as well as mechanical and barrier properties, of the resulting composites. The composites were designed for use in protective clothing and gloves. XNBR compounds were modified with 2 phr of graphene flakes, graphene oxide, or modified bentonite, and crosslinked with sulfur-accelerator system. Rubber compounds were prepared using a conventional method with a laboratory rolling mill. The composites were studied in terms of structure (WAXS), surface morphology (AFM), the presence of functional groups (ATR-FTIR) barrier properties against chemical substances (mineral oil) and swelling properties, as well as mechanical properties (abrasion resistance and tensile strength). The composites were characterized by very high resistance to oil permeation (breakthrough time >480 min). The type of nanofiller added to the XNBR blend in the amount of 2 phr did not significantly affect mechanical parameters. |
| first_indexed | 2024-12-16T08:24:52Z |
| format | Article |
| id | doaj.art-68037203902e435fae5516a9f6058d16 |
| institution | Directory Open Access Journal |
| issn | 1899-4741 |
| language | English |
| last_indexed | 2024-12-16T08:24:52Z |
| publishDate | 2018-06-01 |
| publisher | Sciendo |
| record_format | Article |
| series | Polish Journal of Chemical Technology |
| spelling | doaj.art-68037203902e435fae5516a9f6058d162022-12-21T22:38:01ZengSciendoPolish Journal of Chemical Technology1899-47412018-06-01202152310.2478/pjct-2018-0018pjct-2018-0018Use of carbon and aluminosilicate nanofillers in XNBR composites designed for protective materials against oilsKrzemińska Sylwia M.0Smejda-Krzewicka Aleksandra A.1Leniart Andrzej2Central Institute for Labour Protection – National Research Institute, Department of Personal Protective Equipment, Wierzbowa 48, 90-133Lodz, PolandLodz University of Technology, Institute of Polymer and Dye Technology, Stefanowskiego 12/16, 90-924Lodz, PolandUniversity of Lodz, Faculty of Chemistry, Department of Inorganic and Analytical Chemistry, Tamka 12, 91–403Lodz, PolandThe objective of the work was to investigate the possibility of application of carbon and bentonite nanoparticles in carboxylated acrylonitrile-butadiene rubber (XNBR) and the related effects of the nanofillers on the structure, as well as mechanical and barrier properties, of the resulting composites. The composites were designed for use in protective clothing and gloves. XNBR compounds were modified with 2 phr of graphene flakes, graphene oxide, or modified bentonite, and crosslinked with sulfur-accelerator system. Rubber compounds were prepared using a conventional method with a laboratory rolling mill. The composites were studied in terms of structure (WAXS), surface morphology (AFM), the presence of functional groups (ATR-FTIR) barrier properties against chemical substances (mineral oil) and swelling properties, as well as mechanical properties (abrasion resistance and tensile strength). The composites were characterized by very high resistance to oil permeation (breakthrough time >480 min). The type of nanofiller added to the XNBR blend in the amount of 2 phr did not significantly affect mechanical parameters.https://doi.org/10.2478/pjct-2018-0018carboxylated nitrile butadiene rubberxnbr compositesgraphenegraphene oxidebentonite |
| spellingShingle | Krzemińska Sylwia M. Smejda-Krzewicka Aleksandra A. Leniart Andrzej Use of carbon and aluminosilicate nanofillers in XNBR composites designed for protective materials against oils Polish Journal of Chemical Technology carboxylated nitrile butadiene rubber xnbr composites graphene graphene oxide bentonite |
| title | Use of carbon and aluminosilicate nanofillers in XNBR composites designed for protective materials against oils |
| title_full | Use of carbon and aluminosilicate nanofillers in XNBR composites designed for protective materials against oils |
| title_fullStr | Use of carbon and aluminosilicate nanofillers in XNBR composites designed for protective materials against oils |
| title_full_unstemmed | Use of carbon and aluminosilicate nanofillers in XNBR composites designed for protective materials against oils |
| title_short | Use of carbon and aluminosilicate nanofillers in XNBR composites designed for protective materials against oils |
| title_sort | use of carbon and aluminosilicate nanofillers in xnbr composites designed for protective materials against oils |
| topic | carboxylated nitrile butadiene rubber xnbr composites graphene graphene oxide bentonite |
| url | https://doi.org/10.2478/pjct-2018-0018 |
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