Removal Process of Benzo(α)pyrene from Linseed Oil

Aiming at the problem of benzo(α)pyrene residues in linseed oil, a physical adsorption method was used to remove benzo(α)pyrene from linseed oil. The main research methods were as follows: Activated carbon and activated clay were used as adsorbents, and the adsorption rates of the three adsorbents t...

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Main Authors: ERDUNBAYAR, Ping SUN, Huiru ZHANG, Guoqiang ZHANG, Xueyan YUN, Qianru CHEN, Tongliga DONG
Format: Article
Language:zho
Published: The editorial department of Science and Technology of Food Industry 2022-10-01
Series:Shipin gongye ke-ji
Subjects:
Online Access:http://www.spgykj.com/cn/article/doi/10.13386/j.issn1002-0306.2021120311
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author ERDUNBAYAR
Ping SUN
Huiru ZHANG
Guoqiang ZHANG
Xueyan YUN
Qianru CHEN
Tongliga DONG
author_facet ERDUNBAYAR
Ping SUN
Huiru ZHANG
Guoqiang ZHANG
Xueyan YUN
Qianru CHEN
Tongliga DONG
author_sort ERDUNBAYAR
collection DOAJ
description Aiming at the problem of benzo(α)pyrene residues in linseed oil, a physical adsorption method was used to remove benzo(α)pyrene from linseed oil. The main research methods were as follows: Activated carbon and activated clay were used as adsorbents, and the adsorption rates of the three adsorbents to benzo(α)pyrene were compared by using the two alone or in combination. The content of unsaturated fatty acids in linseed oil before and after treatment by the removal device was identified and analyzed by quadrupole-time-of-flight tandem mass spectrometry combined with NIST standard library. Through the determination of the removal capacity of the three adsorbents, the results showed that when the fixed dosage of activated clay was 4%, benzo(α)pyrene removal rate was nearly 40%; When the amount of activated carbon was 2%, the removal rate reached 83%; When the two were used in series, the removal rate could reach 96%. In addition, through the determination of the removal capacity of three adsorbents, the results showed when the concentration of benzo(α)pyrene was less than 15 μg/kg, activated clay was used for adsorption and filtration; When the concentration of benzo(α)pyrene was 15~30 μg/kg, activated carbon adsorption filtration was chosen; When the concentration of benzo(α)pyrene was more than 30 μg/kg, used the two in series for adsorption and filtration. Among them, the best effect of removing benzo(α)pyrene from linseed oil was activated clay and activated carbon in series by physical adsorption. The optimum conditions were as follows: The ratio of activated clay and activated carbon in series was 0.8%+4%, and the removal rate could reach 96% under these conditions. The use of adsorbents did not cause loss of unsaturated fatty acids in linseed oil. This paper provides a theoretical basis for removing of benzo(α)pyrene in flaxseed oil.
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spelling doaj.art-6804be9b32d84a5da97a6f92340464072022-12-22T04:39:14ZzhoThe editorial department of Science and Technology of Food IndustryShipin gongye ke-ji1002-03062022-10-01431925626310.13386/j.issn1002-0306.20211203112021120311-19Removal Process of Benzo(α)pyrene from Linseed OilERDUNBAYAR0Ping SUN1Huiru ZHANG2Guoqiang ZHANG3Xueyan YUN4Qianru CHEN5Tongliga DONG6School of Food Science and Engineering, Inner Mongolia Agricultural University, Hohhot 010018, ChinaSchool of Food Science and Engineering, Inner Mongolia Agricultural University, Hohhot 010018, ChinaSchool of Food Science and Engineering, Inner Mongolia Agricultural University, Hohhot 010018, ChinaInner Mongolia Yitai Ecological Industry Co., Ltd., Manzhouli 021400, ChinaSchool of Food Science and Engineering, Inner Mongolia Agricultural University, Hohhot 010018, ChinaSchool of Food Science and Engineering, Inner Mongolia Agricultural University, Hohhot 010018, ChinaSchool of Food Science and Engineering, Inner Mongolia Agricultural University, Hohhot 010018, ChinaAiming at the problem of benzo(α)pyrene residues in linseed oil, a physical adsorption method was used to remove benzo(α)pyrene from linseed oil. The main research methods were as follows: Activated carbon and activated clay were used as adsorbents, and the adsorption rates of the three adsorbents to benzo(α)pyrene were compared by using the two alone or in combination. The content of unsaturated fatty acids in linseed oil before and after treatment by the removal device was identified and analyzed by quadrupole-time-of-flight tandem mass spectrometry combined with NIST standard library. Through the determination of the removal capacity of the three adsorbents, the results showed that when the fixed dosage of activated clay was 4%, benzo(α)pyrene removal rate was nearly 40%; When the amount of activated carbon was 2%, the removal rate reached 83%; When the two were used in series, the removal rate could reach 96%. In addition, through the determination of the removal capacity of three adsorbents, the results showed when the concentration of benzo(α)pyrene was less than 15 μg/kg, activated clay was used for adsorption and filtration; When the concentration of benzo(α)pyrene was 15~30 μg/kg, activated carbon adsorption filtration was chosen; When the concentration of benzo(α)pyrene was more than 30 μg/kg, used the two in series for adsorption and filtration. Among them, the best effect of removing benzo(α)pyrene from linseed oil was activated clay and activated carbon in series by physical adsorption. The optimum conditions were as follows: The ratio of activated clay and activated carbon in series was 0.8%+4%, and the removal rate could reach 96% under these conditions. The use of adsorbents did not cause loss of unsaturated fatty acids in linseed oil. This paper provides a theoretical basis for removing of benzo(α)pyrene in flaxseed oil.http://www.spgykj.com/cn/article/doi/10.13386/j.issn1002-0306.2021120311linseed oilbenzo(α)pyreneactivated clayactivated carbonultra performance liquid chromatography-quadrupole-time-of-flight tandem mass spectrometry
spellingShingle ERDUNBAYAR
Ping SUN
Huiru ZHANG
Guoqiang ZHANG
Xueyan YUN
Qianru CHEN
Tongliga DONG
Removal Process of Benzo(α)pyrene from Linseed Oil
Shipin gongye ke-ji
linseed oil
benzo(α)pyrene
activated clay
activated carbon
ultra performance liquid chromatography-quadrupole-time-of-flight tandem mass spectrometry
title Removal Process of Benzo(α)pyrene from Linseed Oil
title_full Removal Process of Benzo(α)pyrene from Linseed Oil
title_fullStr Removal Process of Benzo(α)pyrene from Linseed Oil
title_full_unstemmed Removal Process of Benzo(α)pyrene from Linseed Oil
title_short Removal Process of Benzo(α)pyrene from Linseed Oil
title_sort removal process of benzo α pyrene from linseed oil
topic linseed oil
benzo(α)pyrene
activated clay
activated carbon
ultra performance liquid chromatography-quadrupole-time-of-flight tandem mass spectrometry
url http://www.spgykj.com/cn/article/doi/10.13386/j.issn1002-0306.2021120311
work_keys_str_mv AT erdunbayar removalprocessofbenzoapyrenefromlinseedoil
AT pingsun removalprocessofbenzoapyrenefromlinseedoil
AT huiruzhang removalprocessofbenzoapyrenefromlinseedoil
AT guoqiangzhang removalprocessofbenzoapyrenefromlinseedoil
AT xueyanyun removalprocessofbenzoapyrenefromlinseedoil
AT qianruchen removalprocessofbenzoapyrenefromlinseedoil
AT tongligadong removalprocessofbenzoapyrenefromlinseedoil